Aurélien René Willauer

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The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

Out of the 14 lanthanide (Ln) ions, molecular complexes of Ln(IV) were known only for cerium and more recently terbium. Here we demonstrate that the +IV oxidation state is also accessible for the large praseodymium (Pr) cation. The oxidation of the tetraki ...

The mechanisms behind the large photocarrier diffusion length and the outstanding photovoltaic performances of lead halide perovskites (LHP) are still debated. Hot carrier cooling and the formation of polarons are central to the charge separation process. ...

Trinuclear molecular complexes of europium (II)and ytterbium(II) [Ln3{(Ph2SiO)2O}3(THF)6],1-Ln3L3(Ln = Euand Yb), supported by the dianionic tetraphenyl disiloxanediolateligand, were synthesized via protonolysis of the [Ln{N-(SiMe3)2}2(THF)2] complexes. In ...

Among the 14 lanthanide elements (Ce-Lu), until recently, the tetravalent oxidation state was readily accessible in solution only for cerium while Pr(iv), Nd(iv), Dy(iv) and Tb(iv) had only been detected in the solid state. The triphenylsiloxide ligand rec ...

Rigidtritopic linkers of different sizes were used to buildporous U-(IV) and Th-(IV) 3D frameworks. The charge of the polymerscould be tuned by reaction conditions such as the temperature, pH,solvent, ligand, or metal precursor, yielding a series of neutra ...

The synthesis of lanthanides other than cerium in the oxidation state +IV has remained a desirable but unmet target until recently, when two examples of Tb-IV with saturated coordination spheres were isolated. Here we report the third example of an isolate ...

Dataset underpinning the published article: A. Burgos-Caminal; J. M. Moreno-Naranjo; A. R. Willauer; A. A. Paraecattil; A. Ajdarzadeh and J.-E. Moser. Hot Carrier Mobility Dynamics Unravel Competing Subpicosecond Processes in Lead Halide Perovskites. J. Ph ...

Aurélien René Willauer

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Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Accessing the plus IV Oxidation State in Molecular Complexes of Praseodymium

Hot Carrier Mobility Dynamics Unravel Competing Subpicosecond Processes in Lead Halide Perovskites

Structure and Reactivity of Polynuclear Divalent Lanthanide Disiloxanediolate Complexes br

Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides

Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids

Stabilization of the Oxidation State plus IV in Siloxide-Supported Terbium Compounds

Dataset of "Hot Carrier Mobility Dynamics Unravel Competing Subpicosecond Processes in Lead Halide Perovskites"