Publications de Cédric Klein | EPFL Graph Search

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Ru(4,4-dicarboxylic acid-2,2'-bipyridine) (4,4'-bis(2-(4-(1,4,7,10-tetraoxyundecyl)phenyl)ethenyl)-2,2'-bipyridine) (NCS)(2), a new high molar extinction coefficient ion-coordinating ruthenium sensitizer was synthesized and characterized using H-1 NMR, Fou ...

Exploration of new ruthenium-based sensitizers for dye-sensitized solar cell (DSC) applications requires an easy access to multifunctionalized ligands for efficient screening of sensitizers' properties. Based on the Horner-Emmons-Wadsworth reaction, a conv ...

Citrazinic acid is used as a convenient starting material for both tridentate 2,6-di(pyrazol-1-yl)-pyridine and tetradentate 6,6'-di(pyrazol-1-yl)-2,2'-bipyridine ligands containing carboxylic groups useful for further anchoring of sensitizer on TiO2 for d ...

This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [C^N]2ML, comprising chelate monoionic ligands (L), also called ancillary ligands. It has been surprisingly found that when the ancillary ligand ...

A new Ru(II) complex, Bu4N [ruthenium (4-carboxylic acid-4'-carboxylate-2,2'-bipyridine)(4,4'-di(2-(3,6-dimethoxyphenyl)ethenyl)-2,2'-bipyridine)(NCS)2] (N945H), was synthesized and characterized by anal., spectroscopic, and electrochem. techniques. The ab ...

This invention relates to metal complexes, and the use of such complexes as an electro luminescent material. It also relates to a light-emitting device comprising such metal complexes, and to a method for manufacturing such a light-emitting ...

The present invention relates to novel pyridine compounds that can be used as anchoring ligands in metal-based sensitizing dyes of dye sensitized solar cells (DSCs). The dyes comprising the polypyridine compounds exhibit improved light harvesting ability a ...

A dye sensitized solar cell, comprising a heteroleptic polypyridil complex of Ru, Os or Fe. The donating ligand has an extended conjugated À-system increasing the light absorbance and keeing the LUMO energy level higher than that of the anchoring ligand. A ...

A simple mononuclear cyclometallated iridium(III) complex exhibits white photo- and electro-luminescence in the wavelength range from 440 to 800 nm, which originates from a single emitting excited state of mixed character. ...

A series of allyl-functionalized imidazolium salts are reported, including 1-allyl-3-ethylimidazolium iodide and 1-allyl-3-propylimidazolium iodide, which have m.ps. close to room temp. and show typical properties of supercooled fluids if heated above thei ...

We present two sensitizers, Ru(4,4'-dicarboxyvinyl)-2,2'-bipyridine)(4,4'-dinonyl-2,2'-bipyridine)(NCS)(2) (K9) and Ru(4,4'-dicarboxy(phenylethenyl)-2,2'-bipyridine)(4,4'-dinonyl-2,2'-bipyridine)(NCS)(2) (K23), which were synthesized and characterized by a ...

This invention pertains to light emitting materials comprising novel ortho-metalated transition metal complexes [C^N] 2 ML comprising two orthometalated ligands having imidazole moieties and an ancillary ligand of ²-diketonate type. It has been surprisingl ...

Cédric Klein

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High Molar Extinction Coefficient Ion-Coordinating Ruthenium Sensitizer for Efficient and Stable Mesoscopic Dye-Sensitized Solar Cells

Convenient synthesis of functionalized 4,4 '-disubstituted-2,2 '-bipyridine with extended pi-system for dye-sensitized solar cell applications

Convenient synthesis of tridentate 2,6-di(pyrazol-1-yl)-4-carboxypyridine and tetradentate 6,6 '-di(pyrazol-1-yl)-4,4 '-dicarboxy-2,2 '-bipyridine ligands

Structure/Function Relationships in Dyes for Solar Energy Conversion: A Two-Atom Change in Dye Structure and the Mechanism for Its Effect on Cell Voltage

Light-emitting material

DFT-INDO/S modeling of new high molar extinction coefficient charge-transfer sensitizers for solar cell applications

Electro luminescent metal complexes

Novel anchoring ligands for sensitizers of dye-sensitized photovoltaic devices

2,2 -Bipyridine ligand, sensitizing dye and dye sensitized solar cell

White-light phosphorescence emission from a single molecule: application to OLED

A Supercooled Imidazolium Iodide Ionic Liquid as a Low-Viscosity Electrolyte for Dye-Sensitized Solar Cells

High Molar Extinction Coefficient Ruthenium Sensitizers for Thin Film Dye-Sensitized Solar Cells

Light-emitting material

Design and synthesis of a novel anchoring ligand for highly efficient thin film dye-sensitized solar cells

Amphiphilic Ruthenium Sensitizer with 4,4'-Diphosphonic Acid-2,2'-bipyridine as Anchoring Ligand for Nanocrystalline Dye Sensitized Solar Cells

Controlling Phosphorescence Color and Quantum Yields in Cationic Iridium Complexes: A Combined Experimental and Theoretical Study

A High Molar Extinction Coefficient Sensitizer for Stable Dye-Sensitized Solar Cells

Engineering of a Novel Ruthenium Sensitizer and Its Application in Dye-Sensitized Solar Cells for Conversion of Sunlight into Electricity

Engineering of Efficient Phosphorescent Iridium complex for developing oxygen sensitive polymeric and nanostructured film

A High Molar Extinction Coefficient Charge Transfer Sensitizer and its Application in Dye Sensitized Solar Cell