Mediaspace scheduled maintenance: Aug 25, 2026 07:00 - 12:00 AM. During this time, videos will be temporarily unavailable. Check status updates.

Concept

Nombre d'oxydation

Publications associées (30)

Femtosecond laser-induced modifications and self-organization in complex glass systems

Gözden Torun

Ultrashort laser pulses, i.e., pulses emitted shorter than a picosecond, can tailor material properties by introducing permanent modifications locally in three dimensions. Remarkably, under a certain exposure condition, these modifications are accompanied ...

EPFL2023

Stabilizing Unusual Oxidation States of Lanthanides in Molecular Complexes: Synthesis, Properties, and Reactivity

Aurélien René Willauer

The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...

EPFL2022

Revisiting the Impact of Morphology and Oxidation State of Cu on CO2 Reduction Using Electrochemical Flow Cell

Michael Graetzel, Shaik Mohammed Zakeeruddin, Dan Ren, Jing Gao

Electroreduction of carbon dioxide (CO2) in a flow electrolyzer represents a promising carbon-neutral technology with efficient production of valuable chemicals. In this work, the catalytic performance of polycrystalline copper (Cu), Cu2O-derived copper (O ...

AMER CHEMICAL SOC2022

Thermal Sintering and Phosphorus Poisoning of a Layered Diesel Oxidation Catalyst

Oliver Kröcher, Davide Ferri

The tightening emission regulations have led to the development of commercial DOCs with zoned or layered formulations allowing to cover a wide range of functionalities (i.e. CO, HC and NO oxidation as well as HC or NOx trap). Aging phenomena in such comple ...

SPRINGER/PLENUM PUBLISHERS2023

Pivotal Role of Intersite Hubbard Interactions in Fe-Doped alpha-MnO2

Iurii Timrov

We present a first-principles investigation of the structural, electronic, and magnetic properties of the pristine and Fe-doped alpha-MnO2 using density-functional theory with extended Hubbard functionals. The onsite U and intersite V Hubbard parameters ar ...

AMER CHEMICAL SOC2022

cell2mol: encoding chemistry to interpret crystallographic data

Anne-Clémence Corminboeuf, Rubén Laplaza Solanas, Sergio Vela Llausi, Yuri Cho

The creation and maintenance of crystallographic data repositories is one of the greatest data-related achievements in chemistry. Platforms such as the Cambridge Structural Database host what is likely the most diverse collection of synthesizable molecules ...

NATURE PORTFOLIO2022

Secondary aerosol formation during the dark oxidation of residential biomass burning emissions

Athanasios Nenes

Particulate matter from biomass burning emissions affects air quality, ecosystems and climate; however, quantifying these effects requires that the connection between primary emissions and secondary aerosol production is firmly established. We performed at ...

ROYAL SOC CHEMISTRY2022

Intentional oxygen oscillations on Pd/Al2O3 for enhanced methane removal from the exhaust of natural gas engines

Maneka Claire Roger

Natural gas (NG) is a suitable alternative to gasoline and diesel fuels to decrease the carbon footprint of the mobility and energy sectors. Although NG is considered a fossil fuel, methane (CH4), its main component, can be produced industrially from power ...

EPFL2022

Oxidation of organic micropollutant surrogate functional groups with peracetic acid activated by aqueous Co(II), Cu(II), or Ag(I) and geopolymer-supported Co(II)

Urs von Gunten

Peracetic acid (PAA) in combination with transition metals has recently gained increasing attention for organic micropollutant abatement. In this study, aqueous Co(II), Cu(II), and Ag(I) were compared for their capacity to activate PAA. Co(II) outperformed ...

PERGAMON-ELSEVIER SCIENCE LTD2022

Radical Alkynylations with EthynylBenziodoXolones: From Photocatalysis to Direct Excitation

Jérôme Waser, Stephanie Grace Elizabeth Amos

Ethynylbenziodoxolones (EBXs) have recently emerged as potent reagents for the alkynylation of radicals. Their combination with photocatalysis allows the synthesis of valuable alkynes at room temperature. Herein, we discuss two photomediated strategies for ...

2022