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Concept

Carbure

Publications associées (29)

Novel Alkynylation Methods through the Combination of Hypervalent Iodine Reagents and Alkynyl-trifluoroborate Salts

Julien Aymeric Borrel

The alkyne motif is a versatile functional group often encountered in organic chemistry. It can be involved in various transformations such as the alkyne-azide cycloaddition and has found widespread application in medicinal chemistry, chemical biology and ...

EPFL2024

Liquid metal infiltration of silicon based alloys into porous carbonaceous materials Part-III: Experimental verification of conversion products and infiltration depth by infiltration of Si-Zr alloy into mixed SiC/ graphite preforms

Ludger Weber, Caroline Hain, Manoj Kondibhau Naikade, Annapaola Parrilli

Porous carbonaceous preforms, made from graphite and silicon carbide (SiC) powders, with varying graphite powder mass fractions and particle sizes, were infiltrated at 1500 degrees C and 1700 degrees C by Si-8 at. pct Zr alloy to produce dense Si-Zr-SiC co ...

ELSEVIER SCI LTD2023

Highly Ordered and Thermally Stable FeRh Cluster Superlattice on Graphene for Low-Temperature Catalytic CO Oxidation

Harald Brune, Jean-Guillaume De Groot, Hao Yin

We report on bimetallic FeRh clusters with a narrow size-distribution grown on graphene on Ir(111) as a carbon-supported model catalyst to promote low-temperature catalytic CO oxidation. By combining scanning tunneling microscopy with catalytic performance ...

WILEY-V C H VERLAG GMBH2022

Strengthening mechanisms in dilute and random solid solution high-entropy BCC alloys

Alireza Ghafarollahi

Tuning the mechanical properties of metals, including strength, through adjusting the type and/or concentration of added solute elements, has been recognized as an effective way to design and produce materials with desired or optimized mechanical propertie ...

EPFL2022

Surface Oxygenate Species on TiC Reinforce Cobalt-Catalyzed Fischer-Tropsch Synthesis

Andreas Züttel, Wen Luo

Carbide-supported metal catalysts attract extensive research interests owing to the special properties of metal carbide and the interactions between metals and the carbide supports. While surface oxide species are inevitable in carbide materials, their rol ...

AMER CHEMICAL SOC2021

Processing and micro-mechanical characterization of multi-component transition MC carbides in iron

Andreas Mortensen, Léa Deillon, Goran Zagar, Marta Fornabaio, Lionel Michelet

We prepare multi-component transition monocarbides of chosen composition by arc-melting together a pre-alloy of the transition metals and cast iron. Based on the elements Ti, Ta, V, Nb and W, 51 different binary, ternary and quaternary compositions are pro ...

2021

APT/TEM characterization of the element segregation in ferritic/martensitic steels after irradiation in SINQ

Lijuan Cui

Ferritic /martensitic (FM) steels are among the most important materials in various nuclear applications. As radiation-induced segregation (RIS) is one of the major factors for embrittlement of nuclear materials, thereofre it is essential to study the RIS ...

EPFL2021

Photonic Flash Synthesis of Mo2C/Graphene Electrocatalyst for the Hydrogen Evolution Reaction

Hubert Girault, Danick Reynard, Bhawna Nagar

Nowadays, molybdenum carbides (Mo2C) represent alternative electrocatalysts to noble metal for the hydrogen evolution reaction (HER). Here, a fast and simple process is proposed for the fabrication of Mo2C-based electrocatalysts on a carbon cloth substrate ...

AMER CHEMICAL SOC2021

Stability of flexible thin-film metallization stimulation electrodes: analysis of explants after first-in-human study and improvement ofin vivoperformance

Silvestro Micera, Stanisa Raspopovic, Francesco Maria Petrini

Objective.Micro-fabricated neural interfaces based on polyimide (PI) are achieving increasing importance in translational research. The ability to produce well-defined micro-structures with properties that include chemical inertness, mechanical flexibility ...

2020

Patterns and driving forces of dimensionality-dependent charge density waves in 2H-type transition metal dichalcogenides

László Forró, Helmuth Berger

Charge density wave (CDW) is a startling quantum phenomenon, distorting a metallic lattice into an insulating state with a periodically modulated charge distribution. Astonishingly, such modulations appear in various patterns even within the same family of ...

Nature Research2020

Nature of native atomic defects in ZrTe5 and their impact on the low-energy electronic structure

Helmuth Berger, Oleg Yazyev, Ana Akrap, Shengnan Zhang

Over the past decades, investigations of the anomalous low-energy electronic properties of ZrTe5 have reached a wide array of conclusions. An open question is the growth method's impact on the stoichiometry of ZrTe5 samples, especially given the very small ...

AMER PHYSICAL SOC2020

Machine learning for metallurgy II. A neural-network potential for magnesium

William Curtin, Binglun Yin, Eleanor Yi Kei Mak, Markus Anthony Stricker

Interatomic potentials are essential for studying fundamental mechanisms of deformation and failure in metals and alloys because the relevant defects (dislocations, cracks, etc.) are far above the scales accessible to first-principles studies. Existing pot ...

2020

Improved Alkali Intercalation of Carbonaceous Materials in Ammonia Solution

László Forró, Bálint Náfrádi, Péter Szirmai, Ferenc Simon

Alkali-intercalated graphite compounds represent a compelling modification of carbon with significant application potential and various fundamentally important phases. The intercalation of graphite with alkali atoms (Li and K) using liquid ammonia solution ...

WILEY-V C H VERLAG GMBH2019

Solute/screw dislocation interaction energy parameter for strengthening in bcc dilute to high entropy alloys

William Curtin, Francesco Maresca, Alireza Ghafarollahi

Strengthening, i.e. increased stress required to move a dislocation, in dilute or complex alloys arises from the totality of the interaction energies between the solutes and an individual dislocation. Prevailing theories for strengthening in bcc alloys con ...

IOP PUBLISHING LTD2019

Studying the wettability of Si and eutectic Si-Zr alloy on carbon and silicon carbide by sessile drop experiments

Ludger Weber, Manoj Kondibhau Naikade

The contact angles of two different systems, molten silicon and a eutectic Si-8 at. pct Zr alloy and their evolution over timeon vitreous carbon and polycrystalline silicon carbide (SiC) substrates were investigated at 1500 degrees C under vacuum, as well ...

ELSEVIER SCI LTD2019

Dynamic wetting in pressure-infiltration of ceramic particle preforms by molten metal

Gionata Schneider

This thesis investigates the interaction between mechanically induced flow of a liquid metal into a porous solid, and kinetic effects at the triple line. The approach is experimental and focuses on metal-ceramic systems for which the literature gives value ...

EPFL2019

Defect Formation Energies of Interstitial C, Si, and Ge Impurities in beta-Ga2O3

Alfredo Pasquarello, Assil Bouzid

Formation energies of C, Si, and Ge defects in beta-Ga2O3 are studied through hybrid functional calculations. The interstitial defects of these elements generally occur at higher energies than their substitutional counterparts, but are more stable at low F ...

WILEY-V C H VERLAG GMBH2019

Correlation of microdistortions with misfit volumes in High Entropy Alloys

William Curtin

The yield strengths of High Entropy Alloys have recently been correlated with measured or computed picometer-scale atomic distortions. Here, the root mean square microdistortion in a multicomponent alloy is shown to be nearly proportional to the misfit-vol ...

PERGAMON-ELSEVIER SCIENCE LTD2019

Observation of methane filled hexagonal ice stable up to 150 GPa

Philippe Gillet, Richard Gaal, Livia Eleonora Bove Kado, Umbertoluca Ranieri

Gas hydrates consist of hydrogen-bonded water frameworks enclosing guest gas molecules and have been the focus of intense research for almost 40 y, both for their fundamental role in the understanding of hydrophobic interactions and for gas storage and ene ...

National Academy of Sciences2019

Mechanical properties of MC multimetallic carbides in steel

Lionel Michelet

Carbides constitute a class of materials used for many applications, where excellent mechanical properties, such as stiffness, hardness and fracture toughness, are required. The machining industry is a typical example where carbide are crucial materials. W ...

EPFL2018