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William Curtin

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Publications associées (153)

Mechanistic origin of high strength in refractory BCC high entropy alloys up to 1900K

William Curtin, Francesco Maresca

The body centered cubic (BCC) high entropy alloys (HEAs) MoNbTaW and MoNbTaVW show exceptional strength retention up to 1900K. The mechanistic origin of the retained strength is unknown yet is crucial for finding the best alloys across the immense space of ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Design of Ductile Rare-Earth-Free Magnesium Alloys

William Curtin, Zhaoxuan Wu, Binglun Yin, Rasool Ahmad

Pure Mg has low ductility due to a transition of < c+a > pyramidal dislocations to a sessile basal-oriented structure. Dilute alloying generally improves ductility. Enhancement of pyramidal cross-slip from the lower-energy pyramidal II plane to the higher- ...

SPRINGER INTERNATIONAL PUBLISHING AG2020

Effect of solute-solute interactions on strengthening of random alloys from dilute to high entropy alloys

William Curtin, Shankha Nag

The yield strength of random metal alloys, i.e. alloys with random occupation of the crystalline lattice sites by the elemental constituent atoms all considered as solutes, is primarily understood as controlled by solute/dislocation interactions. Solute-so ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Machine learning for metallurgy I. A neural-network potential for Al-Cu

Albert Johann Glensk, William Curtin, Daniel John Gilles Marchand, Abhinav Jain

High-strength metal alloys achieve their performance via careful control of precipitates and solutes. The nucleation, growth, and kinetics of precipitation, and the resulting mechanical properties, are inherently atomic scale phenomena, particularly during ...

2020

Analysis of double cross-slip of pyramidal I < c plus a > screw dislocations and implications for ductility in Mg alloys

William Curtin, Zhaoxuan Wu, Rasool Ahmad

Solute accelerated cross-slip of pyramidal < c + a > screw dislocations has recently been recognized as a crucial mechanism in enhancing the ductility of solid-solution Mg alloys. In pure Mg, cross-slip is ineffective owing to the energy difference between ...

PERGAMON-ELSEVIER SCIENCE LTD2020

A decohesion pathway for hydrogen embrittlement in nickel: Mechanism and quantitative prediction

Xiaoqing Zhou, William Curtin, Ali Tehranchi

Hydrogen embrittlement (HE) is a ubiquitous and catastrophic mode of fracture in metals. Here, embrittlement is considered as an intrinsic ductile-brittle transition at the crack tip, where H at the crack tip can reduce the stress intensity K-Ic for cleava ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Solute-strengthening in elastically anisotropic fcc alloys

William Curtin, Céline Varvenne, Shankha Nag

Dislocation motion through a random alloy is impeded by its interactions with the compositional fluctuations intrinsic to the alloy, leading to strengthening. A recent theory predicts the strengthening as a function of the solute-dislocation interaction en ...

IOP PUBLISHING LTD2020

Theory of screw dislocation strengthening in random BCC alloys from dilute to "High-Entropy" alloys

William Curtin, Francesco Maresca

Random body-centered-cubic (BCC) "High Entropy" alloys are a new class of alloys, some having high strength and good ductility at room temperature and some having exceptional high-temperature strength. There are no theories of strengthening of screw disloc ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Measurement and prediction of the transformation strain that controls ductility and toughness in advanced steels

Helena Van Swygenhoven, William Curtin, Francesco Maresca, Efthymios Polatidis

New-generation multi-phase martensitic steels derive their high strength from the body-centered cubic (BCC) phase and high toughness from transformation of the metastable face-centered cubic (FCC) austenite that transforms into martensite upon loading. In ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Origin of high strength in the CoCrFeNiPd high-entropy alloy

William Curtin, Binglun Yin

IMPACT STATEMENT Experiments and theory are highlighting chemical ordering in high-entropy alloys (HEAs) as important for mechanical properties but the high strength in CoCrFeNiPd is predicted here to be achievable in the random alloy due to the large misf ...

2020

Yield strength and misfit volumes of NiCoCr and implications for short-range-order

William Curtin, Binglun Yin

The face-centered cubic medium-entropy alloy NiCoCr has received considerable attention for its good mechanical properties, uncertain stacking fault energy, etc, some of which have been attributed to chemical short-range order (SRO). Here, we examine the y ...

Nature Research2020

Design using randomness: a new dimension for metallurgy

William Curtin

High entropy alloys add a new dimension, atomic-scale randomness and the associated scale-dependent composition fluctuations, to the traditional metallurgical axes of time-temperature-composition-microstructure. Alloy performance is controlled by the energ ...

2020

High entropy alloys: A focused review of mechanical properties and deformation mechanisms

William Curtin

The high-entropy alloy (HEA) concept was based on the idea that high mixing entropy can promote formation of stable single-phase microstructures. During the past 15 years, various alloy systems have been explored to identify HEA systems with improved prope ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Vanadium is an optimal element for strengthening in both fcc and bcc high-entropy alloys

William Curtin, Francesco Maresca, Binglun Yin

The element Vanadium (V) appears unique among alloying elements for providing high strengthening in both the fcc Co-Cr-Fe-Mn-Ni-V and bcc Cr-Mo-Nb-Ta-V-W-Hf-Ti-Zr high-entropy alloy families. The origin of Vanadium's special role is its atomic volume: larg ...

2020

Theory of double-kink nucleation in dilute BCC alloys

William Curtin, Alireza Ghafarollahi

Yielding in pure BCC metals and dilute substitutional alloys occurs by double-kink nucleation and propagation along screw dislocations. At low temperatures, the yield stress is controlled by double-kink nucleation. Here, an analytical statistical model is ...

PERGAMON-ELSEVIER SCIENCE LTD2020

First principles study of the effect of hydrogen in austenitic stainless steels and high entropy alloys

William Curtin, Xiao Zhou

Hydrogen (H) embrittlement in multicomponent austenitic alloys is a serious limitation to their application in many environments. Recent experiments show that the High-Entropy Alloy (HEA) CoCrFeMnNi absorbs more H than 304 Stainless Steel but is less prone ...

2020

Designing high ductility in magnesium alloys

William Curtin, Zhaoxuan Wu, Binglun Yin, Rasool Ahmad

The thermally activated pyramidal-to-basal (PB) transition of (c + a) dislocations, transforming glissile pyramidal dissociated core structures into sessile basal dissociated ones, lies at the origin of low ductility in pure magnesium (Mg). Solute-accelera ...

PERGAMON-ELSEVIER SCIENCE LTD2019

Combining experiments and modeling to explore the solid solution strengthening of high and medium entropy alloys

William Curtin, Céline Varvenne

The mechanical properties due to solid solution strengthening are explored within the single phase face-centered cubic (fcc) domain of the Co-Cr-Fe-Mn Ni high entropy alloy (HEA) system. This is achieved by combining an efficient and reproducible metallurg ...

2019

Stress-dependence of generalized stacking fault energies

William Curtin, Predrag Andric, Binglun Yin

2019

Lattice Green function methods for atomistic/continuum coupling: Theory and data-sparse implementation

Guillaume Anciaux, William Curtin, Max Ludwig Hodapp

2019

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