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Concept

Procédé Solvay

Publications associées (18)

In Situ Synthesis of CuxO/N Doped Graphdiyne with Pyridine N Configuration for Ammonia Production via Nitrate Reduction

Sophia Haussener, Jian Li, Roberto Valenza

Electroreduction of nitrate to ammonia provides an interesting pathway for wastewater treatment and valorization. Cu-based catalysts are active for the conversion of NO3− to NO2− but suffer from an inefficient hydrogenation process of NO2−. Herein, CuxO/N- ...

2024

The influence of the gas on the dynamics of cavitation bubbles

Davide Bernardo Preso

Cavitation bubbles, extensively investigated in fluid mechanics, present enduring challenges in hydraulic machinery, while holding considerable potential for practical applications in biomedicine and sonochemistry. Despite more than a century of research, ...

EPFL2023

Multi-time integration approach for combined pulp and ammonia production and seasonal CO2 management

François Maréchal, Daniel Alexander Florez Orrego, Meire Ellen Gorete Ribeiro Domingos

In this work, the gasification of the black liquor is proposed as an alternative ammonia production route. Due to the seasonal variation of the energy prices, a multi-time integration approach that combines different technologies and energy inputs is used ...

2023

Incremental financial analysis of black liquor upgraded gasification in integrated kraft pulp and ammonia production plants under uncertainty of feedstock costs and carbon taxes

François Maréchal, Meire Ellen Gorete Ribeiro Domingos

In this work, the conventional scenario of the black liquor (BL) concentration and combustion is compared with the BL upgrading gasification process for ammonia production. The chemical processes synthesis, modeling and simulation are performed by using As ...

Elsevier2022

Stepwise Reduction of Dinitrogen by a Uranium-Potassium Complex Yielding a U(VI)/U(IV) Tetranitride Cluster

Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Luciano Barluzzi, Nadir Jori

Multimetallic cooperativity is believed to play a key role in the cleavage of dinitrogen to nitrides (N3-), but the mechanism remains ambiguous due to the lack of isolated intermediates. Herein, we report the reduction of the complex [K-2{[U-V(OSi((OBu)-Bu ...

2021

High-resolution hybrid inversion of IASI ammonia columns to constrain US ammonia emissions using the CMAQ adjoint model

Athanasios Nenes

Ammonia (NH3) emissions have large impacts on air quality and nitrogen deposition, influencing human health and the well-being of sensitive ecosystems. Large uncertainties exist in the "bottom-up" NH3 emission inventories due to limited source information ...

Copernicus GmbH2021

Combined exergy analysis, energy integration and optimization of syngas and ammonia production plants: A cogeneration and syngas purification perspective

François Maréchal, Daniel Alexander Florez Orrego, Shivom Sharma

Modern ammonia production plants are equipped with efficient energy integration networks able to recover an important fraction of the waste heat exergy available throughout the chemical system. However, in order to drive the endothermic reforming reactions ...

ELSEVIER SCI LTD2020

Techno-economic comparison of green ammonia production processes

François Maréchal, Jan Van Herle, Ligang Wang

To reduce the fossil-fuel consumption and the impacts of conventional ammonia production on climate change, green ammonia production processes using green hydrogen need to be investigated. For commercial production scale, potential alternatives can be base ...

2020

Investigation of the use of Limestone Calcined Clay Cement (LC3) applied to Thailand

Wilasinee Hanpongpun

The replacement of clinker with supplementary cementitious materials (SCMs) is the most interesting solution to reduce the CO2 emissions from cement production. The abundant availability of clays, which have a sufficient amount of kaolinite content in Thai ...

EPFL2019

Evolution of nitrogen concentration and ammonia production in N-2-seeded H-mode discharges at ASDEX Upgrade

Olivier Sauter, Basil Duval, Richard Pitts, Timothy Goodman, Stefano Coda, Yann Camenen, Marco Wischmeier, Nicola Vianello, Federico Alberto Alfredo Felici, Cristian Sommariva, Laurie Porte, Alberto Bottino, Emiliano Fable, Antoine Pierre Emmanuel Alexis Merle, Andrea Scarabosio, Doohyun Kim, Haomin Sun, Dávid Wágner, Thomas Binderup Jensen

Ammonia formation was studied in a series of dedicated nitrogen seeded H-mode discharges at ASDEX Upgrade. The evolution of ammonia formation was investigated with a reference phase before the seeding, and a long, stable flat-top nitrogen-seeded phase. It ...

IOP Publishing Ltd2019

Improved Alkali Intercalation of Carbonaceous Materials in Ammonia Solution

László Forró, Bálint Náfrádi, Péter Szirmai, Ferenc Simon

Alkali-intercalated graphite compounds represent a compelling modification of carbon with significant application potential and various fundamentally important phases. The intercalation of graphite with alkali atoms (Li and K) using liquid ammonia solution ...

WILEY-V C H VERLAG GMBH2019

Small Molecule Activation by Multimetallic Uranium Complexes

Marta Falcone

The development of new processes for the selective and sustainable transformation of abundant small molecules constitutes one of the major research areas in inorganic and organometallic chemistry. These molecules as CO2, CO, N2 and H2 are abundant reservoi ...

EPFL2019

Characterizing the Effects of a “Switchable Water” Additive on the Aqueous Solubility of Small Molecules

Paul Joseph Dyson

“Switchable water” is an aqueous solution containing a water‐soluble amine additive that exhibits CO2‐switchable properties, such as large changes in ionic strength, by forming an ammonium bicarbonate salt. Switchable water has been used to reversibly “sal ...

2018

Catalytic amino acid production from biomass-derived intermediates

Paul Joseph Dyson, Ning Yan

Amino acids are the building blocks for protein biosynthesis and find use in myriad industrial applications including in food for humans, in animal feed, and as precursors for bio-based plastics, among others. However, the development of efficient chemical ...

National Academy of Sciences2018

Nitrogen reduction and functionalization by a multimetallic uranium nitride complex

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Lucile Sylvie Danielle Chatelain, Marta Falcone

Molecular nitrogen (N-2) is cheap and widely available, but its unreactive nature is a challenge when attempting to functionalize it under mild conditions with other widely available substrates (such as carbon monoxide, CO) to produce value-added compounds ...

2017

Composition and structure of Fe(III)-precipitates formed by Fe(II) oxidation in water at near-neutral pH: Interdependent effects of phosphate, silicate and Ca

Janet Gordon Hering

We studied the interdependent effects of phosphate, silicate and Ca on the formation of Fe(III)-precipitates by oxidation of 0.5 mM Fe(II) in near-neutral bicarbonate-buffered aqueous solutions at concentrations relevant for natural water resources. Comple ...

Pergamon-Elsevier Science Ltd2015

Boron nitride multiwall nanotubes decorated with BN nanosheets

Pierre Stadelmann

We report a simple chemical-route to BN multiwall nanotubes decorated with nanosheets. These nanostructures have been prepared on a large scale from a simple unique chemical process under an ammonia flow onto the surface of an alumina substrate, using carb ...

2011

Link between Alginate Reaction Front Propagation and General Reaction Diffusion Theory

Jürgen Brugger, Philippe Renaud, Thomas Michael Braschler, Ana Valero, Kristopher Pataky, Ludovica Colella

We provide a common theoretical framework reuniting specific models for the Ca2+-alginate system and general reaction diffusion theory along with experimental validation on a microfluidic chip. As a starting point, we use a set of nonlinear, partial differ ...

2011