Mediaspace scheduled maintenance: Aug 25, 2026 07:00 - 12:00 AM. During this time, videos will be temporarily unavailable. Check status updates.

Concept

Ion oxonium

Publications associées (13)

Gentle nano-electrospray ion source for reliable and efficient generation of microsolvated ions

Oleg Boyarkine, Vladimir Kopysov, Andrei Zviagin

We present herein the design of a nano-electrospray ion source capable of reliable generation of large quantities of microsolvated ions. The source is based on a triple molecular skimmer scheme and can be quickly tuned to generate bare ions or their ionic ...

AIP Publishing2022

Resolving the charging paradox of neat oil droplets in water

Sergey Kulik

The thesis covers the series of questions regarding the molecular structure and charge of oil nanodroplets in water. This work proposes a mechanism responsible for the stabilization of oil nanodroplets in water, which does not involve OH- adsorption. First ...

EPFL2022

Cyclometalated Ir(III) complexes as tuneable multiband light sources for optical multisensor systems: Feasibility study

Anastasia Gitlina

Development of novel analytical devices complying with modern requirements of simplicity and cost-effectiveness is an important task. Multisensor systems based on various types of chemical sensors are promising tools in this respect. Herein the development ...

2020

Charge transfer dynamics in Ar+ + CO

Eduardo Carrascosa Casado

Differential cross sections for the charge transfer reaction between Ar(+)and CO have been measured using three-dimensional velocity map imaging in a crossed beam setup at the two relative collision energies 0.55 and 0.74 eV. We find dominant forward scatt ...

Taylor & Francis2020

Investigation of the low-energy stereodynamics in the Ne(3P2) + N2, CO reactions

Andreas Osterwalder, Junwen Zou

We report on an experimental investigation of the low-energy stereodynamics of the energy transfer reactions Ne(3P2) + X, producing Ne(1S) + X+ and [Ne–X]+ (X = N2 or CO). Collision energies in the range 0.2 K–700 K are obtained by using the merged beam te ...

2020

Lewis acid Catalyzed Annulations of Donor-Acceptor Aminocyclopropanes and Aminocyclobutanes

Sophie Lucie Racine

Organic molecules are indispensable have greatly contributed to the confort of our modern life. Nevertheless, humanity is facing now new challenges such as environmental issues and emerging drug resistances. In order to solve these major concerns, chemists ...

EPFL2016

Investigation of the water exchange mechanism of the Plutonyl(VI) and Uranyl(VI) ions with quantum chemical methods

François Rotzinger, Antonio Prlj

The water exchange reactions of PuO2(OH2)(5) and UO2(OH2)(5) were investigated with density functional theory (DFT) and wave function theory (WFT). Geometries and vibrational frequencies were calculated with DFT and CPCM hydration. The electron ...

Taylor & Francis2015

On the use of electron capture rate constants to describe electron capture dissociation mass spectrometry of peptides

Yury Tsybin, Konstantin Zhurov, Aleksey Vorobyev, Unige Anna Laskay

Electron capture dissociation (ECD) tandem mass spectrometry (MS/MS) is a powerful analytical tool for peptide and protein structure analysis. The product ion abundance (PIA) distribution in ECD MS/MS is known to vary as a function of electron irradiation ...

Im Publications2015

The Role of Quantum Effects on Structural and Electronic Fluctuations in Neat and Charged Water

Michele Ceriotti, Federico Giberti

In this work, we revisit the role of nuclear quantum effects on the structural and electronic properties of the excess proton in bulk liquid water using advanced molecular dynamics techniques. The hydronium ion is known to be a weak acceptor of a hydrogen ...

Amer Chemical Soc2014

Novel Approaches in Tandem Mass Spectrometry for Peptide and Protein Structure Analysis

Aleksey Vorobyev

Results of the mechanistic studies of free-electron based fragmentation methods addressing peptide and protein structure analysis with mass spectrometry (MS), electron capture dissociation (ECD) and electron ionization dissociation (EID), are presented. Se ...

EPFL2012

Voltammetric determination of extreme standard Gibbs ion transfer energy

Hubert Girault, Fernando Cortes Salazar, Manuel Alejandro Méndez Agudelo, Astrid Johana Olaya Avendano

A voltammetric methodology to determine the standard Gibbs energy of transfer of highly hydrophobic and hydrophilic ions has been developed. The electrochemical cell used includes a water|1,2-dichloroethane micro-interface supported on a microhole in a thi ...

Elsevier2010

Separation of the Oxide and Halide Part in the Oxohalide Fe3Te3O10Cl Due to High Lewis Acidity of the Cations

Helmuth Berger, Dong Zhang

A new iron tellurite halide Fe3Te3O10Cl has been identified that crystallizes in the monoclinic space group P2(1)/c. The crystal structure comprises channels where the Cl ions and also the stereochemically active lone-pair electrons on Te4+ are located. Th ...

2009

Synthesis, structures and characterisations of truly homoleptic acetonitrile Ln3+ complexes in solid state and in solution

Rosario Scopelliti, Lothar Helm, Ines Raabe

Total halide abstraction from LnCl3 by Ag[Al(OC(CF3)3)4]/CH3CN has been confirmed for a series of lanthanide metal ions by the structural characterization of [Ln(CH3CN)n][Al(OC(CF3)3)4]3 (n = 9, Ln3+ = Nd, Eu, Gd, Dy; n = 8, Ln3+ = Tm) complexes. Evidence ...

2009