Publications de Evgeny Smirnov

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Emulsification of immiscible two-phase fluids, i.e., one condensed phase dispersed homogeneously as tiny droplets in an outer continuous medium, plays a key role in medicine, food, chemical separations, cosmetics, fabrication of micro- and nanoparticles an ...

Functionalization of a soft or liquid-liquid interface by a one gold nanoparticle thick “nanofilm” provides a conductive pathway to facilitate interfacial electron transfer from a lipophilic electron donor to a hydrophilic electron acceptor in a process kn ...

Simple methods to self-assemble coatings and films encompassing nanoparticles are highly desirable in many practical scenarios, yet scarcely any examples of simple, robust approaches to coat macroscopic droplets with continuous, thick (multilayer), reflect ...

The optical and morphological properties of lustrous metal self-healing liquid-like nanofilms were systematically studied towards different applications (e.g., optical mirrors or filters). These nanofilms were formed by a one-step self-assembly methodology ...

The interface between two immiscible liquids, i.e. oil and water, is an extremely attractive scaffold to self-assemble nanoparticles (NP) in arranged films. The liquid-liquid interfaces (LLIs) are defect-free and pristine by the nature, they are transparen ...

Soft or “liquid-liquid” interfaces were functionalized by half a monolayer of mirror-like nanofilms of gold nanoparticles using a precise interfacial microinjection method. The surface coverage of the nanofilm was characterized by ion transfer voltammetry. ...

Here, we propose a simple shake-flask method to produce micron-size colloidosomes from a liquid-liquid interface functionalized with a gold nanoparticle film. A step-by-step extraction process of an organic phase partially miscible with water led to the fo ...

The redox properties of metallic nanoparticles are discussed, in particular the relationships between excess charge, size and the Fermi level of the electrons. The redox potentials are derived using simple electrostatic models to provide a straightforward ...

All redox flow batteries suffer from low energy storage density in comparison with conventional Li-ion batteries. However, this issue can be mitigated by utilization of solid energy storage materials to enhance the energy storage capacity. In this paper we ...

Control over the physical properties of nanoparticle assemblies at a liquid–liquid interface is a key technological advancement to realize the dream of smart electrovariable nanosystems. Electrified interfaces, such as the interface between two immiscible ...

Citrate-stabilized gold nanoparticles were found to spontaneously self-assemble into a lustrous film at a bare water–propylene carbonate interface after vigorous shaking, due to the extremely low interfacial tension. The presence of an electron donor, tetr ...

Evgeny Smirnov

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Ionosomes: Observation of Ionic Bilayer Water Clusters

Heterogeneous versus homogeneous electron transfer reactions at liquid–liquid interfaces: The wrong question?

Gold Nanofilm Redox Catalysis for Oxygen Reduction at Soft Interfaces

Gold Metal Liquid-Like Droplets

Self-Healing Gold Mirrors and Filters at Liquid-Liquid Interfaces

Assemblies of gold nanoparticles at liquid-liquid interfaces : from liquid optics to electrocatalysis

Interfacial Redox Catalysis on Gold Nanofilms at Soft Interfaces

Gold Raspberry-Like Colloidosomes Prepared at the Water-Nitromethane Interface

Charging and Discharging at the Nanoscale: Fermi Level Equilibration of Metallic Nanoparticles

Solid electrochemical energy storage for aqueous redox flow batteries: The case of copper hexacyanoferrate

Electrovariable gold nanoparticle films at liquid–liquid interfaces: from redox electrocatalysis to Marangoni-shutters

Self-assembly and redox induced phase transfer of gold nanoparticles at the water-propylene carbonate interface

Large-scale layer-by-layer inkjet printing of flexible iridium-oxide based pH sensors