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Concept

Pre-exponential factor

Publications associées (20)

Modulating the Reactivity of Liquid Ga Nanoparticle Inks by Modifying Their Surface Chemistry

Raffaella Buonsanti, Laia Castilla Amorós, James Richard Pankhurst

Micro- and nanosized particles of liquid metals, particularly Ga-based alloys, are attracting increasing attention for applications in several fields. The surface functionalization of Ga-based nanoparticles (NPs) with organic ligands renders easily process ...

2022

Mechanistic modelling of solar disinfection (SODIS) kinetics of Escherichia coli, enhanced with H2O2 - Part 2: Shine on you, crazy peroxide

César Pulgarin, Stefanos Giannakis

In this second part of the development of a mechanistic kinetic model of the solar inactivation of E. coli enhanced with hydrogen peroxide, we evaluate the mechanisms based on photonic inactivation and integrate them into the kinetic model of the dark proc ...

ELSEVIER SCIENCE SA2022

Mechanistic modelling of solar disinfection (SODIS) kinetics of Escherichia coli, enhanced with H2O2 - part 1: The dark side of peroxide

César Pulgarin, Stefanos Giannakis

The present bi-partite work describes the development and validation of a mechanistic kinetic model of SODIS E. coli inactivation, enhanced with H2O2. In this first part, the mechanism of the baseline dark phenomena is modelled. A mechanistic model involvi ...

ELSEVIER SCIENCE SA2022

Hydrogen production on demand by redox-mediated electrocatalysis: A kinetic study

Hubert Girault, Danick Reynard, Sunny Isaïe Maye

Producing hydrogen from water using a redox mediator on solid electrocatalyst particles in a reactor offers several advantages over classical electrolysis in terms of safety, membrane degradation, purity and flexibility. Herein, vanadium-mediated hydrogen ...

ELSEVIER SCIENCE SA2021

Phonon-Ion Interactions: Designing Ion Mobility Based on Lattice Dynamics

Sokseiha Muy

This review is focused on the influence of lattice dynamics on the ionic mobility in superionic conductors in particular solid-state Li-ion conductors. After a succinct review of the static view of ionic conduction, the role of polarizability as the underl ...

WILEY-V C H VERLAG GMBH2020

Mechanistic implications of lanthanum-modification on gold-catalyzed formic acid decomposition under SCR-relevant conditions

Oliver Kröcher, Davide Ferri

The use of formate-based ammonia precursors as alternatives to urea in the selective catalytic reduction (SCR) process requires that formic acid released upon their thermolysis in the hot exhaust is rapidly decomposed to carbon dioxide. This work aims at t ...

ELSEVIER SCIENCE BV2019

Solar cooking potential in Switzerland: Nodal modelling and optimization

Andreas Schueler, Josef Andreas Schuler, Dasaraden Mauree, Luc Burnier, Olivia Valérie Charlotte Bouvard, Jérémy Jacques Antonin Fleury

Solar cooking is one possible solution to reduce the domination of fossil fuel in the domestic sector and to benefit from renewable energy. This study assesses the solar cooking potential in Switzerland. A nodal model, based on energy balance equations of ...

PERGAMON-ELSEVIER SCIENCE LTD2019

Morphology and composition of oxidized InAs nanowires studied by combined Raman spectroscopy and transmission electron microscopy

Anna Fontcuberta i Morral, Esther Alarcon Llado, Francesca Amaduzzi

importance for semiconductor nanowires because of the high surface-to-volume ratio and only little is known about the consequences of oxidation for these systems. Here, we study the properties of indium arsenide nanowires which were locally oxidized using ...

Institute of Physics2016

Effect of service temperature on the flexural creep of vacuum infused GFRP laminates used in sandwich floor panels

Thomas Keller

This paper presents an experimental and analytical study about the effect of temperature on the flexural creep of GFRP laminates produced by vacuum infusion. Such laminates are considered for use in the faces of sandwich panels for building floor applicati ...

Elsevier2016

Long-term in-situ oxidation of biogenic uraninite in an alluvial aquifer: impact of dissolved oxygen and calcium

Rizlan Bernier-Latmani, Daniel Scott Alessi, Elena Suvorova Buffat, Harish Veeramani

Oxidative dissolution controls uranium release to (sub)oxic pore waters from biogenic uraninite produced by natural or engineered processes, such as bioremediation Laboratory studies show that uraninite dissolution is profoundly influenced by dissolved oxy ...

Amer Chemical Soc2015

Skill learning based catching motion control

Learned biomechanical strategies prepare the human body in kinematics and kinetics terms during interception tasks, such as throwing and catching, in real world. Based on this, we present a real-time physics-based approach that generates natural and physic ...

Wiley-Blackwell2014

Process influences on the structure, piezoelectric, and gas-barrier properties of PVDF-TrFE copolymer

Jan-Anders Edvin Maansson, Yves Leterrier, Dragan Damjanovic, Antonia Neels, Alex Dommann, Olha Sereda

The influence of annealing between the Curie transition and the melting point of solvent cast polyvinylidene fluoride trifluoroethylene copolymer films on the crystalline structure, mechanical and electrical properties, and oxygen permeability is investiga ...

2014

Dependence of the most probable and average bond rupture force on the force loading rate: First order correction to the Bell-Evans model

Giovanni Dietler, Serguei Sekatski, Fabrizio Benedetti

The Bell-Evans model which predicts the linear dependence of the most probable intermolecular bond rupture force on the logarithm of stretching force loading rate is usually used to discuss the dynamic force spectroscopy experiment data. This model is cons ...

American Institute of Physics2013

Synthesis of Room-Temperature Ionic Liquids with the Weakly Coordinating [Al(ORF)4]- Anion (RF=C(H)(CF3)2) and the Determination of Their Principal Physical Properties

Paul Joseph Dyson, Gabor Laurenczy, Safak Bulut

A large series of ionic liqs. (ILs) based on the weakly coordinating alkoxyaluminate [Al(hfip)4]- (hfip: hexafluoroisopropoxy) with classical as well as functionalized cations were prepd., and their principal phys. properties detd. M.ps. are between 0 ([C4 ...

2010

Investigation of 3D moisture diffusion coefficients and damage in a pultruded E-glass/polyester structural composite

Thomas Keller, Florian Riebel

As civil engineers seek to improve buildings and bridges, they are turning to composite materials for some structural components. Thus the long-term life of these materials in damp highly acidic conditions (from concrete pore solutions) is critical. This a ...

2009

Modeling of stiffness properties of FRP composites under elevated and high temperatures

Thomas Keller, Till Vallée, Yu Bai

When subjected to elevated and high temperatures, the mechanical properties of FRP composites, such as the E- modulus and viscosity, experience significant changes. At a certain temperature, a composite material can be considered a mixture of materials tha ...

2008

Characterization of frequency-dependent glass transition temperature by Vogel-Fulcher relationship

Yu Bai, Li Jin

The complex mechanical modulus of polymer and polymer based composite materials showed a frequency-dependent behaviour during glass transition relaxation, which was historically modelled by the Arrhenius equation. However, this might not be true in a broad ...

2008

Surface diffusion of Ag on Pd(100) measured with specular helium scattering

Wolfgang Harbich

We present a new method to determine surface diffusion constants using specular reflected thermal helium scattering. The specular reflected helium intensity is recorded in real time as a function of surface coverage of the adsorbate and surface temperature ...

1995

Chemisorption and macroscopic diffusion of NO on Pt(111)

Wolfgang Harbich

Thermal energy helium scattering is used to measure the isothermal desorption of NO from Pt(111) in the temperature range 343-383 K. Taking into account the vibrational degrees of freedom to calculate the residence time of the molecules, the energy of adso ...

1994

Measurement of macroscopic diffusion of CO on Pt(111) by thermal helium scattering

Wolfgang Harbich

A new method to measure the diffusion of adsorbed molecules over macroscopic distance on single crystal surfaces is presented and demonstrated with the system CO on Pt(111). A controlled coverage of molecules, typically of the order of 0.01 monolayer, is d ...

1993