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Concept

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Publications associées (19)

Mapping orthorhombic domains with geometrical phase analysis in rare-earth nickelate heterostructures

Duncan Thomas Lindsay Alexander, Bernat Mundet

Most perovskite oxides belong to the Pbnm space group, composed of an anisotropic unit cell, A-site antipolar displacements, and oxygen octahedral tilts. Mapping the orientation of the orthorhombic unit cell in epitaxial heterostructures that consist of at ...

Aip Publishing2024

Micromechanics of oxide inclusions in ferrous alloys

Alejandra Inés Slagter

Oxide inclusions are inevitably present in steel as a direct consequence of the steelmaking process; as a result, a cubic centimetre of modern steel will generally contain about a million of these hard and brittle micrometre-sized ceramic particles. Inclus ...

EPFL2023

A method for the reliable and reproducible precipitation of phase pure high Ca/Si ratio (>1.5) synthetic calcium silicate hydrates (C-S-H)

Karen Scrivener, Paul Bowen, Maya Nicole Harris

Various methods have been developed to synthesize C-S-H; however, these methods have only allowed for the successful production of pure-phase C-S-H with Ca:Si of 1.5 or less. Attempts to form higher Ca:Si ratios by these methods gives C-S-H (Ca:Si 1.5 or l ...

Pergamon-Elsevier Science Ltd2022

A modern scleractinian coral with a two-component calcite–aragonite skeleton

Anders Meibom, Jaroslaw Hubert Stolarski

One of the most conserved traits in the evolution of biomineralizing organisms is the taxon-specific selection of skeletal minerals. All modern scleractinian corals are thought to produce skeletons exclusively of the calcium-carbonate polymorph aragonite. ...

2021

Ab Initio Molecular Dynamics Investigation of Molten Fe-Si-O in Earth's Core

James Badro

Silicon and oxygen are potential light elements in Earth's core because their stronger affinity to metal observed with increasing temperature posits that significant amounts of both can be incorporated into the core. It was proposed that an Fe-Si-O liquid ...

AMER GEOPHYSICAL UNION2019

An alternative model for the formation of hydrous Mg/Ni layer silicates ("deweylite"/"garnierite") in faulted peridotites of New Caledonia: II. Petrography and chemistry of white and green clay infillings

Gabrielle Dublet

This study, which complements a first mineralogical work, presents detailed petrographic and chemical data on the sequences of clay infillings commonly found in serpentine veins of reactivated faults from the New Caledonian peridotite formation. Chemical t ...

E SCHWEIZERBARTSCHE VERLAGSBUCHHANDLUNG2019

Geochemistry, geothermometry and influence of the concentration of mobile elements in the chemical characteristics of carbonate-evaporitic thermal systems. The case of the Tiermas geothermal system (Spain)

The Tiermas low temperature geothermal system, hosted in the Paleocene-Eocene carbonates of the Jaca-Pamplona basin, has been studied to evaluate the geochemistry and the temperature of the waters in the deep reservoir. These waters are of chloride-sodium ...

Elsevier Science Bv2017

Weekly to monthly time scale of melt inclusion entrapment prior to eruption recorded by phosphorus distribution in olivine from mid-ocean ridges

Anders Meibom, Stéphane Laurent Escrig, Lukas Baumgartner, Othmar Müntener

Melt inclusions (MIs) hosted in euhedral olivine have been proposed to represent droplets of primary melt, protected from processes occurring near Earth's surface during eruption. The complex zoning of phosphorus (P) in some olivines and the presence of a ...

Geological Soc Amer, Inc2017

Alkali uptake in calcium alumina silicate hydrate (C-A-S-H)

Karen Scrivener, Émilie Michèle L'Hôpital

Uptake of the alkalis K and Na by calcium silicate hydrate (C-S-H) and calcium alumina silicate hydrate (C-A-S-H) of molar Ca/Si ratios = 0.6 to 1.6 and molar Al/Si ratio = 0 or 0.05 has been studied at 20 degrees C. Alkalis are thought to be bound in the ...

Pergamon-Elsevier Science Ltd2016

Phase transition processes of olivine in the shocked Martian meteorite Tissint: Clues to origin of ringwoodite-, bridgmanite- and magnesiowilstite-bearing assemblages

Philippe Gillet

Tissint is a heavily shocked olivine-phyric shergottite. We investigated and documented several phase transformations and dissociation phenomena of olivine adjacent to and in many shock-induced melt-pockets of Tissint. Olivine grains entrained in the melt- ...

Elsevier2016

Crustal differentiation in the early solar system: Clues from the unique achondrite Northwest Africa 7325 (NWA 7325)

Philippe Gillet

The unique achondrite NWA 7325 is an unusual olivine gabbro composed chiefly of calcic plagioclase (An(85-93)), diopsidic pyroxene (En(50.1-54.0) Wo(44.8-49.3) Fs(0.6-1.3)), and forsteritic olivine (Fo(97)). It is Al and Mg-rich and Fe and Na-poor and disp ...

Pergamon-Elsevier Science Ltd2015

Partitioning of Si and platinum group elements between liquid and solid Fe-Si alloys

James Badro

Crystallization of the Earth's inner core fractionates major and minor elements between the solid and liquid metal, leaving physical and geochemical imprints on the Earth's core. For example, the density jump observed at the Inner Core Boundary (ICB) is re ...

Pergamon-Elsevier Science Ltd2014

An experimental model approach of biologically-assisted silicate dissolution with olivine and Escherichia coli - Impact on chemical weathering of mafic rocks and atmospheric CO2 drawdown

Philippe Gillet

Chemical weathering of Mg, Ca-silicates and alumino-silicates contributes significantly to the drawdown of atmospheric CO2 over long time scales. The present work focuses on how this mode of weathering may change in the presence of free-living bacteria in ...

Pergamon-Elsevier Science Ltd2013

Effects of Fe-enrichment on the equation of state and stability of (Mg,Fe)SiO3 perovskite

Susannah McGregor Dorfman

Fe-rich natural orthopyroxenes with compositions of (Mg0.61Fe0.38Ca0.01)SiO3 (Fe#38) and (Mg0.25Fe0.74Ca0.01)SiO3 (Fe#74) were studied at pressures up to 155 GPa and temperatures up to 3000 K. Single-phase orthorhombic GdFeO3-type perovskite was synthesize ...

Elsevier Science Bv2013

Shock-induced deformation of Shergottites: Shock-pressures and perturbations of magmatic ages on Mars

Philippe Gillet, Pierre Beck

Shergottites and Chassignites practiced major deformation effects whose nature, magnitude and relevance were controversially evaluated and disputatively debated. Our studies of many shocked shergottites present, contrary to numerous previous reports, ample ...

Pergamon-Elsevier Science Ltd2013

A systematic mapping procedure based on the Modified Gaussian Model to characterize magmatic units from olivine/pyroxenes mixtures: Application to the Syrtis Major volcanic shield on Mars

Harold Gabriel Eugène Justin Clenet

Clenet et al. (2011) have developed an adapted version of the Modified Gaussian Model (MGM). The improvements allow the characterization of spectra of olivine-pyroxene(s) mixtures, addressing both modal composition and individual minerals chemical composit ...

Amer Geophysical Union2013

Synthesis of Homogeneous Manganese-Doped Titanium Oxide Nanotubes from Titanate Precursors

László Forró, Arnaud Magrez, Kurt Schenk, Bálint Náfrádi, Endre Horvath, Zlatko Mickovic, Péter Szirmai, Rita Smajda, Dejan Dokic

We report a novel synthesis route of homogeneously manganese-doped TiO2 nanotubes in a broad concentration range. The scroll-type trititanate (H2Ti3O7) nanotubes prepared by hydrothermal synthesis were used as precursors. Mn2+ ions were introduced by an io ...

Amer Chemical Soc2013

Molecular wiring of LiMnPO4 (olivine) by ruthenium(II)-bipyridine complexes

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ladislav Kavan

LiMnPO4 (olivine) was surface-modified by two different complexes: Ru-bis(4,4'-diethoxycarbonyl-2,2'-bipyridine)(4,4'-dicarboxylate-2,2'-bipyridine) and Ru-bis(4-carboxylic acid-4'-carboxylate-2,2'-bipyridine)(4,4'-dinonyl-2,2'bipyridine). These complexes ...

Elsevier2009

Molecular wiring of LiFePO4 (Olivine)

Michael Graetzel, Ladislav Kavan

The carbon-free LiFePO4 (olivine) was modified by a monolayer coverage with [12-(2,5-di-tert-butyl-4-methoxy-phenoxy)-dodecyl]-phosphonic acid, coded DW. Thin film electrodes were bonded with 5% PVDF and deposited on F-doped SnO2 (FTO) support. The surface ...

2008