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Concept

Salt bridge (protein and supramolecular)

Publications associées (26)

Supramolecular Self-Assembly Driven by Electrostatic Repulsion: The 1D Aggregation of Rubrene Pentagons on Au(111)

Wolf-Dieter Schneider, Alfonso Baldereschi, Massimiliano Stengel

At present, organic molecules are among the best candidate "building blocks" for the construction of self-assembling nanoscale devices based on metal substrates. Control of the formation of specific patterns In the submonolayer regime is usually achieved b ...

2010

Substrate effect on supramolecular self-assembly: from semiconductors to metals

Klaus Kern, Dietmar Payer

Terephthalic acid (TPA) deposited on Si(111)-7 x 7, Si(111)-root 3 x root 3-Ag and Ag(111) has been studied as a model system to understand how much passivated semiconductor surfaces differ from semiconductor and metal surfaces in respect of supramolecular ...

2009

The conformational flexibility of the carboxy terminal residues 105-114 is a key modulator of the catalytic activity and stability of macrophage migration inhibitory factor

Ursula Röthlisberger, Hilal Lashuel, Michele Cascella

Macrophage migration inhibitory factor (MIF) is a multifunctional protein and a major mediator of innate immunity. Although X-ray crystallography revealed that MIF exists as a homotrimer, its oligomerization state in vivo and the factors governing its olig ...

American Chemical Society2008

Supramolecular approach to the synthesis of [60]fullerene-metal dithiocarbamate complexes, {(M-II(R(2)dtc)(2))(x)center dot L}center dot C-60 (M = Zn, Cd, Hg, Fe, and Mn; x=1 and 2). The study of magnetic properties and photoconductivity

László Forró, Bálint Náfrádi

Coordination assemblies formed by metal(II) dithiocarbamates M-II(R(2)dtc)2 (M = Zn, Cd, Hg, Mn, and Fe; R = Me, Et, iPr, nPr, and nBu) and nitrogen-containing ligands (L = DABCO, DMP, and HMTA) are shown to be sterically well consistent with the spherical ...

2008

Supramolecular assembly, chirality, and electronic properties of rubrene studied by STM and STS

Marie-Christine Buluschek

This thesis presents the first experimental results of a scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS) investigation of rubrene at the supramolecular, molecular and submolecular level. Based on its semiconducting and fluores ...

EPFL2006

Self-organized growth of ordered functional nanostructures on templates

Thomas Roland Classen

In this thesis, the use of nanotemplates for steering the molecular self-organization at metallic surfaces is investigated. Nanotemplates are surfaces that exhibit a periodic variation of the adhesion energy on the nanometer scale. Preferential adsorption ...

EPFL2005