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Publications associées (27)

A customized MOF-polymer composite for rapid gold extraction from water matrices

Wendy Lee Queen, Daniel Teav Sun, Shuliang Yang, Jun Li, Li Peng, Olga Syzgantseva

With the fast-growing accumulation of electronic waste and rising demand for rare metals, it is compelling to develop technologies that can promotionally recover targeted metals, like gold, from waste, a process referred to as urban mining. Thus, there is ...

AMER ASSOC ADVANCEMENT SCIENCE2023

Print-Light-Synthesis of Gold Thin Film Electrodes for Electrochemical Sensing

Andreas Stephan Lesch, Horst Pick

The one-step fabrication of gold films by inkjet printing of a gold precursor ink and its photochemical reduction by exposure to UV light is presented. Inkjet printing creates on a substrate with high control micrometer-thin reaction volumes in which upon ...

Wiley2023

Ultimate Limit for Optical Losses in Gold, Revealed by Quantitative Near-Field Microscopy

Sergejs Boroviks

We report thorough measurements of surface plasmon polaritons (SPPs) running along nearly perfect air-gold interfaces formed by atomically flat surfaces of chemically synthesized gold monocrystals. By means of amplitude-and phase-resolved near-field micros ...

AMER CHEMICAL SOC2022

Actor neural networks for the robust control of partially measured nonlinear systems showcased for image propagation through diffuse media

Demetri Psaltis, Christophe Moser, Damien Claude-Marie Loterie, Eirini Kakkava, Babak Rahmani, Ugur Tegin, Navid Borhani

The output of physical systems, such as the scrambled pattern formed by shining the spot of a laser pointer through fog, is often easily accessible by direct measurements. However, selection of the input of such a system to obtain a desired output is diffi ...

SPRINGERNATURE2020

One-step access to N-enoxyimides by gold-catalysed addition of N-hydroxyimides to terminal alkynes

Nicolai Cramer, Coralie Danielle Annick Duchemin

N-Enoxyimides have become attractive substrates for novel catalytic transformations, yet their tedious multi-step synthesis hampers full exploitation of their synthetic potential. We report a gold(I)-catalyzed protocol to access N-enoxyimides from simple a ...

2019

Electrochemical Co-Deposition of Gold and Carbon Nanocapsules from a Colloidal Suspension

Stefano Mischler

This paper shows the preparation of a gold suspension containing carbon nanocapsules and their co-deposition from the colloidal galvanic bath on a nickel electrode to obtain gold/nanocapsules composite coatings. The incorporation of the nanocapsules was co ...

ELECTROCHEMICAL SOC INC2019

Tribological response of multilayered gold nickel coating deposited on fine turned surfaces

Stefano Mischler, Valentine Agnès Madeleine Magnin

Gold coating are widely used in industry due to their corrosion resistance, electrical conductivity and low contact resistance. However, friction and wear can limit their functionality and lifetime. This study addresses the degradation of a commercial fine ...

ELSEVIER SCIENCE SA2019

Mixed gold and platinum nanostructured layers for all-solid-state ion sensors

Giovanni De Micheli, Sandro Carrara, Danilo Demarchi, Irene Taurino, Francesca Criscuolo

The great interest in portable and wearable monitoring systems has promoted in recent years a major expansion of all-solid-state Ion-Selective Electrodes (ISEs). Nanostructured Solid-Contacts (SCs) have shown a promising potential in order to eliminate the ...

IEEE2018

Nanoparticle on mirror plasmonic nanostructure for molecular cavity optomechanics

Christophe Marcel Georges Galland, Santiago Tarrago Velez, Aqeel Ahmed

The plasmonic response of gold can be utilized to enhance the incident electromagnetic (EM) field by several orders of magnitude. When a gold nanoparticle is placed in close proximity to a gold film, the incident field can excite a deeply confined plasmon, ...

IEEE2018

Rapid, Selective Extraction of Trace Amounts of Gold from Complex Water Mixtures with a Metal-Organic Framework (MOF)/Polymer Composite

Emad Oveisi, Wendy Lee Queen, Natalia Gasilova, Shuliang Yang, Daniel Teav Sun

With the ever-increasing production of electronics, there is an ensuing need for gold extraction from sources other than virgin mines. Currently, there are no technologies reported to date that can effectively and selectively concentrate ultratrace amounts ...

AMER CHEMICAL SOC2018

Gold-catalyzed domino cyclization-alkynylation reactions with EBX reagents: new insights into the reaction mechanism

Jérôme Waser, Paola Caramenti, Yifan Li

Gold-catalyzed domino processes constitute a useful alternative to C-H functionalization for the synthesis of functionalized (hetero)arenes. Herein, we report computational studies on the gold-catalyzed cyclization alkynylation of keto-allenes with ethynyl ...

2017

Recent Advances in the Synthesis and Applications of Multimodal Gold-Iron Nanoparticles

Francesco Stellacci

Bimetallic particles based on gold and iron have been gathering increasing interest in biomedical applications because of the synergic combination of the plasmonic features of the inert gold component with the magnetic properties of the iron or iron oxide ...

Bentham Science Publishers2017

The structure and binding mode of citrate in the stabilization of gold nanoparticles

David Lyndon Emsley, Jasmine Viger-Gravel

Elucidating the binding mode of carboxylate-containing ligands to gold nanoparticles (AuNPs) is crucial to understand their stabilizing role. A detailed picture of the three-dimensional structure and coordination modes of citrate, acetate, succinate and gl ...

Nature Publishing Group2017

Significance of surface charge and shell material of superparamagnetic iron oxide nanoparticle (SPION) based core/shell nanoparticles on the composition of the protein corona

Heinrich Hofmann, Lionel André Maurizi, Usawadee Sakulkhu, Géraldine Sylvie Coullerez

As nanoparticles (NPs) are increasingly used in many applications their safety and efficient applications in nanomedicine have become concerns. Protein coronas on nanomaterials' surfaces can influence how the cell "recognizes" nanoparticles, as well as the ...

Royal Soc Chemistry2015

Enzyme and Acid Deconjugation of Plasma Sulfated Metanephrines

Sandrine Gerber

Background: Total (i.e. free + sulfated) metanephrines in plasma is a biomarker for the diagnosis of pheochromocytoma/paraganglioma. Sulfated metanephrines must be completely deconjugated by perchloric acid hydrolysis or sulfatase treatment prior to analyt ...

Elsevier2014

A new target for gold(I) compounds: glutathione-S.transferase inhibition by auranofin

Paul Joseph Dyson, Christian Hartinger, Angela Casini

Nowadays, gold compounds occupy a relevant position constituting a promising class of experimental anticancer metallodrugs. Several research efforts have been devoted to the investigations of the pharmacological properties of gold(I) complexes bearing phos ...

Elsevier Science Inc2013

In-Plane Fabricated Insulated Gold-Tip Probe For Electrochemical And Molecular Experiments

Nico de Rooij, Terunobu Akiyama, Peter Van der Wal, Sebastian Gautsch, Yexian Wu

In this contribution we present a scanning probe with a gold-tip completely encapsulated with insulator all the way to the apex. The probe fabrication is unique owing to an in-plane arrangement in which the width of the cantilever is defined by deep reacti ...

IEEE2013

Application of a Versatile Nanoparticle Stabilizer in Phase Transfer and Catalysis

Paul Joseph Dyson, Vincent Laporte, Ilaria Biondi

Gold and rhodium nanoparticles stabilized by a cationic polymer can be readily modified by anion exchange to afford nanoparticles that may be dispersed in a wide range of organic solvents and ionic liquids. The catalytic activity of the Rh nanoparticle dis ...

Wiley-V C H Verlag Gmbh2012

Ethynyl Benziodoxolones for the Direct Alkynylation of Heterocycles: Structural Requirement, Improved Procedure for Pyrroles, and Insights into the Mechanism

Rosario Scopelliti, Jérôme Waser, Jonathan Brand

This report describes a full study of the gold-catalyzed direct alkynylation of indoles, pyrroles, and thiophenes using alkynyl hypervalent iodine reagents, especially the study of the structural requirements of alkynyl benziodoxolones for an efficient ace ...

2012

Cytotoxic gold compounds: synthesis, biological characterization and investigation of their inhibition properties of the zinc finger protein PARP-1

Michael Graetzel, Shaik Mohammed Zakeeruddin, Rosario Scopelliti, Angela Casini, Fabio Edafe

The new gold(III) complexes: [Au{2-(2'-pyridyl) imidazolate}Cl-2] and [Au{2,6-bis(2'-benzimidazolate) pyridine}(OCOCH3)] and the mono-and binuclear gold(I) complexes: Au{2-(2'-pyridyl) imidazole} (PPh3), [Au(2-phenylimidazolate)(DAPTA)] (DAPTA = 3,7 ...

Royal Society of Chemistry2012