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Concept

Salt bridge (protein and supramolecular)

Publications associées (26)

Architecture-Controllable Single-Crystal Helical Self-assembly of Small-Molecule Disulfides with Dynamic Chirality

Lukas Pfeifer

Beyond the common supramolecular helical polymers in solutions, controlling single-crystal helical self-assembly with precisely defined chirality and architectures has been challenging. Here, we report that simply merging static homochiral amino acids with ...

AMER CHEMICAL SOC2023

Supramolecular Modifications of Semicrystalline Polymers

Michael Alan Giffin

Supramolecular interactions play an important role in defining the structure and the resulting mechanical properties of materials. For instance, interchain hydrogen-bonding in PAs gives them superior strength and stiffness in engineering materials, while t ...

EPFL2023

Insight into the Growth of Anisotropic CdSe Nanocrystals: Attachment of Intrinsically Different Building Blocks

Martinus Adela Maria Gijs, Virendra Kumar Parashar, Xiaopeng Huang

An in-depth understanding of the growth mechanism of nanocrystals (NCs) is of great significance for shape control of colloidal semiconductor nanostructures. In this study, we elucidate the formation mechanism of anisotropic CdSe NCs by systematically inve ...

AMER CHEMICAL SOC2020

The role of xanthophylls in the supramolecular organization of the photosynthetic complex LHCII in lipid membranes studied by high-resolution imaging and nanospectroscopy

Giovanni Dietler, Serguei Sekatski, Jiangtao Zhou

The xanthophyll cycle is a regulatory mechanism operating in the photosynthetic apparatus of plants. It consists of the conversion of the xanthophyll pigment violaxanthin to zeaxanthin, and vice versa, in response to light intensity. According to the curre ...

ELSEVIER2020

Establishing a Ternary System for Optical Monitoring of DNA-Protein Interactions with Single-Walled Carbon Nanotubes

Shang-Jung Wu

DNA-protein interactions lie at the crux of life's essential processes. As such, various technologies have been developed to characterize these interactions. The distinct advantages of these technologies can be leveraged to study different facets of these ...

EPFL2020

Cages vs. Prisms: Controlling the Formation of Metallosupramolecular Architectures with Ligand Side-Chains

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Giacomo Cecot, Ophélie Marie Planes, Andrea Luca Ramorini

Metallosupramolecular assemblies of the general formula M2nLn can adopt prismatic or cage‐like structures. The factors controlling the aggregation number n and the geometry of the final assembly are still not fully understood. Here, we describe the synthes ...

2019

Investigation of nanoparticle-protein interactions with novel methods

Ahmet Bekdemir

Advancements in novel nanomaterials present promising avenue for therapeutics and diagnosis in nanomedicine. Importantly, in these applications, nanoparticles (NPs) are almost instantly coated with a complex layer of proteins in biological environment, ter ...

EPFL2018

Beyond the Hofmeister Series: Ion-Specific Effects on Proteins and Their Biological Functions

Halil Ibrahim Okur

Ions differ in their ability to salt out proteins from solution as expressed in the lyotropic or Hofmeister series of cations and anions. Since its first formulation in 1888, this series has been invoked in a plethora of effects, going beyond the original ...

Amer Chemical Soc2017

Reversible Local and Global Switching in Multicomponent Supramolecular Networks: Controlled Guest Release and Capture at the Solution/Solid Interface

Magalí Alejandra Lingenfelder, Fernando Pablo Cometto

Dynamically switchable supramolecular systems offer exciting possibilities in building smart surfaces, the structure and thus the function of which can be controlled by using external stimuli. Here we demonstrate an elegant approach where the guest binding ...

Amer Chemical Soc2015

Light absorption in 1D and 2D nanostructured organic semiconductors

Damien Rolland

Organic photovoltaics will be one of the corner stones in solving the increasing world's energy demand issue. For this reason, a better understanding of the detailed mechanisms involved in energy conversion in the employed nanostructured materials is still ...

EPFL2015

Two-Fold Odd-Even Effect in Self-Assembled Nanowires from Oligopeptide-Polymer-Substituted Perylene Bisimides

Holger Frauenrath, Roman Niklaus Marty, Robin Nigon, Deborah Leite

Organic nanowires are important building blocks for nanoscopic organic electronic devices. In order to ensure efficient charge transport through such nanowires, it is important to understand in detail the molecular parameters that guide self-assembly of pi ...

Amer Chemical Soc2014

Resonance Light Scattering in Dye-Aggregates Forming in Dewetting Droplets

Jakob Heier, Raffaele Mezzenga, Gian-Luca Bona

Small organic semiconducting molecules assembling into supramolecular J- and H- aggregates have attracted much attention due to outstanding optoelectronic properties. However, their easy and reproducible fabrication is not yet sufficiently developed for in ...

American Chemical Society2014

From Reinforcement to High-Performance Damping : An Oligopeptide Toolbox for Tailored Elastomers

Emmanuel Croisier

Biomaterials such as structure proteins are constructed from limited sets of chemical building blocks and supramolecular motifs. Nevertheless, they exhibit extraordinary properties specifically tailored for a broad range of applications because hierarchica ...

EPFL2013

Modern computational approaches for quantifying inter- and intramolecular interactions

Jérôme Florian Gonthier

This thesis introduces modern computational approaches for quantifying and analyzing both intra- and intermolecular interactions. An original formalism to quantify intramolecular interactions ab initio is first introduced. Inspired from intermolecular Symm ...

EPFL2013

Development of a robust supramolecular method to prepare well-defined nanofibrils from conjugated molecules

Holger Frauenrath, Roman Niklaus Marty, Liangfei Tian

In order to produce materials with tailored structures and functions via supramolecular self-assembly of molecular precursors in a predictable fashion, it is necessary to develop 'supramolecular methods' based on structurally simple 'supramolecular synthon ...

2012

Varying molecular interactions by coverage in supramolecular surface chemistry

Klaus Kern, Magalí Alejandra Lingenfelder

The possibility of modifying the intermolecular interactions of absorbed benzene-carboxylic acids from coordination to hydrogen bonding by changing their surface coverage is demonstrated through a combination of scanning tunnelling microscopy, X-ray photo- ...

Royal Society of Chemistry2012

Ultrafast One- and Two-Dimensional UV Transient Absorption Spectroscopy of Haem Proteins

Cristina Consani

Proteins are dynamic macromolecules, which accomplish biological function driven by long-range interactions and global motions. While their biological function is often clear, little is known about the collective interactions which make these systems real ...

EPFL2012

Controlling the formation of metallosupramolecular assemblies by metal ionic radii

The formation of either dinuclear double-stranded or pentanuclear circular helicates from a ligand containing two tridentate domains separated by a phenylene unit can be controlled by inter-ligand steric interactions which themselves are governed by the si ...

Royal Society of Chemistry2010

Ultrafast charge transfer through p-oligo(phenylene) bridges: effect of nonequilibrium vibrations

Michael Graetzel, Mohammad Khaja Nazeeruddin, Shaik Mohammed Zakeeruddin, Jacques-Edouard Moser, Christophe Bauer, Pascal Comte, Joël Teuscher, Bernard Wenger, Serge Pelet

Electron transfers (ET) between a donor (D) and an acceptor (A) through a molecular bridge (B) are of great importance in biological systems, molecular electronics and molecular based light-energy conversion systems. Here, the back and the forward electron ...

Current Science Assoc // Indian Academy of Sciences2010

The Baseplate Wedges of Bacteriophage T4 Spontaneously Assemble into Hubless Baseplate-Like Structure In Vitro

Petr Leiman

The baseplate of phage T4 is an important model system in viral supramolecular assembly. The baseplate consists of six wedges surrounding the central hub. We report the first successful attempt at complete wedge assembly using an in vitro approach based on ...

Elsevier2010