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Composé organophosphoré

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Publications associées (25)

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Growth modification of hematite by phosphonate additives

Heinrich Hofmann, Paul Bowen, Ulrich Aschauer

The hydroxylated surface structures of seven morphologically important crystallographic surfaces of hematite were calculated allowing the determination of the surface energies and, consequently,the hematite equilibrium morphology. The docking of two organi ...

2008

Ligand synthesis for homogeneous catalysis : from tertiary monophosphines to atropisomeric bisphosphines

Michael Maurin

Organophosphorus compounds found applications in varied fields of the organic chemistry: they are particularly present in natural compounds such as the deoxyribonucleic acid (DNA) and in the field of catalysis in which their utility is also proven. Thus, t ...

EPFL2007

Transition metal complexes for inhibiting resistance in the treatment of cancer and metastasis

Paul Joseph Dyson, Wee Han Ang

The present invention relates to organometallic compounds useful in the treatment of metastasis. The organometallic compounds comprise a ligand that is convalently bound to a bioactive compound, which is an inhibitor of a resistance pathway or a derivative ...

2007

Proton mobility in 2-substituted 1,3-dichlorobenzenes: "ortho" or "meta" metalation?

Rosario Scopelliti, Christophe Heiss

Nine 1,3-dichlorobenzene congeners were selected as model compds. to assess the relative rates of proton abstraction from 4- and 5-positions ("ortho" vs. "meta" metalation). Using lithium 2,2,6,6-tetramethylpiperidide as the basic reagent, the chlorine-adj ...

2006

The synthesis and characterisation of bis(phosphane)-linked (eta(6)-p-cymene)ruthenium(II)-borane compounds

Paul Joseph Dyson, Rosario Scopelliti

The reaction of [(η6-p-cymene)RuCl2]2 with some bis(phosphane) ligands (dppm, dppe, dppv, dppa, dpp14b, dppf) has been investigated. In general mixtures of products were obtained, although the pendant phosphane complexes [( ...

2005