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Concept

Irreversible process

Publications associées (20)

Thermodynamic bounds on time-reversal asymmetry

Shiling Liang

Quantifying irreversibility of a system using finite information constitutes a major challenge in stochastic thermodynamics. We introduce an observable that measures the time-reversal asymmetry between two states after a given time lag. Our central result ...

Amer Physical Soc2023

Process modeling and integration of hydrogen and synthetic natural gas production in a kraft pulp mill via black liquor gasification

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

The black liquor gasification integrated to chemical plants has shown potential for reducing the process irreversibility and promoting the decarbonization of this industrial sector. In the integrated chemical plants proposed in this work, the purpose is co ...

Pergamon-Elsevier Science Ltd2023

Techno-economic and environmental analysis of methanol and dimethyl ether production from syngas in a kraft pulp process

François Maréchal, Daniel Alexander Florez Orrego

The conventional configuration of a pulp mill, in which black liquor is concentrated and burnt, is compared to the upgrading gasification routes for methanol (MeOH) or dimethyl ether (DME) co-production. To this end, various exergy-based and environmental ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Luminescent and electronic properties of perovskite solar cells

Brian Irving Carlsen

Perovskite solar cells show great promise to serve as an alternative for traditional silicon-based solar cells, however several problems present obstacles for their commercialization. Standard perovskite cells contain lead, which is toxic to humans and har ...

EPFL2022

80 K cryogenic stage for ice lithography

Danick Briand, Rubaiyet Iftekharul Haque, Jaemin Kim

We present a cryogenic system design and development for ice lithography. The cryo-stage is designed with embedded channels to allow direct liquid nitrogen flow, enabling fast cryogenic cooling, and low sample temperature. The stage cools down to 78.8 K in ...

ELSEVIER2022

Surface energy contributions to the work of infiltration in metal matrix composite processing

Andreas Mortensen, Gionata Schneider

The work needed to mechanically drive molten metal into a porous solid preform when producing a composite material by infiltration can significantly exceed the energy change required for thermodynamically reversible infiltration. We measure, by quantitativ ...

2021

Design and Development of Injectable, Tough and Intrinsically-Adhesive Hydrogels for Biomedical Applications

Peyman Karami

Despite the development of hydrogels with a wide range of mechanical properties, insufficient adhesion between these materials and biological surfaces limits their use in the biomedical applications. Most recent advancements in highly adhesive hydrogel sys ...

EPFL2021

Hydrodynamic dead zone in multiphase geophysical flows impacting a rigid obstacle

Xingyue Li

When a gravity-driven solid-fluid mixture, such as those in geophysical flows, hits a wall-like rigid obstacle, a metastable jammed zone called hydrodynamic dead zone (HDZ) may emerge. The unjammed-jammed transition of HDZ, controlled by the intricate inte ...

2021

Designing Singlet Fission Candidates from Donor-Acceptor Copolymers

Anne-Clémence Corminboeuf, Maria Fumanal Quintana, Sergio Vela Llausi, Jacob Terence Blaskovits

Singlet fission (SF) has demonstrated significant promise for boosting the power conversion efficiency (PCE) of solar cells. Traditionally, SF is targeted as an intermolecular process; however, its dependence on crystal packing makes molecular design diffi ...

AMER CHEMICAL SOC2020

SARS-CoV-2 Inhibition by Sulfonated Compounds

Francesco Stellacci, Matteo Gasbarri, Valeria Cagno

Severe acute respiratory syndrome-related coronavirus 2 (SARS-CoV-2) depends on angiotensin converting enzyme 2 (ACE2) for cellular entry, but it might also rely on attachment receptors such as heparan sulfates. Several groups have recently demonstrated an ...

2020

Non-equilibrium kinetics and trajectory thermodynamics of synthetic molecular pumps

Cristian Pezzato

A major goal in the design of synthetic molecular machines is the creation of pumps that can use the input of energy to transport material from a reservoir at low chemical potential to a different reservoir at higher chemical potential, thereby forming and ...

ROYAL SOC CHEMISTRY2020

Instability of p-i-n perovskite solar cells under reverse bias

Christophe Ballif, Sylvain Nicolay, Quentin Thomas Jeangros, Laura Ding, Florent Sahli, Chien-Jen Yang, Fan Fu, Arnaud Walter, Peter Joseph Fiala, Daniel Anthony Jacobs, Marion Solange Madeleine Dussouillez

Partial shading can trigger permanent damage in photovoltaic modules because the illuminated solar cells drive the shaded cells into reverse bias. Under reverse bias conditions, perovskite solar cells have been shown to degrade quickly due to processes tha ...

Royal Society of Chemistry2020

Unsteady Flow Numerical Simulations on Internal Energy Dissipation for a Low-Head Centrifugal Pump at Part-Load Operating Conditions

François Avellan, Xiaoran Zhao

Dredge pumps are usually operated at part-load conditions, in which the low-solidity centrifugal impeller could experience large internal energy dissipation, related to flow separation and vortices. In this study, SST k- and SAS-SST turbulence models were ...

2019

Exergetic, environmental and economic assessment of sugarcane first-generation biorefineries

François Maréchal, Daniel Alexander Florez Orrego

First generation ethanol (1G) contributes to the majority of the ethanol produced worldwide, predominantly centered on corn and sugarcane. Nevertheless, several issues are regularly highlighted concerning the long-term sustainability of this technology, in ...

2019

The morning commute in urban areas with heterogeneous trip lengths

Nikolaos Geroliminis, Raphael Ali Francis Lamotte

This paper investigates the equilibrium properties of the morning commute problem at the network level with heterogeneous trip lengths. Congestion is modeled with a Macroscopic Fundamental Diagram relating the space-mean speed of a network to the vehicular ...

2018

Hydro-mechanical analysis of gas transport in compacted bentonite: uncertainty modelling

Lyesse Laloui, Aldo Madaschi

In the last years, transport of gases in clay buffer materials for Engineered Barrier Systems (EBS) has been deeply investigated by many research programs in the framework of nuclear waste storage. At present state, the coupled hydromechanical models to an ...

TU Delft2018

Composite Double-Network Hydrogels To Improve Adhesion on Biological Surfaces

Dominique Pioletti, Pierre-Etienne Bourban, Christophe Moser, Andreas Schmocker, Azadeh Khoushabi, Peyman Karami, Céline Samira Wyss, Martin Broome

Despite the development of hydrogels with high mechanical properties, insufficient adhesion between these materials and biological surfaces significantly limits their use in the biomedical field. By controlling toughening processes, we designed a composite ...

2018

Mediatorless, Reversible Optical Nanosensor Enabled through Enzymatic Pocket Doping

Ardemis Anoush Boghossian, Vitalijs Zubkovs, Benjamin Paul Johanès Gabriel Lambert, Nils Schürgers

This study presents a reversible, mediatorless, near-infrared glucose sensor based on glucose oxidase-wrapped SWCNTs. A combination of fluorescence, absorption, and Raman spectroscopy measurements suggest a fluorescence enhancement mechanism based on local ...

Wiley-Blackwell2017

Combined Exergy Analysis and Energy Integration for the Optimization of Nitrogen Fertilizer Plants

François Maréchal, Daniel Alexander Florez Orrego, Shivom Sharma

Modern ammonia production plants are equipped with efficient energy integration networks able to recover an important fraction of the enthalpy of reaction released by the exothermic chemical systems. However, to fully supply the exergy demands of the highl ...

University of San Diego2017

The morning commute in urban areas with heterogeneous trip lengths

Nikolaos Geroliminis, Raphael Ali Francis Lamotte

2017