Publications associées à Environmental implications of solid oxide fuel cell system for hydrogen sustainability

Publications associées (20)

Configuring a Liquid State High-entropy Metal Alloy Electrocatalyst

A high-entropy liquid metal alloy (Ga-Fe-Zn-Sn-Bi-Ni) is developed to address the multi-step complexity of green ammonia electrosynthesis from nitrate. Guided by molecular dynamics, design of experiments, and density functional theory, this alloy exploits ...

WILEY-V C H VERLAG GMBH2025

Print-light-synthesis of electrocatalytically active gas diffusion electrodes for fuel cell applications

Hubert Girault, Kumar Varoon Agrawal, Luc Sébastien Bondaz

The present work reports a simple approach to manufacture electrocatalytically active gas diffusion electrodes (GDEs) in two steps: (i) inkjet printing and (ii) flash light irradiation from a xenon flash lamp, a process called Print-light-synthesis (PLS). ...

Royal Society of Chemistry2025

Performance assessment and fast diagnosis of a μ-CHP solid oxide fuel cell system

Florian Bernard Berset, Jan Van Herle, Philippe Aubin, Hangyu Yu, Cédric Frantz

Online performance characterization and faulty condition diagnosis of micro-combined-heat-and-power (μ-CHP) solid oxide fuel cell (SOFC) system is crucial for ensuring safe in-house operation and lifespan prolongation. However, fast accurate detection of f ...

2025

Amine modification enables selective CO2 electroreduction to ethanol via coupling of carbon-containing intermediates

Jing Gao

Electrochemical CO2-to-ethanol conversion faces challenges due to competing ethylene formation. We demonstrate a strategy steering selectivity toward ethanol by modifying copper nanowires with N,N,N′,N′-tetramethylethylenediamine (TMe). The TMe-Cu catalyst ...

2025

Realising efficient conversion of nitrogen-containing plastic waste with ceria-based catalysts

Xinbang Wu

The proliferation of plastic waste in the 21st century has serious environmental impacts on biodiversity and human health. Besides single-use plastic waste, there is mounting evidence that durable plastics, such as nitrogen-containing plastics, are being m ...

EPFL2025

A novel hydrogen-based desalination system for a self-sustaining community

François Maréchal, Du Wen

This work proposes a novel hydrogen-based desalination system to replace fossil fuelbased plants. The system has a water-hydrogen nexus framework to achieve an efficient operation, providing electricity, potable water, and green hydrogen. Through optimal p ...

2024

Co2 and h2o co-electrolyser system

François Maréchal, Jan Van Herle, Suhas Nuggehalli Sampathkumar

A water and carbon dioxide co-electrolyser system (1) comprising an anion exchange membrane (AEM) electrolyser (2) having at least one AEM electrolyser cell (2c) comprising a cathode (8), an anode (12) and an AEM membrane (16) separating the cathode from t ...

2024

Renewable synthesis fuels for a circular economy: A life cycle assessment

François Maréchal, Du Wen

Renewable synthesis fuels play a crucial role in enabling a circular economy. This study assesses the environmental impacts of power-to-hydrogen and biomass-to-hydrogen routes, considering four hydrogen storage options: hydrogen, ammonia, methane, and meth ...

2024

A High-Temperature, High-Speed, Oil-Free Syngas Compressor for Small-Scale Combined Heat and Power

Jan Van Herle, Jürg Alexander Schiffmann, Victoria Xu Hong He

For low-emission, small-scale combined heat and power generation, integrating a biomass gasifier with a downstream solid oxide fuel cell system is very promising due to their similar operating conditions in terms of temperatures and pressures. This match a ...

2024

Modelling The Effect of Future Uncertainty in Energy Prices on Decarbonization Pathways for Secondary Aluminium Production

Lorenzo Aimone, François Maréchal, Daniel Alexander Florez Orrego, Manuele Domenico Margni, Dareen Zuhir Omar Dardor

Aluminium is one of the most widely used metals in the world, but its production is highly energy intensive and largely dependent on the use of fossil fuels. A typical secondary aluminium production facility consumes 700-1,000 kWh of natural gas and 200-40 ...

2024

Process modeling and integration of hydrogen and synthetic natural gas production in a kraft pulp mill via black liquor gasification

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

The black liquor gasification integrated to chemical plants has shown potential for reducing the process irreversibility and promoting the decarbonization of this industrial sector. In the integrated chemical plants proposed in this work, the purpose is co ...

Pergamon-Elsevier Science Ltd2023

Flexible and Binder-Free Iron Phosphide Electrodes Using a Three-Dimensional Support for High Hydrogen Productivity

Maria Isabel Diez Garcia

In this work, an inexpensive and reliable microstructured electrode for the hydrogen evolution reaction (HER) is developed. This cathode is made of Earth-abundant elements consisting of iron phosphide as an electrocatalyst and carbon felt (CF) as a flexibl ...

2023

Understanding the role of surface oxygen-containing functional groups on carbon-supported cobalt catalysts for the oxygen evolution reaction

Manhui Wei, Andreas Züttel, Kangning Zhao, Liping Zhong, Thi Ha My Pham, Youngdon Ko

Supported Co-based catalysts exhibit promising catalytic activities in the oxygen evolution reaction (OER) during alkaline water electrolysis. Surface functionalization of the support modulates the dispersion of the catalysts and their interaction with the ...

Royal Society of Chemistry2023

Redox dual-flow battery for combined electricity storage and hydrogen production

Danick Reynard

The energy transition towards a carbon-neutral and sustainable economy is one of the greatest challenges of the 21st century to combat global warming and pollution. The decarbonization process is affecting every sector of the economy (electricity, transpor ...

EPFL2022

Exergy and exergoeconomic assessment of sustainable light olefins production from an integrated methanol synthesis and methanol-to-olefins system

François Maréchal

Integrated methanol synthesis and methanol-to-olefins systems are considered attractive and promising technologies to produce light olefins from syngas derived from biomass feedstock. In this study, a flowsheet model of a proposed system was developed and ...

ELSEVIER SCI LTD2022

Quantitative Design of a New e-Methanol Production Process

Alfred Rufer

In the context of the need to significantly reduce greenhouse gas emissions from personal transportation, a new process for the production of e-methanol is presented. It is a CO2 hydrogenation process, powered mainly by renewable energy sources such as pho ...

MDPI2022

Water Structure at the Hydrophobic Nanodroplet Surface Revealedby Vibrational Sum Frequency Scattering Using Isotopic Dilution br

Sylvie Roke, Saranya Pullanchery Sankara Narayanan, Sergey Kulik

The water structure at the hydrophobic/waterinterface is key toward understanding hydrophobicity at themolecular level. Herein, we characterize the hydrogen-bondingnetwork of interfacial water next to sub-micron-sized hydrophobicoil droplets dispersed in w ...

AMER CHEMICAL SOC2022

Performance Analysis of Ammonia in Solid Oxide Fuel Cells

Jan Van Herle, Suhas Nuggehalli Sampathkumar

Ammonia (NH3) has 17.8 wt% hydrogen and is easily liquified at 25°C and 8 bar pressure. Ammonia is carbon-free and can be produced sustainably at large scale and low cost. Solid oxide fuel cells generate electricity with efficiencies greater than 60% and c ...

ECS2021

Electric vehicle charging station using fuel cell technology: Two different scenarios and thermodynamic analysis

Jan Van Herle, Hossein Pourrahmani

This study evaluates two different scenarios of an integrated system to generate electricity for a charging station using proton exchange membrane fuel cell (PEMFC) and solid oxide fuel cell (SOFC). To improve the efficiency, the exhaust heat of these two ...

ELSEVIER2021

Assessing Tetrel-Based Neutral Frustrated Lewis Pairs for Catalytic Hydrogenation

Shubhajit Das

Frustrated Lewis pair (FLP) chemistry has gained significant attention in the past decade as the main group hydrogenation catalysts. The majority of the reported FLP catalysts utilize either boron-containing Lewis acids (LAs) or alternatively isolobal and ...

AMER CHEMICAL SOC2021