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Shaik Mohammed Zakeeruddin

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Publications associées (534)

The influence of dye structure on charge recombination in dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Yuhang Liu

Replacing the nonyl groups on the solar cell dye Ru(4,4'-carboxylic acid-2,2'-bipyridine)-( 4,4'-dinonyl-2,2'-bipyridine)(NCS)(2) (Z-907) with amino groups results in a marked decrease in solar cell performance. This is despite the fact that the amino deri ...

2011

High-Efficiency Solid-State Dye-Sensitized Solar Cells: Fast Charge Extraction through Self-Assembled 3D Fibrous Network of Crystalline TiO2 Nanowires

László Forró, Michael Graetzel, Shaik Mohammed Zakeeruddin, Arnaud Magrez, Laurent Gabriel Félix Alexandre Stéphane Bungener, Jérémie Minh-Châu Brillet, Nicolas Tétreault, Rita Smajda, Endre Horvath, Thomas Moehl, Peng Wang

Herein, we present a novel morphology for solid-state dye-sensitized solar cells based on the simple and straightforward self-assembly of nanorods into a 3D fibrous network of fused single-crystalline anatase nanowires. This architecture offers a high roug ...

American Chemical Society2010

Doping a TiO2 Photoanode with Nb5+ to Enhance Transparency and Charge Collection Efficiency in Dye-Sensitized Solar Cells

Pascal Comte, Michael Graetzel, Shaik Mohammed Zakeeruddin, Aravind Kumar Chandiran

The optoelectronic properties of our benchmark nanocrystalline anatase TiO2 photoanode were modified by means of aliovalent doping with Nb5+. Even for a low doping level, the charge collection efficiency can be noticeably improved as a result of a higher e ...

American Chemical Society2010

High molecular extinction coefficient metal dyes

Michael Graetzel, Shaik Mohammed Zakeeruddin, Peng Wang

The present invention relates to novel compounds that are useful as ligands in organometallic dyes. More particularly, the invention relates to dyes comprising the compounds, said dyes being sensitizing dyes useful in solar cell technology. According to an ...

2010

Organic sensitizers

Michael Graetzel, Shaik Mohammed Zakeeruddin, Peng Wang, Hao Qin

The present invention relates to new organic sensitizer compounds and to photoelectric conversion devices, in particular dye-sensitised solar cells comprising the new sensitizers. The present invention also relates to flexible photoelectric conversion devi ...

2010

Synthesis, characterisation and biological properties of gold(iii) compounds with modified bipyridine and bipyridylamine ligands

Michael Graetzel, Shaik Mohammed Zakeeruddin, Rosario Scopelliti, Paul Joseph Dyson, Angela Casini, Mariam-Céline Diawara

Square planar gold(iii) complexes that contain functionalised bipyridine ligands of general formula [Au(NN)Cl2][PF6] [where NN = 2,2'-bipyridine, 4,4'-dimethyl-2,2'-bipyridine, 4,4'-dimethoxy-2,2'-bipyridine and 4,4'-diamino-2,2'-bipyridine] have been prep ...

Royal Society of Chemistry2010

Effect of heat and light on the performance of dye-sensitized solar cells based on organic sensitizers and nanostructured TiO2

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Jun Ho Yum

The dye-sensitized solar cells based on the functionalized organic sensitizer, 3-(5-(5-(4-(bis(4-(hexyloxy)-phenyl)amino)phenyl)thiophen-2-yl)thiophen-2-yl)-2-cyanoacrylic acid (D21L6) exhibit comparable stability to the ruthenium sensitizers under 60 degr ...

Elsevier2010

Efficient Electron Transfer and Sensitizer Regeneration in Stable π-Extended Tetrathiafulvalene-Sensitized Solar Cells

Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Joël Teuscher, Davide Di Censo, Sophie Wenger, Qianli Chen

The development of metal-free organic sensitizers is a key issue in dye-sensitized solar cell research. We report successful photovoltaic conversion with a new class of stable tetrathiafulvalene derivatives, showing surprising electrochemical and kinetic p ...

American Chemical Society2010

Molecular design of metal-free D–π-A substituted sensitizers for dye-sensitized solar cells

Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Joël Teuscher, Davide Di Censo, Mingkui Wang, Nuttapol Pootrakulchote, Leila Alibabaei, Yuxiang Yu

Novel donor-p-acceptor (D--A) dyes, coded as SD-1, SD-2 and SD-5, were designed and synthesized for dye-sensitized solar cells. All these dyes comprised the same donor and acceptor units while the oligo thiophene units were introduced as linkers between th ...

2010

Surface Molecular Quantification and Photoelectrochemical Characterization of Mixed Organic Dye and Coadsorbent Layers on TiO2 for Dye-Sensitized Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Xiaoqing Jiang

Different molecular layers on TiO2 were prepared by using the p-dimethylaniline triphenylamine based organic dye, D29, together with the coadsorbents decylphosphonic acid (DPA), dineohexyl bis(3,3-dimethylbutyl)phosphinic acid (DINHOP), and chenodeoxycholi ...

American Chemical Society2010

An organic redox electrolyte to rival triiodide/iodide in dye-sensitized solar cells

Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Mingkui Wang

Dye-sensitized solar cells (DSCs) have achieved impressive conversion efficiencies for solar energy of over 11% with an electrolyte that contains triiodide/iodide as a redox couple. Although triiodide/iodide redox couples work efficiently in DSCs, they suf ...

2010

Highly Efficient Mesoscopic Dye-Sensitized Solar Cells Based on Donor-Acceptor-Substituted Porphyrins

Michael Graetzel, Shaik Mohammed Zakeeruddin, Takeru Bessho

To dye for: A porphyrin chromophore, which is integrated into a donor-acceptor dye as a π-conjugated bridge (see picture), exhibits an unprecedented efficiency of 11 □ % when used as a photosensitizer in a double-layer TiO2 film. A greatly enhanced photovo ...

Wiley-VCH Verlag GmbH2010

Efficient and Stable Solid-State Dye-Sensitized Solar Cells Based on a High-Molar-Extinction-Coefficient Sensitizer

Michael Graetzel, Shaik Mohammed Zakeeruddin, Robin Humphry-Baker, Soo-Jin Moon, Mingkui Wang, Peng Wang

The high-molar-extinction-coefficient heteroleptic ruthenium aye, cis-Ru (4,4'-bis(5-octylthieno[3,2-b] thiophen-2-yl)-2,2'-bipyridine) (4,4'-dicarboxyl-2,2'-bipyridine) (NCS)(2), exhibits an AM 1.5 solar (100 mW cm(-2))-to-electric power-conversion effici ...

Wiley-Blackwell2010

CdSe quantum dot (QD) and molecular dye hybrid sensitizers for TiO2 mesoporous solar cells: working together with a common hole carrier of cobalt complexes

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin

Redox couples based on cobalt complexes were found to be effective in regenerating both inorganic CdSe quantum dot-and organic dye-sensitizers. The hybrid sensitizer composed of CdSe QD and ruthenium sensitizer (Z907Na) dye showed a maximum power conversio ...

Royal Society of Chemistry2010

Application of Cu(II) and Zn(II) coproporphyrins as sensitizers for thin film dye sensitized solar cells

Pascal Comte, Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Joël Teuscher, Davide Di Censo, Mingkui Wang, Leila Alibabaei

We synthesized the Cu(II) and Zn(II) complexes of the 2,7,12,17-tetrapropionic acid of 3,8,13,18-tetramethyl-21H,23H porphyrin (coproporphyrin-I) and successfully employed them as sensitizers in dye-sensitized solar cells. Copper(II) coproporphyrin-I exhib ...

Royal Society of Chemistry2010

A new family of substituted triethoxysilyl iodides as organic iodide sources for dye-sensitised solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mingkui Wang

This paper reports the synthesis and characterisation of a family of heterocyclic triethoxysilyl iodides of general formula, (EtO)(3)SiR2-(N+R1), where R-1 = -C5H11, -CH2C6H5 or -C16H33; N+ = pyrrolidinium or piperidinium; and R-2 = -(CH2)(3)- and -(CH2)(1 ...

Royal Society of Chemistry2010

Multi-walled carbon nanotubes functionalized by carboxylic groups: Activation of TiO2 (anatase) and phosphate olivines (LiMnPO4; LiFePO4) for electrochemical Li-storage

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ladislav Kavan, Florian Le Formal

Multi-walled carbon nanotubes functionalized by carboxylic groups, exhibit better affinity towards TiO2 (P90, Degussa) as compared to that of pristine nanotubes. Also the electrochemical performance of TiO2 is improved by nanotube networking, but the Li-st ...

Elsevier2010

Novel anchoring ligands for sensitizers of dye-sensitized photovoltaic devices

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Amaresh Mishra

The present invention relates to novel pyridine compounds that can be used as anchoring ligands in metal-based sensitizing dyes of dye sensitized solar cells (DSCs). The dyes comprising the polypyridine compounds exhibit improved light harvesting ability a ...

2010

D-π-A Sensitizers for Dye-Sensitized Solar Cells: Linear vs Branched Oligothiophenes

Michael Graetzel, Shaik Mohammed Zakeeruddin, Mingkui Wang, Sophie Wenger, Amaresh Mishra

Two donor-π-acceptor (D-π-A) dyes, coded as L-3T-DPA 1 and B-5T-DPA 2, were synthesized for application in dye-sensitized solar cells. These D-π-A sensitizers use diphenylamine as donor, an oligothiophene as π-bridge, and cyanoacrylic acid as an acceptor g ...

American Chemical Society2010

Ultrafast charge transfer through p-oligo(phenylene) bridges: effect of nonequilibrium vibrations

Serge Pelet, Bernard Wenger, Pascal Comte, Michael Graetzel, Jacques-Edouard Moser, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Joël Teuscher, Christophe Bauer

Electron transfers (ET) between a donor (D) and an acceptor (A) through a molecular bridge (B) are of great importance in biological systems, molecular electronics and molecular based light-energy conversion systems. Here, the back and the forward electron ...

Current Science Assoc // Indian Academy of Sciences2010

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