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Concept

Spectrométrie d'absorption des rayons X

Publications associées (30)

Ruthenium on phosphorous-modified alumina as an effective and stable catalyst for catalytic transfer hydrogenation of furfural

Oliver Kröcher, Davide Ferri, Gaël Peng, Thibault Xavier Florian Fovanna

Supported ruthenium was used in the liquid phase catalytic transfer hydrogenation of furfural. To improve the stability of Ru against leaching, phosphorous was introduced on a Ru/Al2O3 based catalyst upon impregnation with ammonium hypophosphite followed b ...

2020

Photoemission from non-polar aromatic molecules in the gas and liquid phase

Majed Chergui, Frank van Mourik, Christopher Alexander Arrell, José Javier Pancracio Ojeda Andara, Jakob Grilj, Lars-Hendrik Mewes, Luca Longetti

The photoelectron spectra of both liquid and gas phase aromatic molecules are reported. The spectra were obtained using a 34.1 eV source produced by high harmonic generation and analysed with the help of high-level ab initio simulations using the reflectio ...

ROYAL SOC CHEMISTRY2020

Ultrafast X-ray Spectroscopy of Heme Proteins

Dominik Kinschel

With the advent of X-ray free-electron lasers (XFELs) time-resolved X-ray spectroscopic techniques have advanced to the femtosecond regime. These are element selective techniques which offer unique insight into the electronic and chemical environment and d ...

EPFL2020

Increased nickel exsolution from LaFe0.8Ni0.2O3 perovskite-derived CO2 methanation catalysts through strontium doping

Oliver Kröcher, Davide Ferri, Patrick Simon Steiger

Perovskite-derived Ni catalysts offer the remarkable benefit of redox stability that allows their regeneration after deactivation through poisoning or Ni particle growth. Here, the catalytic activity of LaFe0.8Ni0.2O3 towards CO2 methanation was improved b ...

ELSEVIER2020

Valorization of biomass derivatives through the conversion of phenol over silica-supported Mo-Re oxide catalysts

Ricardo Javier Serpell Carriquiry

Liquid-phase hydrodeoxygenation of phenol over silica-supported MoOx-ReOx catalysts was investigated at 300 degrees C and 5 MPa of H-2. Mixed-oxides catalysts with similar surface metal density (2.3 atoms of metal per nm(2) of SiO2) but different relative ...

2020

Biological responses at the interface of Ti-doped diamond-like carbon surfaces for indoor environment application

Sami Rtimi

Diamond-like carbon (DLC) and titanium-doped DLC coatings were prepared by hybrid PECVD/direct current magnetron sputtering (DCMS). In this study, we show that the operating conditions of titanium-doped DLC coatings used for implants in surgical devices si ...

SPRINGER HEIDELBERG2020

Insights into the Photocatalytic Bacterial Inactivation by Flower-Like Bi2WO6 under Solar or Visible Light, Through in Situ Monitoring and Determination of Reactive Oxygen Species (ROS)

César Pulgarin, Juan Kiwi, Sami Rtimi, Stefanos Giannakis

This study addresses the visible light-induced bacterial inactivation kinetics over a Bi2WO6 synthesized catalyst. The systematic investigation was undertaken with Bi2WO6 prepared by the complexation of Bi with acetic acid (carboxylate) leading to a flower ...

2020

New Evidence for Ag-Sputtered Materials Inactivating Bacteria by Surface Contact without the Release of Ag Ions: End of a Long Controversy?

Juan Kiwi, Sami Rtimi

The study provides new evidence for Ag-coated polyester (PES) mediating Escherichia colt inactivation by way of genetically engineered E. coli (without porins, from now denoted porinless bacteria). This allows the quantification of the bactericidal kinetic ...

AMER CHEMICAL SOC2020

Evaluation of materials for iodine and technetium immobilization through sorption and redox-driven processes

Wendy Lee Queen, Daniel Teav Sun

Radioactive iodine-129 (I-129) and technetium-99 (Tc-9(9)) pose a risk to groundwater due to their long half-lives, toxicity, and high environmental mobility. Based on literature reviewed in Moore et al. (2019) and Pearce et aL (2019), natural and engineer ...

ELSEVIER2020

From synchrotrons for XFELs: the soft x-ray near-edge spectrum of the ESCA molecule

Christoph Bostedt

A predictive understanding of soft x-ray near-edge absorption spectra of small molecules is an enduring theoretical challenge and of current interest for x-ray probes of molecular dynamics. We report the experimental absorption spectrum for the electron sp ...

IOP Publishing2020