Publications associées à Hydrazine

Promoting Persistent Superionic Conductivity in Sodium Monocarba-closo-dodecaborate NaCB11H12 via Confinement within Nanoporous Silica

Superionic phases of bulk anhydrous salts based on large cluster-like polyhedral (carba)borate anions are generally stable only well above room temperature, rendering them unsuitable as solid-state electrolytes in energy-storage devices that typically oper ...

AMER CHEMICAL SOC2021

Quantum Dynamics of H-2 and D-2 Confined in Hydrate Structures as a Function of Pressure and Temperature

Philippe Gillet, Richard Gaal, Livia Eleonora Bove Kado, Umbertoluca Ranieri

We present an extensive study of the quantum dynamics of molecular hydrogen trapped within the nanocavities of two hydrate structures at low temperatures, namely, clathrate structure II and filled ice structure Cl. By inelastic neutron scattering measureme ...

AMER CHEMICAL SOC2019

Organocatalytic Nucleophilic Addition of Hydrazones to Imines: Synthesis of Enantioenriched Vicinal Diamines

Jieping Zhu, Qian Wang, Yang Wang

In the presence of a catalytic amount of chiral phosphoric acid, nucleophilic addition of N-monosubstituted hydrazones to N-Boc imines affords differentially protected vicinal diamines in the form of b-amino N,N’-dialkyldiazenes in excellent yields with hi ...

Wiley-Blackwell2017

Highly dispersed cobalt oxides nanoparticles on activated carbon fibres as efficient structured catalysts for the transfer hydrogenation of m-nitrostyrene

Paul Joseph Dyson, Lioubov Kiwi, Oliver Anthony Beswick

The facile preparation of structured catalysts featuring highly-dispersed non-precious metal (Fe, Ni, Co) oxide nanoparticles stabilized within a super-microporous network of activated carbon fibres (ACF) is described. The catalyst morphology was controlle ...

Elsevier Science Bv2017

"Palladium-Catalyzed Diamination of Alkynes in Synthesis of Tetracycles" and "Copper-Catalyzed Cyanoalkylation of Unactivated Alkenes"

Minh Tu Ha

The thesis deals with the development of transition metal-catalyzed difunctionalization of alkenes and alkynes, which can be categorized into two major topics: (1) palladium-catalyzed diamination of alkynes for the synthesis of tetracycles; (2) copper-cata ...

EPFL2017

A Pyridine-Based Ligand with Two Hydrazine Functions for Lanthanide Chelation: Remarkable Kinetic Inertness for a Linear, Bishydrated Complex

Lothar Helm

To study the influence of hydrazine functions in the ligand skeleton, we designed the heptadentate HYD ligand (2,2',2 '',2 ''-(2,2'-(pyridine-2,6-diyl)bis(2-methylhydrazine-2,1,1-triyl)) tetraacetic acid) and compared the thermodynamic, kinetic, and relaxa ...

American Chemical Society2015

Preparation and medical use of triazenes

Kay Severin, Gregor Kiefer

The present invention relates to a novel method for preparing triazenes. Further, the invention relates to novel triazenes and the use of N2O for preparing a compound comprising a triazene group. Further, the invention relates to the use of the novel triaz ...

2015

Iron oxide nanoparticles supported on activated carbon fibers catalyze chemoselective reduction of nitroarenes under mild conditions

Lioubov Kiwi, Duncan Thomas Lindsay Alexander, Oliver Anthony Beswick

Highly dispersed iron oxide (Fe2O3) nanoparticles (NPs) have been immobilized on structured supports of activated carbon fibers (ACF). Systematic catalyst characterizations suggest that ACF-based catalysts remain ultra-microporous after Fe2O3 NPs (similar ...

Elsevier Science Bv2015

Fabrication of reduced graphene oxide hybrid materials that exhibit strong fluorescence

Paul Joseph Dyson, Zhaofu Fei

Fluorescent graphene-based materials have been prepared by a facile ion exchange route comprising the reaction of carboxylated, reduced graphene oxide (c-RGO) with fluorescent anthracene-modified imidazolium salts in water-ethanol solution. The resulting r ...

Royal Society of Chemistry2012