Maxime Christian Gérard Tricoire

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Lanthanide redox reactivity remains limited to one-electron transfer reactions due to their inability to access a broad range of oxidation states. Here, we show that multielectron reductive chemistry is achieved for ytterbium by using the tripodal tris(sil ...

Synthetic strategies to isolate molecular complexes of lanthanides, other than cerium, in the +4 oxidation state remain elusive, with only four complexes of Tb(iv) isolated so far. Herein, we present a new approach for the stabilization of Tb(iv) using a s ...

The silsesquioxane ligand (Bu-i)(7)Si7O9(OH)(3) ((POSSH3)-P-iBu) is revealed as an attractive system for the assembly of robust polynuclear complexes of uranium(III) and allowed the isolation of the first example of a trinuclear U(III) complex ([U-3((POSS) ...

Thesynthesis of molecular uranium complexes in oxidation stateslower than +3 remains a challenge despite the interest for their multielectrontransfer reactivity and electronic structures. Herein, we report theone- and two-electron reduction of a U(III) com ...

Maxime Christian Gérard Tricoire

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Multielectron Redox Chemistry of Ytterbium Complexes Reaching the +1 and Zero Formal Oxidation States

Siloxide tripodal ligands as a scaffold for stabilizing lanthanides in the +4 oxidation state

A trinuclear metallasilsesquioxane of uranium(III)

Multielectron Redox Chemistry of Uranium by Accessing the plus II Oxidation State and Enabling Reduction to a U(I) Synthon