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Jovana Milic

Cette personne a quitté l’EPFL

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Publications associées (43)

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Spectro-electrochemical toolbox for monitoring and controlling quinone-mediated redox-driven molecular gripping

Jovana Milic

The control of molecular systems by electrical charge or light is a prerequisite for their application in nanoelectronics. Such potential has been uniquely exploited in quinone-based resorcin[4]arene cavitands that can act as molecular grippers, reversibly ...

2019

Supramolecular Modulation for Hybrid Perovskite Photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jovana Milic, Masaud Hassan S Almalki, Felix Thomas Eickemeyer, Hong Zhang, Ghewa Alsabeh

Hybrid perovskites are emerging as top contenders in the next generation of photovoltaics, yet their stability under operational conditions remains a significant challenge. Specifically, degradation occurs at the interface with charge transport layers in p ...

2024

Benzylammonium‐Mediated Formamidinium Lead Iodide Perovskite Phase Stabilization for Photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Dominik Józef Kubicki, David Lyndon Emsley, Zaiwei Wang, Anwar Qasem M Alanazi, Jovana Milic, Dan Ren, Masaud Hassan S Almalki, Aditya Mishra, Felix Thomas Eickemeyer, Hong Zhang

There is an ongoing surge of interest in the use of formamidinium (FA) lead iodide perovskites in photovoltaics due to their exceptional optoelectronic properties. However, thermodynamic instability of the desired cubic perovskite (α-FAPbI3) phase at ambie ...

2021

Photo De-Mixing in Dion-Jacobson 2D Mixed Halide Perovskites

Michael Graetzel, Ursula Röthlisberger, Marko Mladenovic, Jovana Milic, Algirdas Ducinskas

2D halide perovskites feature a versatile structure, which not only enables the fine-tuning of their optoelectronic properties but also makes them appealing as model systems to investigate the fundamental properties of hybrid perovskites. In this study, th ...

2022

Reversible Pressure-Dependent Mechanochromism of Dion-Jacobson and Ruddlesden-Popper Layered Hybrid Perovskites

Michael Graetzel, Ursula Röthlisberger, Jovana Milic, Mathias Dankl, Algirdas Ducinskas

Layered Dion-Jacobson (DJ) and Ruddlesden-Popper (RP) hybrid perovskites are promising materials for optoelectronic applications due to their modular structure. To fully exploit their functionality, mechanical stimuli can be used to control their propertie ...

Wiley-V C H Verlag Gmbh2022

Nanosegregation in arene-perfluoroarene pi-systems for hybrid layered Dion-Jacobson perovskites

Michael Graetzel, Shaik Mohammed Zakeeruddin, Pascal Alexander Schouwink, Jovana Milic, Masaud Hassan S Almalki, Algirdas Ducinskas, Lukas Pfeifer, Laura Piveteau

Layered hybrid perovskites are based on organic spacers separating hybrid perovskite slabs. We employ arene and perfluoroarene moieties based on 1,4-phenylenedimethylammonium (PDMA) and its perfluorinated analogue (F-PDMA) in the assembly of hybrid layered ...

2022

Multifunctional Molecular Modulation for Efficient and Stable Hybrid Perovskite Solar Cells

Michael Graetzel, Dominik Józef Kubicki, David Lyndon Emsley, Jovana Milic

Hybrid organic-inorganic perovskites have become one of the leading thin-film semiconductors for optoelectronics. Their broad application will greatly depend on overcoming the key obstacles associated with poor stability and limited scalability. There has ...

2019

The Impact of Spacer Size on Charge Transfer Excitons in Dion–Jacobson and Ruddlesden–Popper Layered Hybrid Perovskites

Michael Graetzel, Jacques-Edouard Moser, Aaron Tomas Terpstra, Jovana Milic, George Cameron Fish, Masaud Hassan S Almalki, Algirdas Ducinskas, Lukas Pfeifer

Organic materials can tune the optical properties in layered (2D) hybrid perovskites, although their impact on photophysics is often overlooked. Here, we use transient absorption spectroscopy to probe the Dion−Jacobson (DJ) and Ruddlesden−Popper (RP) 2D pe ...

2023

Thiocyanate-Mediated Dimensionality Transformation of Low- Dimensional Perovskites for Photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Claudia Esther Avalos, Zaiwei Wang, Yuhang Liu, Brian Irving Carlsen, Jovana Milic, Dan Ren

Two-dimensional (2D) hybrid perovskite solar cells have induced widespread research interest owing to their higher stability as compared to three-dimensional (3D) analogues. The photovoltaic performance, however, is still limited. Here, we report a perovsk ...

2022

The Advent of Molecular Photovoltaics and Hybrid Perovskite Solar Cells

Michael Graetzel, Jovana Milic

Over the past decade, we witnessed a remarkable development of a new generation of photovoltaic technologies, in particular dyesensitized and perovskite solar cells. These systems have demonstrated potential to provide solutions for a more sustainable futu ...

2019

Atomic-Level Microstructure of Efficient Formamidinium-Based Perovskite Solar Cells Stabilized by 5-Ammonium Valeric Acid Iodide Revealed by Multinuclear and Two-Dimensional Solid-State NMR

Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Marine Eva Fedora Bouduban, Marko Mladenovic, Fabrizio Giordano, Dominik Józef Kubicki, David Lyndon Emsley, Farzaneh Jahanbakhshi, Essa Awadh R Alharbi, Daniel Prochowicz, Anwar Qasem M Alanazi, Jovana Milic, Dan Ren

Chemical doping of inorganic–organic hybrid perovskites is an effective way of improving the performance and operational stability of perovskite solar cells (PSCs). Here we use 5-ammonium valeric acid iodide (AVAI) to chemically stabilize the structure of ...

2019

Multifunctional molecular modulators for perovskite solar cells with over 20% efficiency and high operational stability

Shaik Mohammed Zakeeruddin, Pierre Mettraux, Norman Pellet, Dominik Józef Kubicki, Xiong Li, Jingshan Luo, David Lyndon Emsley, Dongqin Bi, Jovana Milic

Perovskite solar cells present one of the most prominent photovoltaic technologies, yet their stability, scalability, and engineering at the molecular level remain challenging. We demonstrate a concept of multifunctional molecular modulation of scalable an ...

Nature Research2018

Interfacial Modulation through Mixed-Dimensional Heterostructures for Efficient and Hole Conductor-Free Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Anwar Qasem M Alanazi, Jovana Milic, Felix Thomas Eickemeyer, Hong Zhang, Laura Piveteau

Perovskite solar cells have led the new surge of solar energy research. However, their instability is a pressing issue mostly attributed to the perovskite interface with charge-selective transport layers. In this work, diethylammonium iodide (DEAI) surface ...

Wiley-V C H Verlag Gmbh2023

Multimodal host–guest complexation for efficient and stable perovskite photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Ulf Anders Hagfeldt, Marko Mladenovic, David Lyndon Emsley, Farzaneh Jahanbakhshi, Paramvir Ahlawat, Zaiwei Wang, Jovana Milic, Dan Ren, Aditya Mishra, Felix Thomas Eickemeyer, Hong Zhang, Zhaowen Dong, Jinming Guo, Michael Allan Hope, Anurag Krishna, Olivier Ouellette, Zhiwen Zhou

Formamidinium lead iodide perovskites are promising light-harvesting materials, yet stabilizing them under operating conditions without compromising optimal optoelectronic properties remains challenging. We report a multimodal host–guest complexation strat ...

Nature Research2021

Nanoscale Phase Segregation in Supramolecular π-Templating for Hybrid Perovskite Photovoltaics from NMR Crystallography

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Ulf Anders Hagfeldt, Marko Mladenovic, Dominik Józef Kubicki, Manuel Cordova, David Lyndon Emsley, Farzaneh Jahanbakhshi, Paramvir Ahlawat, Yuhang Liu, Brian Irving Carlsen, Jovana Milic, Rashmi Runjhun, Aditya Mishra, Michael Allan Hope

The use of layered perovskites is an important strategy to improve the stability of hybrid perovskite materials and their optoelectronic devices. However, tailoring their properties requires accurate structure determination at the atomic scale, which is a ...

2021

Dopant Engineering for Spiro‐OMeTAD Hole‐Transporting Materials towards Efficient Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jiyoun Seo, Hui-Seon Kim, Jovana Milic, Seckin Akin, Marco Alejandro Ruiz Preciado

One of the most prominent hole-transporting material (HTM) for hybrid perovskite solar cells has been 2,2″,7,7″-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene (spiro-OMeTAD), which is commonly doped with metal bis(trifluoromethylsulfonyl)imide ...

2021

Unravelling the structural complexity and photophysical properties of adamantyl-based layered hybrid perovskites

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ursula Röthlisberger, Ulf Anders Hagfeldt, Amita Ummadisingu, Mohammad Ibrahim Dar, Marko Mladenovic, Wolfgang Richard Tress, Farzaneh Jahanbakhshi, Paramvir Ahlawat, Brian Irving Carlsen, Yang Li, Jovana Milic, Algirdas Ducinskas

Layered hybrid perovskites comprising adamantyl spacer (A) cations based on the A(2)FA(n-1)Pb(n)I(3n+1)(n= 1-3, FA = formamidinium) compositions have recently been shown to act as promising materials for photovoltaic applications. While the corresponding p ...

Royal Society of Chemistry2020

Supramolecular Modulation of Hybrid Perovskite Solar Cells via Bifunctional Halogen Bonding Revealed by Two-Dimensional 19F Solid-State NMR Spectroscopy

Shaik Mohammed Zakeeruddin, Amita Ummadisingu, Dominik Józef Kubicki, David Lyndon Emsley, Albert Hofstetter, Jovana Milic, Marco Alejandro Ruiz Preciado

There has been an ongoing effort to overcome the limitations associated with the stability of hybrid organic–inorganic perovskite solar cells by using different organic agents as additives to the perovskite formulations. The functionality of organic additi ...

2020

Bifunctional Organic Spacers for Formamidinium-Based Hybrid Dion-Jacobson Two-Dimensional Perovskite Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Amita Ummadisingu, Mohammad Ibrahim Dar, Jeong-Hyeok Im, Jiyoun Seo, Peng Wang, Hui-Seon Kim, Yuhang Liu, Yang Li, Jovana Milic

Three-dimensional (3D) perovskite materials display remarkable potential in photovoltaics owing to their superior solar-to-electric power conversion efficiency, with current efforts focused on improving stability. Two-dimensional (2D) perovskite analogues ...

AMER CHEMICAL SOC2019

Unravelling the Behavior of Dion-Jacobson Layered Hybrid Perovskites in Humid Environments

Michael Graetzel, David Lyndon Emsley, Jovana Milic, Algirdas Ducinskas, Aditya Mishra, Michael Allan Hope

Layered hybrid halide perovskites are known to be more environmentally stable than their 3D analogues. The enhanced stability is particularly relevant for Dion-Jacobson-type layered perovskites due to their promising photovoltaic performances. However, in ...

2021