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Concept

Plastocyanine

Publications associées (14)

Cycloalkane Oxidation Catalyzed by Copper-based Catalysts with H2O2 under Mild Conditions

Nukorn Plainpan

Copper-catalyzed cycloalkane oxidation using H2O2 as an oxidant was investigated under mild conditions. The copper catalysts studied in this work ranged from commercially-available copper(II) salts to copper(II) complexes containing polypyridyl ligands. Va ...

WILEY-V C H VERLAG GMBH2023

Schiff base ligands derived from 1,2-bis(2 '-nitro-/amino-phenoxy)-3-R-benzene and 2-hydroxy-1-naphthaldehyde and their Cu/Zn(II) complexes: synthesis, characterization, X-ray structures and computational studies

Rosario Scopelliti

1,2-Bis(2'-nitrophenoxy)-3-R-benzenes {R = H (1), CH3 (2) and OCH3 (3)} have been prepared from the S-N-Ar reaction between 1-fluoro-2-nitrobenzene and 3-R-catechol (aromatic diol), and are then reduced to the corresponding diamines 1,2-bis(2'-aminophenoxy ...

ROYAL SOC CHEMISTRY2021

Coordination-Driven Monolayer-to-Bilayer Transition in Two-Dimensional Metal–Organic Networks

Henning Paul-Julius Stahlberg, Mina Moradi

We report on monolayer-to-bilayer transitions in 2D metal–organic networks (MONs) from amphiphiles supported at the water–air interface. Functionalized calix[4]arenes are assembled through the coordination of selected transition metal ions to yield monomol ...

2021

Controllable CO adsorption determines ethylene and methane productions from CO2 electroreduction

Jun Li, Zhiwen Zhou

Among all CO2 electroreduction products, methane (CH4) and ethylene (C2H4) are two typical and valuable hydrocarbon products which are formed in two different pathways: hydrogenation and dimerization reactions of the same CO intermediate. Theoretical studi ...

ELSEVIER2021

Fine-tuning the coordination atoms of copper redox mediators: an effective strategy for boosting the photovoltage of dye-sensitized solar cells

Ulf Anders Hagfeldt, Chong Liu

Natural systems have marvelously utilized copper complexes featuring sulfur-coordinating ligands, known as blue copper proteins, as efficient electron-transfer mediators in biological processes. Copper complexes with sulfur-coordinating ligands have been a ...

Royal Society of Chemistry2019

Effect of Coordination Sphere Geometry of Copper Redox Mediators on Regeneration and Recombination Behavior in Dye-Sensitized Solar Cell Applications

Ulf Anders Hagfeldt, Shaik Mohammed Zakeeruddin, Jacques-Edouard Moser, Joël Teuscher, Fabrizio Giordano, Marina Freitag, Yasemin Saygili, Marko Stojanovic

The recombination of injected electrons with oxidized redox species and regeneration behavior of copper redox mediators are investigated for four copper complexes, [Cu(dmby)2]2+/1+ (dmby = 6,6′-dimethyl-2,2′- bipyridine), [Cu(tmby)2]2+/1+ (tmby = 4,4′,6,6′ ...

2018

A genetic algorithm based design and experimental characterization of a highly thermostable metalloprotein

Ursula Röthlisberger, Rudolf Hovius, Esra Bozkurt, Nicholas John Browning

The development of thermostable and solvent-tolerant metalloproteins is a long-sought goal for many applica- tions in synthetic biology and biotechnology. In this work, we were able to engineer a highly thermo- and organic solvent- stable metallo variant o ...

2018

Resonant elastic x-ray scattering from the skyrmion lattice in Cu2OSeO3

Helmuth Berger

We report the study of the skyrmion state near the surface of Cu2OSeO3 using soft resonant elastic x-ray scattering (REXS) at the Cu L-3 edge. Within the lateral sampling area of 200 x 200 mu m(2), we found a long-range-ordered skyrmion lattice phase as we ...

Amer Physical Soc2016

Investigations of the non-adiabatic photophysics of Cu(I)-phenanthroline complexes

Gloria Capano

Cu(I)-phenanthrolines are an important class of metal-organic molecules that exhibits much promise for solar energy harvesting and solar-driven catalysis applications. Although many experimental studies have been performed calling for high-level simulation ...

EPFL2016

Critical Factors Driving the High Volumetric Uptake of Methane in Cu-3(btc)(2)

Berend Smit

A thorough experimental and computational study has been carried out to elucidate the mechanistic reasons for the high volumetric uptake of methane in the metal-organic framework Cu-3(btc)(2) (btc(3-) = 1,3,5-benzenetricarboxylate; HKUST-1). Methane adsorp ...

American Chemical Society2015

Molecular dynamics simulations of apocupredoxins: insights into the formation and stabilization of copper sites under entatic control

Matteo Dal Peraro, Luciano Andres Abriata

Cupredoxins perform copper-mediated long-range electron transfer (ET) in biological systems. Their copper-binding sites have evolved to force copper ions into ET-competent systems with decreased reorganization energy, increased reduction potential, and a d ...

Springer2014

Accelerated Escherichia coli inactivation in the dark on uniform copper flexible surfaces

César Pulgarin, Juan Kiwi, Sami Rtimi, Rosendo Sanjines, Michaël Bensimon

The bacterial inactivation of Escherichia coli on Cu/CuO-polyester surfaces prepared by direct current magnetron sputtering was investigated in the dark and under actinic light (360nm

American Vacuum Society2014

Cell-wall-dependent effect of carboxyl-CdSe/ZnS quantum dots on lead and copper availability to green microalgae

Vera Slaveykova-Startcheva, Miguel Garcia

The present study examines the effect of carboxyl-CdSe/ZnS quantum dots (QDs) on Cu and PI) availability to microalgae with different cell wall characteristics: Chlorella kesslerii possessing a cellulosic cell wall and two strains of Chlamydomonas reinhard ...

2012

Electron transfer induced dissociation of chloro-cyano-benzene radical anion: driving chemical reactions via charge restraints

Ursula Röthlisberger

We introduce a new quantum mechanics/mol. mechanics based method to drive electron transfer reactions. Our approach uses the dynamically restrained electrostatic potential derived charges of the quantum atoms as a reaction coordinate, and allows an estn. o ...

2005