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Antonio Abate

Cette personne n’est plus à l’EPFL

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Publications associées (48)

Monolithic perovskite/silicon-heterojunction tandem solar cells processed at low temperature

Michael Graetzel, Mohammad Khaja Nazeeruddin, Ulf Anders Hagfeldt, Ludmilla Steier, Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba

Tandem solar cells combining silicon and perovskite absorbers have the potential to outperform state-of-the-art high efficiency silicon single junction devices. However, the practical fabrication of monolithic silicon/perovskite tandem solar cells is chall ...

Royal Soc Chemistry2016

Carbon nanotube-based hybrid hole-transporting material and selective contact for high efficiency perovskite solar cells

Michael Graetzel, Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Antonio Abate

We demonstrate a high efficiency perovskite solar cell with a hybrid hole-transporting material-counter electrode based on a thin single-walled carbon nanotube (SWCNT) film and a drop-cast 2,2,7,-7-tetrakis(N, N-di-p-methoxyphenylamine)-9,90-spirobifluoren ...

Royal Soc Chemistry2016

Inverted Current-Voltage Hysteresis in Mixed Perovskite Solar Cells: Polarization, Energy Barriers, and Defect Recombination

Michael Graetzel, Wolfgang Richard Tress, Antonio Abate, Michael Saliba

Organic-inorganic metal halide perovskite solar cells show hysteresis in their current-voltage curve measured at a certain voltage sweep rate. Coinciding with a slow transient current response, the hysteresis is attributed to a slow voltage-driven (ionic) ...

Wiley-VCH Verlag Berlin2016

High Absorption Coefficient Cyclopentadithiophene Donor-Free Dyes for Liquid and Solid-State Dye-Sensitized Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Yelin Hu, Yiming Cao, Antonio Abate

We report a series of "donor-free" dyes featuring moieties of oligo(4,4-dihexyl-4H-cyclopenta[1,2-b:5,4-b']dithiophene) (CPDT) functionalized with cyanoacrylic end groups for mesoscopic titania solar cells based on I-/I-3(-) or Co(II)/Co(III) redox couple ...

Amer Chemical Soc2016

Enhanced Efficiency and Stability of Perovskite Solar Cells Through Nd-Doping of Mesostructured TiO2

Michael Graetzel, Henry Snaith, Antonio Abate

Block-copolymer templated chemical solution deposition is used to prepare mesoporous Nd-doped TiO2 electrodes for perovskite-based solar cells. X-ray diffraction and photothermal deflection spectroscopy show substitutional incorporation into the TiO2 cryst ...

Wiley-V C H Verlag Gmbh2016

Enhanced electronic properties in mesoporous TiO2 via lithium doping for high-efficiency perovskite solar cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Fabrizio Giordano, Juan-Pablo Correa-Baena, Antonio Abate, Taisuke Matsui, Michael Saliba

Perovskite solar cells are one of the most promising photovoltaic technologies with their extraordinary progress in efficiency and the simple processes required to produce them. However, the frequent presence of a pronounced hysteresis in the current volta ...

Nature Publishing Group2016

Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Konrad Domanski, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Jiyoun Seo, Taisuke Matsui, Michael Saliba

Today's best perovskite solar cells use a mixture of formamidinium and methylammonium as the monovalent cations. With the addition of inorganic cesium, the resulting triple cation perovskite compositions are thermally more stable, contain less phase impuri ...

Royal Society of Chemistry2016

Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide

Michael Graetzel, Ulf Anders Hagfeldt, Ludmilla Steier, Konrad Domanski, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Taisuke Matsui, Michael Saliba, Elham Halvani Anaraki

Perovskite solar cells (PSCs) are one of the most promising lab-scale technologies to deliver inexpensive solar electricity. Low-temperature planar PSCs are particularly suited for large-scale manufacturing. Here, we propose a simple, solution-processed te ...

Royal Society of Chemistry2016

Optical analysis of CH3NH3SnxPb1-I-x(3) absorbers: a roadmap for perovskite-on-perovskite tandem solar cells

Michael Graetzel, Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Antonio Abate, Michael Saliba

Organic-inorganic perovskite structures in which lead is substituted by tin are exceptional candidates for broadband light absorption. Herein we present a thorough analysis of the optical properties of CH3NH3SnxPb1-xI3 films, providing the field with defin ...

Royal Society of Chemistry2016

Unbroken Perovskite: Interplay of Morphology, Electro-optical Properties, and Ionic Movement

Michael Graetzel, Ulf Anders Hagfeldt, Konrad Domanski, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Taisuke Matsui, Michael Saliba, Tor Jesper Jacobsson

Hybrid organic-inorganic perovskite materials have risen up as leading components for light-harvesting applications. However, to date many questions are still open concerning the operation of perovskite solar cells (PSCs). A systematic analysis of the inte ...

Wiley-V C H Verlag Gmbh2016

Mesoporous SnO2 electron selective contact enables UV-stable perovskite solar cells

Michael Graetzel, Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Antonio Abate

Perovskite solar cells are a promising new technology for large scale energy applications. The current major challenge for commercialization is increasing the device lifetime under real working conditions. State-of-the-art perovskite solar cells are prepar ...

Elsevier Science Bv2016

Ionic Liquid Control Crystal Growth to Enhance Planar Perovskite Solar Cells Efficiency

Michael Graetzel, Shaik Mohammed Zakeeruddin, Kurt Schenk, Ulf Anders Hagfeldt, Amita Ummadisingu, Konrad Domanski, Fabrizio Giordano, Jingshan Luo, Juan-Pablo Correa-Baena, Antonio Abate, Jiyoun Seo, Taisuke Matsui, Michael Saliba, Mahboobeh Hadadian

Ionic liquids can retard the perovskite crystallization with the aim to form compact films with larger and more uniformly distributed grain size. The ionic liquid driven crystallization is exploited to prepared a record planar perovskite solar cell with st ...

Wiley-VCH Verlag Berlin2016

Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Amita Ummadisingu, Konrad Domanski, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Jiyoun Seo, Taisuke Matsui, Michael Saliba

All of the cations currently used in perovskite solar cells abide by the tolerance factor for incorporation into the lattice. We show that the small and oxidation-stable rubidium cation (Rb+) can be embedded into a "cation cascade" to create perovskite mat ...

American Association for the Advancement of Science2016

Perovskite Solar Cell Stability in Humid Air: Partially Reversible Phase Transitions in the PbI2-CH3NH3I-H2O System

Michael Graetzel, Antonio Abate

After rapid progress over the past five years, organic-inorganic perovskite solar cells (PSCs) currently exhibit photoconversion efficiencies comparable to the best commercially available photovoltaic technologies. However, instabilities in the materials a ...

Wiley-VCH Verlag Berlin2016

Highly Efficient and Stable Perovskite Solar Cells based on a Low-Cost Carbon Cloth

Michael Graetzel, Ulf Anders Hagfeldt, Ludmilla Steier, Konrad Domanski, Fabrizio Giordano, Wolfgang Richard Tress, Juan-Pablo Correa-Baena, Antonio Abate, Taisuke Matsui, Michael Saliba

Wiley-VCH Verlag Berlin2016

Enhancing Efficiency of Perovskite Solar Cells via N-doped Graphene: Crystal Modification and Surface Passivation

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Amita Ummadisingu, Jingshan Luo, Juan-Pablo Correa-Baena, Antonio Abate, Jiyoun Seo, Michael Saliba, Mahboobeh Hadadian

Controlling the morphology and surface passivation in perovskite solar cells is paramount in obtaining optimal opto-electronic properties. This study incorporates N-doped graphene nanosheets in the perovskite layer, which simultaneously induces an improved ...

Wiley2016

A New 1,3,4-Oxadiazole-Based Hole-Transport Material for Efficient CH3NH3PbBr3 Perovskite Solar Cells

Michael Graetzel, Ulf Anders Hagfeldt, Juan-Pablo Correa-Baena, Antonio Abate

A new hole-transport material (HTM) based on the 1,3,4-oxadiazole moiety (H1) was prepared through a single-step synthetic pathway starting from commercially available products. Thanks to a deep HOMO level, H1 was used as HTM in CH3NH3PbBr3 perovskite sola ...

Wiley-V C H Verlag Gmbh2016

Silolothiophene-linked triphenylamines as stable hole transporting materials for high efficiency perovskite solar cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Peng Gao, Fabrizio Giordano, Sanghyun Paek, Juan-Pablo Correa-Baena, Antonio Abate, Taisuke Matsui, Michael Saliba

In this work, we synthesized novel hole transporting materials (HTMs) and studied their impact on the stability of perovskite-based solar cells (PSCs). The steady-state maximum power output of devices in working condition was monitored to assess the stabil ...

Royal Society of Chemistry2015

Efficient photosynthesis of carbon monoxide from CO2 using perovskite photovoltaics

Michael Graetzel, Shaik Mohammed Zakeeruddin, Marcel Roland Schreier, Ludmilla Steier, Fabrizio Giordano, Matthew Thomas Mayer, Jingshan Luo, Antonio Abate

Artificial photosynthesis, mimicking nature in its efforts to store solar energy, has received considerable attention from the research community. Most of these attempts target the production of H-2 as a fuel and our group recently demonstrated solar-to-hy ...

Nature Publishing Group2015

Triazatruxene-Based Hole Transporting Materials for Highly Efficient Perovskite Solar Cells

Michael Graetzel, Mohammad Khaja Nazeeruddin, Peng Gao, Kasparas Rakstys, Gwénolé Jean Jacopin, Mohammad Ibrahim Dar, Antonio Abate

Four center symmetrical star-shaped hole transporting materials (HTMs) comprising planar triazatruxene core and electron-rich methoxy-engineered side arms have been synthesized and successfully employed in (FAPbI(3))(0.85)(MAPbBr(3))(0.15) perovskite solar ...

Amer Chemical Soc2015

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