Publications de Haiqiang Deng | EPFL Graph Search

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The oxygen reduction reaction by decamethylferrocene (DMFc), triggered by hydrophilic metallic cations behaving as Lewis acids towards water molecules in a homogeneous organic phase reaction, was investigated using cyclic voltammetry at the water|1,2-dichl ...

Molecular oxygen and hydrogen peroxide reduction by 1,2-diferrocenylethane (DFcE) was investigated at a polarized water/1,2-dichloroethane (W/DCE) interface. The overall reaction points to a proton-coupled electron transfer (PCET) mechanism, where the firs ...

Herein, we present a simple microelectrode preparation methodology consisting in coating a platinum wire or a carbon fiber with a thin insulating Parylene C film (e.g. 1–10 μm), to produce SECM probes with a small and constant probe RG (i.e. ratio between ...

Single-emulsion toluene oil droplets (femtoliter) containing a hydrophobic redox probe that are dispersed in water stochastically collide with an ultramicroelectrode (UME). The fast-scan cyclic voltammetry (FSCV) or Fourier-transformed sinusoidal voltammet ...

The concept of artificial photosynthesis at a polarised liquid membrane is presented. It includes two photosystems, one at each interface for the hydrogen and oxygen evolution respectively. Both reactions involve proton coupled electron transfer reactions, ...

Gold nanoparticle (Au NP) mirrors, that exhibit both high reflectance and electrical conductance, were self-assembled at a [heptane + 1,2-dichloroethane]/water liquid/liquid interface. The highest reflectance, as observed experimentally and confirmed by fi ...

The present work describes the application of scanning electrochemical microscopy (SECM) in the feedback mode to determine the kinetics of oxygen reduction at or near the liquid/liquid interface – between water and 1,2-dichloroethane (w/DCE). The system co ...

Face to face: Flakes of reduced graphene oxide, synthesized in situ at the liquid/liquid interface from a graphene-oxide precursor, are capable of catalyzing the biphasic reduction of protons to hydrogen peroxide in the presence of molecular oxygen and an ...

The mechanism of the oxygen reduction reaction (ORR) at a liquid|liquid interface, employing ferrocene (Fc) derivatives – such as decamethylferrocene (DMFc) – as a lipophilic electron donor along with sulfuric acid as an aqueous proton source, was elucidat ...

Lithium cations are shown to have a significant role on catalyzing oxygen and proton reduction along with SN1 reactions in biphasic systems. We propose that this catalytic effect is due to the surprising acidity of the hydrated cations; interactions betwee ...

Haiqiang Deng

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Electrochemical oxygen reduction at soft interfaces catalyzed by the transfer of hydrated lithium cations

Oxygen and hydrogen peroxide reduction by 1,2-diferrocenylethane at a liquid/liquid interface

Parylene C Coated Microelectrodes For Scanning Electrochemical Microscopy

Single Organic Droplet Collision Voltammogram via Electron Transfer Coupled Ion Transfer

Artificial Photosynthesis at Soft Interfaces

Conductive Gold Nanoparticle Mirrors at Liquid/Liquid Interfaces

Kinetic differentiation of bulk/interfacial oxygen reduction mechanisms at/near liquid/liquid interfaces using scanning electrochemical microscopy

Oxygen Reduction at Soft Interfaces Catalyzed by In Situ-Generated Reduced Graphene Oxide

Oxygen Reduction at Soft Interfaces

Mechanism of oxygen reduction by metallocenes near liquid|liquid interfaces

Surprising acidity of hydrated lithium cations in organic solvents