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Hubert Girault

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Publications associées (428)

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Mass Barcode Signal Amplification for Multiplex Allergy Diagnosis by MALDI-MS

Hubert Girault, Liang Qiao, Natalia Gasilova, Xiaoqin Zhong

A highly sensitive method based on mass-barcoded gold nanoparticles (AuNPs) and immunomagnetic separation has been developed for multiplex allergy diagnosis by MALDI mass spectrometry in a component-resolved manner. Different analytical probes were prepare ...

American Chemical Society2016

Simulations of the adsorption of ionic species at polarisable liquid liquid interfaces

Hubert Girault, Bin Su, Nicolas Eugster

The adsorption of ions at the interface between two immiscible electrolyte solutions (ITIES) is primarily controlled by the potential distribution across the interface, which in turn is influenced by the adsorption process. In the present paper, we simulat ...

2005

All-Vanadium Dual Circuit Redox Flow Battery for Renewable Hydrogen Generation and Desulfurisation

Hubert Girault, Pekka Eero Peljo, Heron Vrubel, Frédéric Gumy, Véronique Amstutz, Kathryn Ellen Toghill, Christopher Raymond Dennison

An all-vanadium dual circuit redox flow battery is an electrochemical energy storage system capable to function as a conventional battery, but also to produce hydrogen and perform desulfurization when surplus of electricity is available by chemical dischar ...

Royal Society of Chemistry2016

Melittin Adsorption and Lipid Monolayer Disruption at Liquid-Liquid Interfaces

Hubert Girault, Manuel Alejandro Méndez Agudelo, Yu Lu

Melittin, a membrane-active peptide with antimicrobial activity, was investigated at the interface formed between two immiscible electrolyte solutions (ITIES) supported on a metallic electrode. Ion-transfer voltammetry showed well-defined semi-reversible t ...

American Chemical Society2011

Ion current rectification and rectification inversion in conical nanopores: a perm-selective view

Hubert Girault, Fernando Cortes Salazar, Dmitry Momotenko

Ionic transport in charged conical nanopores is known to give rise to ion current rectification. The present study shows that the rectification direction can be inverted when using electrolyte solutions at very low ionic strengths. To elucidate these pheno ...

Royal Society of Chemistry2011

Decamethylruthenocene Hydride and Hydrogen Formation at Liquid|Liquid Interfaces

Hubert Girault, Pekka Eero Peljo, Manuel Alejandro Méndez Agudelo, Micheal Diarmaid Scanlon, Thomas James Stockmann, Lucie Josette Renée Rivier

The formation and the dissociation of metal hydrides are key steps within the hydrogen evolution reaction (HER) pathway for photochemical water splitting, but also impacts a wide range of other catalytic, industrial, and biochemical reactions. Herein, we d ...

American Chemical Society2015

Perspective Alkaline electrolyzers: Powering industries and overcoming fundamental challenges

Hubert Girault

For the sustainable development of the renewable hydrogen sector, alkaline electrolysis appears to be a technology of choice. Nevertheless, despite its long history that showed its reliability in the industrial field and despite the traditional belief from ...

Cell Press2024

Microscale total analysis system

Hubert Girault

The invention relates to an apparatus for performing chemical assays in an aqueous medium. The apparatus contains a reaction chamber(s) and a liquid in-flow channel connected to each chamber. The flow of liquid through the fluid in-flow channel to the reac ...

2005

How to polarise an interface with ions: the discrete Helmholtz model

Hubert Girault, Astrid Johana Olaya Avendano, Grégoire Clément Gschwend

The distribution of electrolytes in an electric field usually relies on theories based on the Poisson-Boltzmann formalism. These models predict that, in the case of a metallic electrode, ionic charges screen the electrode potential, leading to concentratio ...

2020

Point-of-care amperometric determination of L-dopa using an inkjet-printed carbon nanotube electrode modified with dandelion-like MnO2 microspheres

Hubert Girault, Andreas Stephan Lesch, Milica Jovic

An electrochemical sensor is described for the determination of L-dopa (levodopa; 3,4-dihydroxyphenylalanine). An inkjet-printed carbon nanotube (IJPCNT) electrode was modified with manganese dioxide microspheres by drop-casting. They coating was character ...

2019

The redox aspects of lithium-ion batteries

Hubert Girault

This article aims to present the redox aspects of lithium-ion batteries both from a thermodynamic and from a conductivity viewpoint. We first recall the basic definitions of the electrochemical potential of the electron, and of the Fermi level for a redox ...

ROYAL SOC CHEMISTRY2024

Variation of the Fermi level and the Electrostatic Force of a Metallic Nanoparticle upon Colliding with an Electrode

Hubert Girault, Pekka Eero Peljo

When a metallic nanoparticle (NP) comes in close contact with an electrode, its Fermi level equilibrates with that of the electrode if their separation is less than the cut-off distance for electron tunnelling. In the absence of chemical reactions in solut ...

Royal Soc Chemistry2017

Nanomaterial-assisted laser desorption ionization for mass spectrometry-based biomedical analysis

Hubert Girault, Liang Qiao

Nanomaterials have been widely used to assist laser desorption ionization of biomolecules for mass spectrometry analysis. Compared with classical matrix-assisted laser desorption ionization, strategies based on nanomaterial-assisted ionization generate a c ...

2010

Study of Amyloid beta-Peptide (A beta 12-28-Cys) Interactions with Congo Red and beta-Sheet Breaker Peptides Using Electrochemical Impedance Spectroscopy

Hubert Girault

A surface-based approach is presented to study the interactions of A beta 12-28-Cys assembled on gold surfaces with Congo red (CR) and a beta-sheet breaker (BSB) peptide. The various aspects of the peptide film have been examined using different electroche ...

American Chemical Society2012

Soft Microelectrode Linear Array for Scanning Electrochemical Microscopy

Hubert Girault, Andreas Stephan Lesch, Fernando Cortes Salazar, Gunther Wittstock, Dmitry Momotenko

A linear array of eight individual addressable microelectrodes has been developed in order to perform highthroughput scanning electrochemical microscopy (SECM) imaging of large sample areas in contact regime. Similar to previous reports, the soft microelec ...

American Chemical Society2010

Kinetics of Proteolytic Reactions in Nanoporous Materials

Hubert Girault, Liang Qiao, Hongyan Bi

Proteolysis with proteases preloaded within nanopores of porous material is a very fast process, where proteins can be digested in minutes compared to the conventional bulk enzyme reactions taking place over hours. To model this surprising phenomenon, a mo ...

American Chemical Society2009

Interfacial Photoreduction of Supercritical CO2 by an Aqueous Catalyst

Hubert Girault, Manuel Alejandro Méndez Agudelo, Patrick Voyame

Not just a solvent anymore: CO2 reduction under supercritical conditions was achieved in a biphasic water–supercritical CO2 system using an aqueous soluble catalyst (see picture). The introduction of such an interface provides a suitable reaction medium wh ...

Wiley-VCH Verlag GmbH2011

Role of Adsorbates on Dynamics of Hot-Electron (type I and II) Thermalization within Gold Nanoparticles

Hubert Girault, Jean-Pierre Abid, Christophe Bauer

Early stages of hot-electron thermalization in small gold nanoparticles wrapped in an adsorbates shell have been investigated by femtosecond transient absorption spectroscopy. Type-I hot electrons thermalize in 800 fs (to form type-II hot electron) either ...

Elsevier2006

Thin-Chip Microspray System for High-Performance Fourier-Transform Ion-Cyclotron Resonance Mass Spectrometry of Biopolymers

Hubert Girault, Joël Stéphane Rossier, Niels Erik Lion

Wiley-VCH Verlag GmbH2003

Ionic Partiton Diagram of the Zwitterionic Antihistamine Cetrizine

Hubert Girault, Pierre-Alain Carrupt

Wiley-VHCA AG2001