Publications de Luciano Barluzzi

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Uranium nitride compounds are important molecular analogues of uranium nitride materials such as UN and UN2 which are effective catalysts in the Haber-Bosch synthesis of ammonia, but the synthesis of molecular nitrides remains a challenge and studies of th ...

The activation of small molecules is a paramount challenge in modern chemistry. The use of cheap and abundant molecules such as N2, H2, CO2, or CO as energy supplies or as precursors for fine chemicals production is highly desirable. In particular, the onl ...

Molecular uranium nitride complexes were prepared to relate their small molecule reactivity to the nature of the U & xe001;N & xe001;U bonding imposed by the supporting ligand. The U4+-U4+ nitride complexes, [NBu4][{(((BuO)-Bu-t)(3)SiO)(3)U}(2)(mu-N)], [NB ...

Despite their synthetic interest and potential attractive properties, the preparation of heteroleptic U(III) complexes containing monodentate ligands remains challenging. Here we report the synthesis, structure and magnetic properties of three heteroleptic ...

The synthesis and reactivity of uranium compounds supported by the tris-tert-butoxysiloxide ligand is surveyed. The multiple binding modes of the tert-butoxysiloxide ligand have proven very well suited to stabilize highly reactive homo- and heteropolymetal ...

Single-atom (group 15 and group 16 anions) bridged dimetallic complexes of low oxidation state uranium provide a convenient route to implement multielectron transfer and promote magnetic communication in uranium chemistry, but remain extremely rare. Here w ...

Multimetallic cooperativity is believed to play a key role in the cleavage of dinitrogen to nitrides (N3-), but the mechanism remains ambiguous due to the lack of isolated intermediates. Herein, we report the reduction of the complex [K-2{[U-V(OSi((OBu)-Bu ...

Terminal uranium nitrides have so far proven impossible to isolate by photolysis of azides. Here we report the second ever example of an isolated terminal uranium(VI) nitride. We show that the terminal nitride [NBu4] [U(OSi((OBu)-Bu-t)(3))(4)(N)], 3, can b ...

Correction for Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex' by Luciano Barluzzi et al., Chem. Sci., 2019, DOI: ; 10.1039/c8sc05721d. ...

Luciano Barluzzi

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Synthesis, structure, and reactivity of uranium(VI) nitrides

Design, synthesis, reactivity, and magnetic properties of uranium based oxide and nitride complexes

Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands

Structure and Magnetic Properties of a Series of Uranium Bis-Siloxide Complexes

Small molecule activation by multimetallic uranium complexes supported by siloxide ligands

Synthesis, structure and redox properties of single-atom bridged diuranium complexes supported by aryloxides

Stepwise Reduction of Dinitrogen by a Uranium-Potassium Complex Yielding a U(VI)/U(IV) Tetranitride Cluster

Photochemical Synthesis of a Stable Terminal Uranium(VI) Nitride

Correction: Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex (vol 10, pg 3543, 2019)

Tuning reactivity of nitride bridged uranium complexes with amide and siloxide ligands