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Concept

Électrode réversible à hydrogène

Publications associées (30)

Demonstration and Characterization of Ladder-Type Conjugated Polymer Photoanode for Direct Light-Driven Water Oxidation

Pauline Bornoz

Energy production is not only a scientific challenge. It also has implications on human and animal health, global environment, and international politics and economics. In order to reduce these effects, the development of a new clean and renewable method i ...

EPFL2017

Reconstitution of [Fe]-hydrogenase using model complexes

Xile Hu, Matthew Wodrich, Dafa Chen, Tao Xu

[Fe]-Hydrogenase catalyses the reversible hydrogenation of a methenyltetrahydromethanopterin substrate, which is an intermediate step during the methanogenesis from CO2 and H-2. The active site contains an iron-guanylylpyridinol cofactor, in which Fe2+ is ...

Nature Publishing Group2015

Enhancing the Performance of a Robust Sol-Gel-Processed p-Type Delafossite CuFeO2 Photocathode for Solar Water Reduction

Kevin Sivula, Nestor Guijarro Carratala, Mathieu Steven Prévot

Delafossite CuFeO2 is a promising material for solar hydrogen production, but is limited by poor photocurrent. Strategies are demonstrated herein to improve the performance of CuFeO2 electrodes prepared directly on transparent conductive substrates by usin ...

Wiley-VCH Verlag Berlin2015

Solar Hydrogen Production by Amorphous Silicon Photocathodes Coated with a Magnetron Sputter Deposited Mo

Christophe Ballif, Xile Hu, Björn Niesen, Carlos Gilberto Morales Guio, Laurent Liardet

Coupling of Earth-abundant hydrogen evolution catalysts to photoabsorbers is crucial for the production of hydrogen fuel using sunlight. In this work, we demonstrate the use of magnetron sputtering to deposit Mo2C as an efficient hydrogen evolution reactio ...

Amer Chemical Soc2015

Hydrogen and Hydrogen Peroxide Formation in Trifluorotoluene-Water Biphasic Systems

Hubert Girault, Jonnathan Cesar Hidalgo Acosta

Hydrogen or hydrogen peroxide can be generated in liquid-liquid biphasic systems, where the organic phase contains sufficiently strong electron donor (whose redox potential is lower than the potential of reversible hydrogen electrode). H2O2 generation with ...

Amer Chemical Soc2014

Study of the Redox Properties of Singlet and Triplet Tris(2,2 '-bipyridine)ruthenium(II) ([Ru(bpy)(3)](2+)) in Aqueous Solution by Full Quantum and Mixed Quantum/Classical Molecular Dynamics Simulations

Ursula Röthlisberger, Ivano Tavernelli, Jérôme Florian Gonthier, Polydefkis Diamantis

The oxidation of ground-state (singlet) and triplet Ru(bpy)(3) were studied by full quantum-mechanical (QM) and mixed quantum/classical (QM/MM) molecular dynamics simulations. Both approaches provide reliable results for the redox potentials of the t ...

2014

Understanding the Role of Underlayers and Overlayers in Thin Film Hematite Photoanodes

Michael Graetzel, Stanley David Tilley, Ludmilla Steier

Recent research on photoanodes for photoelectrochemical water splitting has introduced the concept of under-and overlayers for the activation of ultrathin hematite films. Their effects on the photocatalytic behavior were clearly shown; however, the mechani ...

Wiley-V C H Verlag Gmbh2014

Ruthenium Oxide Hydrogen Evolution Catalysis on Composite Cuprous Oxide Water-Splitting Photocathodes

Michael Graetzel, Morgan Mertens Stefik, Marcel Roland Schreier, Stanley David Tilley

Photocathodes based on cuprous oxide (Cu2O) are promising materials for large scale and widespread solar fuel generation due to the abundance of copper, suitable bandgap, and favorable band alignments for reducing water and carbon dioxide. A protective ove ...

Wiley-Blackwell2014

Hydrogen evolution from a copper(I) oxide photocathode coated with an amorphous molybdenum sulphide catalyst

Michael Graetzel, Xile Hu, Heron Vrubel, Stanley David Tilley, Carlos Gilberto Morales Guio

Concerns over climate change resulting from accumulation of anthropogenic carbon dioxide in the atmosphere and the uncertainty in the amount of recoverable fossil fuel reserves are driving forces for the development of renewable, carbon-neutral energy tech ...

Nature Publishing Group2014

A dip coating process for large area silicon-doped high performance hematite photoanodes

Michael Graetzel, Yelin Hu, Florent Alexandre Boudoire

A facile and low-cost dip-coating process for the deposition of silicon doped hematite films (Si:alpha-Fe2O3) for hydrogen production by solar water splitting in photo-electrochemical cells (PEC) is presented. The precursors include iron nitrate, oleic aci ...

Amer Inst Physics2013