Publications de Barnali Dutta | EPFL Graph Search

Chattez avec Graph Search

Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.

AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.

Investigations of ruthenium halfsandwich complexes have mostly focused on Cp and Cp* based derivatives due to the availability of easily accessible starting materials. However, it is interesting to have complexes with substituted cyclopentadienyl ligands i ...

RhCl3 is shown to mediate unusual coupling reactions of tert-butyl acetylene. When RhCl3(H2O)n was heated with four equivalents of tert-butyl acetylene in methanol, the dinuclear complex [{Rh(μ-Cl)(CH2tBu)(tBuC=CHCOCH2tBu)}2] (2) was isolated. A larger exc ...

Cyclopentadienyl-ruthenium half-sandwich complexes with 2-bound alkyne ligands have been suggested as catalytic intermediates in the early stages of Ru-catalyzed reactions with alkynes. We show that electronically unsaturated complexes of the formula [RuCl ...

The dimeric ruthenium complex Cp^RuCl2 is easily accessible in a one-pot reaction from RuCl3(solv)(n) and tert-butylacetylene. It features sterically very demanding "Cp-roof" ligands (Cp^ = eta(5)-1-methoxy-2,4-tert-butyl-3-neopentylcyclopentadienyl), ...

The water-sol. complexes [(Cp'OR)RuCl(PTA)2] (Cp'OR = h5-1-alkoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl; R = Me, Et; PTA = 1,3,5-triaza-7-phosphaadamantane) are considerably more cytotoxic (.apprx.2 orders of magnitude) than the cyclopentadienyl an ...

Barnali Dutta

Chattez avec Graph Search

Novel Ruthenium Complexes with Sterically Demanding Cyclopentadienyl Ligands : Syntheses, Reactivity and Catalytic Applications

RhCl3-Mediated Coupling Reactions of tert-Butyl Acetylene

Reactions of Alkynes with [RuCl(cyclopentadienyl)] Complexes: The Important First Steps

Contributions to the Chemistry of the Cyclopentadienyl Complex [Cp^RuCl2](2) ("Cp-roof" = eta(5)-1-Methoxy-2,4-tert-butyl-3-neopentylcyclopentadienyl)

Importance of the p-Ligand: Remarkable Effect of the Cyclopentadienyl Ring on the Cytotoxicity of Ruthenium PTA Compounds

Ruthenium Half-Sandwich Complexes with Sterically Demanding Cyclopentadienyl Ligands

Synthesis, Structure, and Reactivity of the Methoxy-Bridged Dimer [Cp^Ru(mu-OMe)]2 (Cp^ = 1-Methoxy-2,4-di-ter-butyl-3-neopentylcyclopentadienyl)

A New Coupling Reaction for the Synthesis of Ruthenium Halfsandwich Complexes with Sterically Demanding Cyclopentadienyl Ligands