Concept

Uranium

Publications associées (30)

Highlights of the Science and Life of Peter Varga (1946-2018)

Peter Varga has passed on October 27, 2018. His pioneering discoveries of chemical resolution at the atomic scale on surface alloys, atomic resolution of ultrathin alkali halides, nucleation of bcc iron in ultrathin films, and the microscopic structure of ...

2020

Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex

Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Lucile Sylvie Danielle Chatelain, Luciano Barluzzi

Uranium nitride complexes are of high interest because of their ability to effect dinitrogen reduction and functionalization and to promote magnetic communication, but studies of their properties and reactivity remain rare. Here we have prepared in 73% yie ...

2019

Small molecule activation by multimetallic uranium complexes supported by siloxide ligands

Marinella Mazzanti, Marta Falcone, Luciano Barluzzi

The synthesis and reactivity of uranium compounds supported by the tris-tert-butoxysiloxide ligand is surveyed. The multiple binding modes of the tert-butoxysiloxide ligand have proven very well suited to stabilize highly reactive homo- and heteropolymetal ...

Royal Society of Chemistry2019

Small Molecule Activation by Multimetallic Uranium Complexes

Marta Falcone

The development of new processes for the selective and sustainable transformation of abundant small molecules constitutes one of the major research areas in inorganic and organometallic chemistry. These molecules as CO2, CO, N2 and H2 are abundant reservoi ...

EPFL2019

Non-crystalline tetravalent uranium species in the subsurface: formation and stability

Luca Loreggian

Uranium (U) contamination of ground and surface waters poses an acute hazard on the ecosystem and human health. Since the discovery of microbial U(VI) reduction, U bioremediation has been explored as a promising and cost-effective method compared to tradit ...

EPFL2019

Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Anne-Clémence Corminboeuf, Alberto Fabrizio, Luciano Barluzzi

Molecular uranium nitride complexes were prepared to relate their small molecule reactivity to the nature of the U & xe001;N & xe001;U bonding imposed by the supporting ligand. The U4+-U4+ nitride complexes, [NBu4][{(((BuO)-Bu-t)(3)SiO)(3)U}(2)(mu-N)], [NB ...

2019

Effect of Aging on the Stability of Microbially Reduced Uranium in Natural Sediment

Rizlan Bernier-Latmani, Barbora Bártová, Yuheng Wang, Luca Loreggian, Sophie Louise Bretagne, Agnès Novotny

Reductive immobilization of uranium has been explored as a remediation strategy for the U-contaminated subsurface. Via the in situ biostimulation of microbial processes, hexavalent U is reduced to less soluble tetravalent species, which are immobilized wit ...

2019

Structural Snapshots of Cluster Growth from {U6 } to {U38 } During the Hydrolysis of UCl4

Marinella Mazzanti, Farzaneh Fadaei Tirani, Lucile Sylvie Danielle Chatelain, Radmila Faizova

Herein we report the assembly of large uranium(IV) clusters with novel nuclearities and/or shapes from the controlled hydrolysis of UCl4 in organic solution and in the presence of the benzoate ligands. {U6}, {U13}, {U16}, {U24}, {U38} oxo and oxo/hydroxo c ...

Wiley-VCH Verlag GmbH2019

Measurement of CP-Violating and Mixing-Induced Observables in B-s(0) -> phi gamma Decays

Olivier Schneider, Aurelio Bay, Yiming Li, Guido Haefeli, Frédéric Blanc, Christoph Frei, Tatsuya Nakada, François Fleuret, Jorge Miguel Dias Almeida Rodrigues Soares, Michael Thompson McCann, Michel De Cian, Achille Mauri, Luca Pescatore, Craig Matthew Smith, Elena Graverini, Chitsanu Khurewathanakul, Renato Quagliani, Federico Betti, Aravindhan Venkateswaran, Luis Miguel Garcia Martin, Vitalii Lisovskyi, Veronica Sølund Kirsebom, Jian Wang, Mingkui Wang, Zhirui Xu, Yi Zhang, Lei Zhang, Ho Ling Li, Mark Tobin, Minh Tâm Tran, Niko Neufeld, Matthew Needham, Marc-Olivier Bettler, Greig Alan Cowan, Maurizio Martinelli, Vladislav Balagura, Donal Patrick Hill, Liang Sun, Pietro Marino, Mirco Dorigo, Xiaoxue Han, Liupan An, Federico Leo Redi, Plamen Hristov Hopchev, Thibaud Humair, Maxime Schubiger, Hang Yin, Guido Andreassi, Violaine Bellée, Maria Vieites Diaz, Olivier Göran Girard, Axel Kuonen, Preema Rennee Pais, Pavol Stefko, Tara Nanut, Maria Elena Stramaglia, Tommaso Colombo, Vladimir Macko, Guillaume Max Pietrzyk, Evgenii Shmanin, Sebastian Schulte, Surapat Ek-In, Dipanwita Dutta, Zheng Wang, Yi Wang, Hans Dijkstra, Gerhard Raven, Peter Clarke, Frédéric Teubert, Giovanni Carboni, Victor Coco, Adam Davis, Paolo Durante, Wenyu Zhang, Yu Zheng, Anton Petrov, Maxim Borisyak, Feng Jiang, Zhipeng Tang, Xuan Li, Almagul Kondybayeva

A time-dependent analysis of the B-s(0) -> phi gamma decay rate is performed to determine the CP -violating observables S-phi gamma and C-phi gamma and the mixing-induced observable A(phi gamma)(Delta). The measurement is based on a sample of pp collision ...

2019

Reversible Dihydrogen Activation and Hydride Transfer by a Uranium Nitride Complex

Marinella Mazzanti, Farzaneh Fadaei Tirani, Marta Falcone, Lok Nga Poon

Cleavage of dihydrogen is an important step in the industrial and enzymatic transformation of N2 into ammonia. The reversible cleavage of dihydrogen was achieved under mild conditions (room temperature and 1 atmosphere of H2) by the molecular uranium nitri ...

Wiley-VCH Verlag GmbH2018