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Concept

Chlorure de rubidium

Publications associées (25)

Nanogels with Metal‐Organic Cages as Functional Crosslinks

Kay Severin, Chaolei Hu

A dinuclear metal-organic cage with four acrylate side chains was prepared by self-assembly. Precipitation polymerization of the cage with N-isopropylacrylamide yielded a thermoresponsive nanogel. The host properties of the cage were retained within the ge ...

Wiley-VCH Verlag GmbH2024

Photogeneration of Hydrogen: Insights from a Pt(II)-Complex Incorporated into a Covalent Organic Framework

Federico De Biasi

Pt(II)-based molecular catalysts stand as a prototypical system in hydrogen evolution reactions (HER) owing to their consistently elevated activity levels. Their integration into heterogeneous systems thus provides an ideal platform to develop catalytic ma ...

Wiley-VCH Verlag2024

Anionic character of the conduction band of sodium chloride

Klaus Kern, Abhishek Grewal

The alkali halides are ionic compounds. Each alkali atom donates an electron to a halogen atom, leading to ions with full shells. The valence band is mainly located on halogen atoms, while, in a traditional picture, the conduction band is mainly located on ...

Nature Portfolio2022

Influence of the Anion on the Oxidation of 5-Hydroxy-methylfurfural by Using Ionic-Polymer-Supported Platinum Nanoparticle Catalysts

Paul Joseph Dyson, Zhaofu Fei, Ning Yan, Felix Daniel Bobbink, Sviatlana Siankevich

Platinum nanoparticles stabilized by an imidazolium-based cross-linked polymer (with chloride as the counteranion) efficiently catalyzed the oxidation of 5-hydroxymethylfurfural to form 2,5-furandicarboxylic acid in water under mild conditions with oxygen ...

2018

An Acid Test: Facile SI-ARGET-ATRP of Methacrylic Acid

Harm-Anton Klok, Piotr Mocny

Atom transfer radical polymerization (ATRP) of methacrylic acid (MAA) is challenging. Herein is reported a study of conditions for facile surface-initiated ATRP by activator regenerated electron transfer (SI-ARGET-ATRP) growth of poly-methacrylic acid (PMA ...

2018

Microfluidic Platform for Seawater Desalination by Coulometric Removal of Chloride Ions through Printed Ag Electrodes

Herbert Shea, Peter Van der Wal, Marianna Fighera

This paper reports on the electrochemical characterization and comparison of printable silver inks for the fabrication of planar electrodes to integrate in a microfluidic platform for in situ desalination of seawater prior to detection of nutrients in mari ...

Electrochemical Soc Inc2017

Orientational ordering of water in extended hydration shells of cations is ion-specific and is correlated directly with viscosity and hydration free energy

Sylvie Roke, Yixing Chen, Halil Ibrahim Okur, Chung-Wen Liang

Specific ion effects in aqueous solutions are investigated at the molecular, nanoscopic and macroscopic levels. Femtosecond elastic second harmonic scattering (fs-ESHS) is used here to assess the chemical effects of ions on molecular and nanoscopic length ...

2017

Halide removal from aqueous solution by novel silver-polymeric materials

Urs von Gunten

The objective of this study was to analyze the behavior of a new material, silver-doped polymeric cloth (Ag-cloth), in the removal of bromide and iodide from waters. Silver is immobilized on the cloth, guaranteeing selective adsorption of the halide ions a ...

Elsevier2016

Bubble electrodeposition of gold porous nanocorals for the enzymatic and non-enzymatic detection of glucose

Sandro Carrara, Irene Taurino

Au nanocorals are grown on gold screen-printed electrodes (SPEs) by using a novel and simple one-step electro-deposition process. Scanning electron microscopy was used for the morphological characterization. The devices were assembled on a three-electrode ...

Elsevier2016

Symmetry breaking in hexagonal and cubic polymorphs of BaTiO3

Dragan Damjanovic, Alberto Biancoli

BaTiO3 appears in cubic and hexagonal variants, both of which are centrosymmetric. Samples of cubic BaTiO3 are known to exhibit breaking of the centric symmetry locally and globally. It has been proposed that the local symmetry breaking originates in polar ...

American Institute of Physics2016

Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Wolfgang Richard Tress, Michael Saliba, Antonio Abate, Juan-Pablo Correa-Baena, Konrad Domanski, Jiyoun Seo, Amita Ummadisingu

All of the cations currently used in perovskite solar cells abide by the tolerance factor for incorporation into the lattice. We show that the small and oxidation-stable rubidium cation (Rb+) can be embedded into a "cation cascade" to create perovskite mat ...

American Association for the Advancement of Science2016

Critical influence of chloride ions on silver ion-mediated acute toxicity of silver nanoparticles to zebrafish embryos

Kristin Schirmer

The toxicity of silver nanoparticles (AgNP) to aquatic organisms, including zebrafish (Danio rerio), has been demonstrated, but differing opinions exist on the contribution of the physical properties of the particles themselves and the free dissolved silve ...

Informa Healthcare2015

Picosecond solvation dynamics of alkali cations in superfluid 4He nanodroplets

Marcel Drabbels, Alberto Hernando de Castro

The dynamics following the photoionization of neutral Rb and Cs atoms residing in a dimple at the surface of a superfluid 4He1000 nanodroplet has been investigated within time-dependent density functional theory, complementing a previous study on Ba. The c ...

American Physical Society2014

Investigation Regarding the Role of Chloride in Organic-Inorganic Halide Perovskites Obtained from Chloride Containing Precursors

Michael Graetzel, Mohammad Khaja Nazeeruddin, Peng Gao, Mohammad Ibrahim Dar, Peng Gao, Neha Arora

As the photovoltaic performance of a device is strongly influenced by the morphology of perovskite, achieving precise control over the crystal formation of organic-inorganic halide perovskites synthesized in the ambience of chloride ions has garnered much ...

American Chemical Society2014

Full-waveform GPR inversion to assess chloride gradients in concrete

Eugen Brühwiler, Alexis Kalogeropoulos

The spreading of deicing salt on roads during winter and the consequent migration of chloride ions within concrete exposes structures reinforcement to corrosion. Reinforcement corrosion is problematic because it reduces the structure's load carrying capaci ...

Elsevier2013

An Imine-Based Molecular Cage with Distinct Binding Sites for Small and Large Alkali Metal Cations

Rosario Scopelliti, Kay Severin, Clément Schouwey

The synthesis of a cylindrical, imine-based cage composed of two trimeric metallamacrocycles is described. The cage acts as a heterotopic receptor for alkali metal cations. The small cations Li+, Na+, and K+ bind to the outside of the cage with good select ...

Wiley-V C H Verlag Gmbh2013

Chloride Ions in the Pore of Glycine and GABA Channels Shape the Time Course and Voltage Dependence of Agonist Currents

Michele Giugliano

In the vertebrate CNS, fast synaptic inhibition is mediated by GABA and glycine receptors. We recently reported that the time course of these synaptic currents is slower when intracellular chloride is high. Here we extend these findings to measure the effe ...

2011

Brine absorption in concrete at low temperature: Experimental investigation and modeling

Eugen Brühwiler, David Conciatori

An experimental campaign supports a model named TransChlor for bringing liquid water moved by capillary suction and chloride ions into concrete. The principal objective of the experimental campaign is to represent conventional concretes under real conditio ...

American Society of Civil Engineers2011

Palladium-catalyzed desulfinylative C–C allylation of Grignard reagents and enolates using allylsulfonyl chlorides and esters

Pierre Vogel

2-Methylprop-2-ene-, prop-2-ene-, 1-methylprop-2-ene-, and (E)-but-2-enesulfonyl chlorides have been used as electrophilic partners in desulfinylative palladium- catalyzed C–C coupling with Grignard reagents and sodium salts of dimethyl malonate and methyl ...

2009

Role of Inner- and Outer-Sphere Bonding in the Sensitization of EuIII-Luminescence Deciphered by Combined Analysis of Experimental Electron Density Distribution Function and Photophysical Data

Jean-Claude Bünzli

A series of lanthanide adducts with different amounts of 1,10-phenanthroline, chloride ions, and water molecules in the inner and outer coordination spheres are investigated with the aim of relating the chemical bonding pattern in the crystals to the lumin ...

2008