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Concept

Polychlorodibenzo-p-dioxine

Publications associées (19)

Molecular imine cages with π-basic Au3(pyrazolate) faces

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Noga Eren

One tetrahedral and two trigonal prismatic cages with π-basic Au3(pyrazolate)3 faces were obtained by connection of pre-formed gold complexes via dynamic covalent imine chemistry. The parallel arrangement of the Au3(pyrazolate)3 complexes in the prismatic ...

2024

Chlorination of arenes via the degradation of toxic chlorophenols

Paul Joseph Dyson, Mingyang Liu, Xuemei Yang

Aryl chlorides are among the most versatile synthetic precursors, and yet inexpensive and benign chlorination techniques to produce them are underdeveloped. We propose a process to generate aryl chlorides by chloro-group transfer from chlorophenol pollutan ...

2022

Biochar and environmental sustainability: Emerging trends and techno-economic perspectives

Edgard Gnansounou

Environmental pollutants including emerging contaminants are a growing concern worldwide. Organic wastes, such as food waste, compost, animal manure, crop residues, and sludge are generally used as feedstock. The conventional treatment methodologies (prima ...

Elsevier2021

Occurrence of organic micropollutants and human health risk assessment based on consumption of Amaranthus viridis, Kinshasa in the Democratic Republic of the Congo

Florian Frédéric Vincent Breider, Dominique Grandjean

The contamination of water resource and food chain by persistent organic pollutants (POPs) constitutes a major environmental and human health concern worldwide. The aim of this study was to investigate the levels of POPs in irrigation water, soil and in Am ...

2020

Chlorination of Phenols Revisited: Unexpected Formation of α,β-Unsaturated C4-Dicarbonyl Ring Cleavage Products

Urs von Gunten

Despite decades of research on the fate of phenolic compounds when water is disinfected with hypochlorous acid (HOCl), there is still considerable uncertainty regarding the formation mechanisms and identity of ring cleavage products, especially at higher c ...

2020

Heavy metals and persistent organic pollutants contamination in river, estuary, and marine sediments from Atlantic Coast of Democratic Republic of the Congo

Florian Frédéric Vincent Breider, Dominique Grandjean

The pollution assessment and the evaluation of potential risks in the Atlantic Coastal Region of the Democratic Republic of the Congo are still very limited. Consequently, the present study investigates for the first time the concentrations of heavy metals ...

Springer2020

Indirect Evidence Link PCB Dehalogenation with Geobacteraceae in Anaerobic Sediment-Free Microcosms

Christof Holliger, Luiz Felippe De Alencastro, Pierre Rossi, Martina Praveckova

Although polychlorinated biphenyls (PCBs) production was brought to a halt 30 years ago, recalcitrance to degradation makes them a major environmental pollutant at a global scale. Previous studies confirmed that organohalide-respiring bacteria (OHRB) were ...

Frontiers Media SA2016

An in-situ assessment of low-density polyethylene and silicone rubber passive samplers using methods with and without performance reference compounds in the context of investigation of polychlorinated biphenyl sources in rivers

Luiz Felippe De Alencastro, Nicolas Estoppey, Adrien Schopfer

This study firstly aims to assess the field performances of low density polyethylene (LDPE) and silicone rubber (SR) samplers for the monitoring of polychlorinated biphenyls (PCBs) in water regarding the uptake, the sam- pling rate (RS) estimated by using ...

Elsevier Science Bv2016

Low density polyethylene (LDPE) passive samplers for the investigation of PCB point sources in rivers

Luiz Felippe De Alencastro, Julien Omlin, Nicolas Estoppey, Adrien Schopfer

This study aims to provide a passive sampling approach which can be routinely used to investigate polychlorinated biphenyl (PCB) sources in rivers. The approach consists of deploying low density polyeth- ylene (LDPE) strips downstream and upstream of poten ...

Pergamon-Elsevier Science Ltd2015

Divergent PCB organohalide-respiring consortia enriched from the efflux channel of a former Delor manufacturer in Eastern Europe

Christof Holliger, Luiz Felippe De Alencastro, Pierre Rossi, Martina Praveckova

Polychlorinated biphenyl (PCB) organohalide-respiring communities from the efflux channel of a former Delor manufacturer in Eastern Slovakia were assessed using metagenomic, statistical and cultivation-adapted approaches. Multivariate analysis of environme ...

Elsevier2015

GCxGC Quantification of Priority and Emerging Nonpolar Halogenated Micropollutants in All Types of Wastewater Matrices: Analysis Methodology, Chemical Occurrence, and Partitioning

Jeremy Samuel Arey, Jonas Gros, Rebecca Rutler, Petros Dimitriou Christidis, Saer Samanipour, Alex Bonvin

We report the development and validation of a method to detect and quantify diverse nonpolar halogenated micropollutants in wastewater treatment plant (WWTP) influent, effluent, primary sludge, and secondary sludge matrices (including both the liquid and p ...

Amer Chemical Soc2015

Effect of water velocity on the uptake of polychlorinated biphenyls (PCBs) by silicone rubber (SR) and low-density polyethylene (LDPE) passive samplers. An assessment of the efficiency of performance reference compounds (PRCs) in river-like flow conditions

Luiz Felippe De Alencastro, Julien Omlin, Nicolas Estoppey, Adrien Schopfer

One aim of this study is to determine the impact of water velocity on the uptake of indicator polychlorinated biphenyls (iPCBs) by silicone rubber (SR) and low-density polyethylene (LDPE) passive samplers. A second aim is to assess the efficiency of perfor ...

Elsevier Science Bv2014

Trace metals and persistent organic pollutants in sediments from river-reservoir systems in Democratic Republic of Congo (DRC): Spatial distribution and potential ecotoxicological effects

Luiz Felippe De Alencastro, Dominique Grandjean

This paper discusses the occurrence and spatial distribution of metals and persistent organic pollutants (POPs: including organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), Polybrominated diphenyl ethers (PBDEs), and polycyclic aromatic hy ...

Elsevier2014

An evolutionarily conserved role for the aryl hydrocarbon receptor in the regulation of movement

Johan Auwerx, Bart Deplancke, Laurent Mouchiroud, Evan Graehl Williams, Pénélope Andreux, Michael Vincent Frochaux

The BXD genetic reference population is a recombinant inbred panel descended from crosses between the C57BL/6 (B6) and DBA/2 (D2) strains of mice, which segregate for about 5 million sequence variants. Recently, some of these variants have been established ...

Public Library of Science2014

Integrated toxicity evaluation of a pulp deposit using organisms of different trophic levels

In order to assess possible adverse effects originating from pulp deposits in a Swiss lake, a sediment quality triad approach was applied with chemical, ecotoxicological and ecological assessment methods. To obtain an integrative picture of the potential e ...

Springer Heidelberg2013

Organic pollutants in compost and digestate. Part 2. Polychlorinated dibenzo-p-dioxins, and -furans, dioxin-like polychlorinated biphenyls, brominated flame retardants, perfluorinated alkyl substances, pesticides, and other compounds

Joseph Tarradellas, Rahel Christine Brändli

Compost and digestate are important recycling fertilizers and have beneficial effects on soil parameters. However, they can contain significant amounts of organic pollutants. Here, the first comprehensive data set on dibenzo-p-dioxins and -furans ( PCDD/F) ...

Royal Society of Chemistry2007

Fate of PCBs, PAHs and their source characteristic ratios during composting and digestion of source-separated organic waste in full-scale plants

Joseph Tarradellas

Composting and digestion are important waste management strategies. However, the resulting products can contain significant amounts of organic pollutants such as polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs). In this study we ...

2007

Organic pollutants in compost and digestate. Part 1. Polychlorinated biphenyls, polycyclic aromatic hydrocarbons and molecular markers

Joseph Tarradellas, Reinhard Furrer, Rahel Christine Brändli

In Europe, 9.3 x 10(6) t(dry weight ( dw)) of compost and digestate are produced per year. Most of this is applied to agricultural land, which can lead to considerable inputs of organic pollutants, such as polychlorinated biphenyls ( PCB) and polycyclic ar ...

Royal Society of Chemistry2007

Organic pollutants in Swiss compost and digestate

Rahel Christine Brändli

Composting (aerobic treatment of organic wastes) and digestion (anaerobic treatment of organic wastes combined with biogas production) are important waste management strategies with increasing significance in the European Union and Switzerland. Most of the ...

EPFL2006