Publications de Marinella Mazzanti

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Nuclear magnetic resonance suffers from an intrinsically low sensitivity, which can be overcome by dynamic nuclear polarization (DNP). Gd(III) complexes are attractive exogenous polarizing agents for magic angle spinning (MAS) DNP due to their high chemica ...

Complexes of uranium in low oxidation state have shown the ability to activate non-reactive small molecules such as N-2. However, the multi-electron transfer required for such activation remains limited in uranium chemistry. Here, we review our recent rese ...

Multimetallic cooperativity is believed to play a key role in the cleavage of dinitrogen to nitrides (N3-), but the mechanism remains ambiguous due to the lack of isolated intermediates. Herein, we report the reduction of the complex [K-2{[U-V(OSi((OBu)-Bu ...

Trinuclear molecular complexes of europium (II)and ytterbium(II) [Ln3{(Ph2SiO)2O}3(THF)6],1-Ln3L3(Ln = Euand Yb), supported by the dianionic tetraphenyl disiloxanediolateligand, were synthesized via protonolysis of the [Ln{N-(SiMe3)2}2(THF)2] complexes. In ...

The stabilization of uranyl(v) (UO21+) by Fe(ii) in natural systems remains an open question in uranium chemistry. Stabilization of UVO21+ by Fe(ii) against disproportionation was ...

Understanding the role of multimetallic cooperativity and of alkali ion-binding in the second coordination sphere is important for the design of complexes that can promote dinitrogen (N-2) cleavage and functionalization. Herein, we compare the reaction pro ...

The biological reduction of soluble U(VI) complexes to form immobile U(IV) species has been proposed to remediate contaminated sites. It is well established that multiheme c-type cytochromes (MHCs) are key mediators of electron transfer to aqueous phase U( ...

Gadolinium(III) complexes have recently been demonstrated to have potential as polarizing agents for high-field dynamic nuclear polarization (DNP) NMR spectroscopy. By tailoring the ligand design to reduce the zero-field splitting (ZFS), we demonstrate a q ...

The chemistry of actinide-nitrides has witnessed significant advances in the last ten years with a large focus on uranium and a few breakthroughs with thorium. Following the early discovery of the first terminal and bridging nitride complexes, various synt ...

The conversion of metal nitrides to NH3 is an essential step in dinitrogen fixation, but there is limited knowledge of the reactivity of nitrides with protons (H+). Herein, we report comparative studies for the reactions of H+ and NH3 with uranium nitrides ...

The preparation and characterization of a series of complexes of the Yb and Eu cations in the oxidation state II and III with the tetradentate N,O-donor tripodal ligands (tris(2-pyridylmethyl)amine (TPA), BPA(-) (HBPA=bis(2-pyridylmethyl)(2-hydroxybenzyl)a ...

The reaction of a terminal Mo(II) nitride with a U(III) complex yields an heterodimetallic U-Mo nitride which is the first example of a transition metal-capped uranium nitride. The nitride is triply bonded to U(V) and singly bonded to Mo(0) and supports a ...

Uranium-based compounds have been put forward as ideal candidates for the design of single-molecule magnets (SMMs) with improved properties, but to date, only two examples of exchange-coupled 3d-5f SMM containing uranium have been reported and both are bas ...

Among the 14 lanthanide elements (Ce-Lu), until recently, the tetravalent oxidation state was readily accessible in solution only for cerium while Pr(iv), Nd(iv), Dy(iv) and Tb(iv) had only been detected in the solid state. The triphenylsiloxide ligand rec ...

Multimetallic cooperative binding of heteroallenes provides an attractive route to their activation, but the reduction of CS2 at heterobimetallic sites, associating an electron-rich metal with a main group Lewis acid has not been explored. Here we show tha ...

The chemistry of lanthanides is limited to one electron transfer reactions due to the difficulty of accessing multiple oxidation states. Here we report that a redox-active ligand combining three siloxides with an arene ring in a tripodal ligand can stabili ...

Herein, we report the synthesis and characterisation of the first terminal uranium(V) sulfide and a related UV trithiocarbonate complex supported by sterically demanding tris(tert-butoxy)siloxide ligands. The reaction of the potassium-bound UV imido comple ...

Terminal uranium nitrides have so far proven impossible to isolate by photolysis of azides. Here we report the second ever example of an isolated terminal uranium(VI) nitride. We show that the terminal nitride [NBu4] [U(OSi((OBu)-Bu-t)(3))(4)(N)], 3, can b ...

Rigidtritopic linkers of different sizes were used to buildporous U-(IV) and Th-(IV) 3D frameworks. The charge of the polymerscould be tuned by reaction conditions such as the temperature, pH,solvent, ligand, or metal precursor, yielding a series of neutra ...

Dinitrogen cleavage provides an attractive but poorly studied route to the assembly of multimetallic nitride clusters. Here, we show that the monoelectron reduction of the dinitrogen complex [{U(OC6H2-Bu-3(t)-2,4,6)(3)}(2)(mu-eta(2):eta(2)-N-2)], 1, allows ...

Marinella Mazzanti

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Design Principles for the Development of Gd(III) Polarizing Agents for Magic Angle Spinning Dynamic Nuclear Polarization

Multi-electron Transfer by U(II) and Masked U(II) Complexes

Stepwise Reduction of Dinitrogen by a Uranium-Potassium Complex Yielding a U(VI)/U(IV) Tetranitride Cluster

Structure and Reactivity of Polynuclear Divalent Lanthanide Disiloxanediolate Complexes br

The mechanism of Fe induced bond stability of uranyl(v)

Dinitrogen cleavage by a dinuclear uranium(III) complex

Mechanism of Reduction of Aqueous U(V)-dpaea and Solid-Phase U(VI)-dpaea Complexes: The Role of Multiheme c-Type Cytochromes

A Factor Two Improvement in High-Field Dynamic Nuclear Polarization from Gd(III) Complexes by Design

Progress in the chemistry of molecular actinide-nitride compounds

Nitride protonation and NH3 binding versus N-H bond cleavage in uranium nitrides

Lanthanide(II) Complexes Supported by N,O-Donor Tripodal Ligands: Synthesis, Structure, and Ligand-Dependent Redox Behavior

Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer

Heterometallic Fe-2(II)-U-V and Ni-2(II)-U-V Exchange-Coupled Single-Molecule Magnets: Effect of the 3d Ion on the Magnetic Properties

Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

Isolation and redox reactivity of cerium complexes in four redox states

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide

Photochemical Synthesis of a Stable Terminal Uranium(VI) Nitride

Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids

Multimetallic Uranium Nitride Cubane Clusters from Dinitrogen Cleavage