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Concept

Ammoniaque

Publications associées (26)

Development of a magnetic calcium-alginate hydrogel-sphere encapsulated with Fe-Mn-Zr ternary metal composite for heavy metal adsorption

Xinyi Huang

Heavy metal contamination has become one of the greatest global environmental problems. In this study, a magnetic calcium-alginate hydrogel-sphere encapsulated with Fe-Mn-Zr ternary-metal composite (MCHETC) was prepared through a combined co-precipitation ...

2023

Salt Bridge Structure of Microhydrated Arginine Kinetically Trapped in the Gas Phase by Evaporative Cooling

Oleg Boyarkine, Andrei Zviagin

Aminoacids and peptides generally exhibit zwitterionic forms withsalt bridge (SB) structures in solution but charge-solvated (CS) motifsin the gas phase. Here, we report a study of non-covalent complexesof the protonated amino acid arginine, ArgH(+)(H2O)( ...

2023

The influence of the gas on the dynamics of cavitation bubbles

Davide Bernardo Preso

Cavitation bubbles, extensively investigated in fluid mechanics, present enduring challenges in hydraulic machinery, while holding considerable potential for practical applications in biomedicine and sonochemistry. Despite more than a century of research, ...

EPFL2023

Visible-light driven water oxidation and oxygen production at soft interfaces

Hubert Girault, Astrid Johana Olaya Avendano, Jorge Gustavo Uranga, Julieta Soledad Riva

The visible light driven water oxidation reaction (WOR) by the organic electron acceptor 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-quinodimethane (TCNQF(4)) was studied at the water|butyronitrile interface. The WOR was performed at neutral pH, and without any ...

Royal Society of Chemistry2022

Weakening effect of various pore fluids on the tensile strength of granite

Guanyi Lu

Laboratory three-point bending experiments are carried out to evaluate the effect of various fluids on the tensile strength of granite. The granite specimens were tested under both dry and saturated conditions. The fluids used to saturate the granite inclu ...

SPRINGER HEIDELBERG2022

In Situ Monitoring of the Surface Evolution of a Silver Electrode from Polycrystalline to Well-Defined Structures

Yunchang Liang

Capturing the surface-structural dynamics of metal electrocatalysts under certain electrochemical environments is intriguingly desired for understanding the behavior of various metal-based electrocatalysts. However, in situ monitoring of the evolution of a ...

AMER CHEMICAL SOC2022

Aging of industrial Fe-zeolite based catalysts for nitrous oxide abatement in nitric acid production plants

Oliver Kröcher, Davide Ferri, Filippo Buttignol, Pierdomenico Biasi

The influence of hydrothermal aging on the structural and catalytic properties of two commercial Fe-exchanged zeolite catalysts (Fe-FER and Fe-ZSM-5) in the extruded form employed for the removal of N2O from the exhaust of nitric acid production plants has ...

ROYAL SOC CHEMISTRY2022

Super adsorption performance of carboxymethyl cellulose/copper oxide-nickel oxide nanocomposite toward the removal of organic and inorganic pollutants

Shaik Mohammed Zakeeruddin

A novel nanocomposite bead based on polymeric matrix of carboxymethyl cellulose and copper oxide-nickel oxide nanoparticles was synthesized, characterized, and applied for adsorptive removal of inorganic and organic contaminants at trace level of part per ...

SPRINGER HEIDELBERG2021

Performance Analysis of Ammonia in Solid Oxide Fuel Cells

Jan Van Herle, Suhas Nuggehalli Sampathkumar

Ammonia (NH3) has 17.8 wt% hydrogen and is easily liquified at 25°C and 8 bar pressure. Ammonia is carbon-free and can be produced sustainably at large scale and low cost. Solid oxide fuel cells generate electricity with efficiencies greater than 60% and c ...

ECS2021

A Highly Water-Stable meta-Carborane-Based Copper Metal-Organic Framework for Efficient High-Temperature Butanol Separation

Kyriakos Stylianou, Arunraj Chidambaram

Biofuels are considered sustainable and renewable alternatives to conventional fossil fuels. Biobutanol has recently emerged as an attractive option compared to bioethanol and biodiesel, but a significant challenge in its production lies in the separation ...

AMER CHEMICAL SOC2020

Direct observation of water-mediated single-proton transport between hBN surface defects

Aleksandra Radenovic, Ahmet Avsar, Evgenii Glushkov, Jean Camille Benjamin Comtet

Super-resolution microscopy of defects in a two-dimensional material unveils the transport of single proton charges at solid/water interfaces. Aqueous proton transport at interfaces is ubiquitous and crucial for a number of fields, ranging from cellular tr ...

2020

Using High-Temporal-Resolution Ambient Data to Investigate Gas-Particle Partitioning of Ammonium over Different Seasons

Athanasios Nenes

Ammonium is one of the dominant inorganic water-soluble ions in fine particulate matter (PM2.5). In this study, source apportionment and thermodynamic equilibrium models were used to analyze the relationship between pH and the partitioning of ammonium (eps ...

AMER CHEMICAL SOC2020

Improved Alkali Intercalation of Carbonaceous Materials in Ammonia Solution

László Forró, Bálint Náfrádi, Péter Szirmai, Ferenc Simon

Alkali-intercalated graphite compounds represent a compelling modification of carbon with significant application potential and various fundamentally important phases. The intercalation of graphite with alkali atoms (Li and K) using liquid ammonia solution ...

WILEY-V C H VERLAG GMBH2019

Optimizing Mesostructured Silver Catalysts for Selective Carbon Dioxide Conversion into Fuels

Sophia Haussener, Silvan Suter

Mesostructured silver catalysts have shown a substantial rise in reaction selectivity for the conversion of CO2 into fuels with increasing thickness of ordered, inverse-opal films. The challenge lies in the optimization of the morphology to maximize the CO ...

2019

Small Molecule Activation by Multimetallic Uranium Complexes

Marta Falcone

The development of new processes for the selective and sustainable transformation of abundant small molecules constitutes one of the major research areas in inorganic and organometallic chemistry. These molecules as CO2, CO, N2 and H2 are abundant reservoi ...

EPFL2019

Catalytic valorization of the acetate fraction of biomass to aromatics and its integration into the carboxylate platform

Jeremy Luterbacher, Benjamin Pierre Le Monnier, Masoud Talebi Amiri, Ydna Marie Questell-Santiago, Jher Hau Yeap, Bartosz Rozmyslowicz

In many plant species, the acetate fraction is the fourth most prominent fraction by weight after cellulose, hemicellulose and lignin, and can be easily extracted as a single stable molecule, acetic acid, at high yields. Despite this, upgrading the acetate ...

2019

Mechanistic implications of lanthanum-modification on gold-catalyzed formic acid decomposition under SCR-relevant conditions

Oliver Kröcher, Davide Ferri

The use of formate-based ammonia precursors as alternatives to urea in the selective catalytic reduction (SCR) process requires that formic acid released upon their thermolysis in the hot exhaust is rapidly decomposed to carbon dioxide. This work aims at t ...

ELSEVIER SCIENCE BV2019

Energy and orientation independence of the channel branching in Ne* + ND3 chemi-ionisation

Andreas Osterwalder, Sean Dennis Steven Gordon

Collisions of excited neon atoms with ammonia molecules can lead to two reaction processes, dissociative ionisation and Penning ionisation. Both processes result in the ionisation of the ammonia molecule and redistribution of the electronic energy into the ...

2019

Characterizing the Effects of a “Switchable Water” Additive on the Aqueous Solubility of Small Molecules

Paul Joseph Dyson

“Switchable water” is an aqueous solution containing a water‐soluble amine additive that exhibits CO2‐switchable properties, such as large changes in ionic strength, by forming an ammonium bicarbonate salt. Switchable water has been used to reversibly “sal ...

2018

Additive free, room temperature direct homogeneous catalytic carbon dioxide hydrogenation in aqueous solution using an iron(II) phosphine catalyst

Gabor Laurenczy, Mickael Montandon-Clerc

The negative consequences of the global warming require an important reduction of CO2 emission; and the valorization of the carbon dioxide, its transformation into useful chemicals is essential. We present here our studies on the direct CO2 hydrogenation r ...

2018