Concept

Système conjugué

Publications associées (32)

Crystallization and Organic Field-Effect Transistor Performance of a Hydrogen-Bonded Quaterthiophene

Rosario Scopelliti, Holger Frauenrath, Anne-Clémence Corminboeuf, Philippe Bugnon, Stéphane Suarez, Riccardo Petraglia, Bilal Özen, Jan Gebers, Piotr De Silva

Crystalline thin films of pi-conjugated molecules are relevant as the active layers in organic electronic devices. Therefore, materials with enhanced control over the supramolecular arrangement, crystallinity, and thin-film morphology are desirable. Herein ...

2020

Even-odd conductance effect in graphene nanoribbons induced by edge functionalization with aromatic molecules: basis for novel chemosensors

Oleg Yazyev, Michele Pizzochero, Kristians Cernevics

We theoretically investigate the electron transport in armchair and zigzag graphene nanoribbons (GNRs) chemically functionalized withp-polyphenyl and polyacene groups of increasing length. Our nearest-neighbor tight-binding calculations indicate that, depe ...

2020

To bend or not to bend, the dilemma of multiple bonds

Michele Pizzochero

Beyond the second row of the periodic table, the nature of the multiple bonds between the elements of the main groups remains yet elusive, and "non-classical" bonding schemes are often invoked for their description. Here, focusing on group 14, we have perf ...

ROYAL SOC CHEMISTRY2019

Amplitude analysis of B-s(0) -> K-S(0) K-+/-pi(-/+) decays

Olivier Schneider, Aurelio Bay, Yiming Li, Guido Haefeli, Frédéric Blanc, Christoph Frei, Tatsuya Nakada, Michel De Cian, Luca Pescatore, Chitsanu Khurewathanakul, Veronica Sølund Kirsebom, François Fleuret, Matthieu Philippe Luther Marinangeli, Minh Tâm Tran, Elena Graverini, Pietro Marino, Federico Leo Redi, Renato Quagliani, Plamen Hristov Hopchev, Federico Betti, Maxime Schubiger, Guido Andreassi, Aravindhan Venkateswaran, Violaine Bellée, Luis Miguel Garcia Martin, Olivier Göran Girard, Vitalii Lisovskyi, Axel Kuonen, Katharina Müller, Preema Rennee Pais, Jian Wang, Pavol Stefko, Mingkui Wang, Tara Nanut, Zhirui Xu, Maria Elena Stramaglia, Yi Zhang, Vladimir Macko, Guillaume Max Pietrzyk, Lei Zhang, Lino Ferreira Lopes, Xiao Yuan, Ho Ling Li, Mark Tobin, Ana Bárbara Rodrigues Cavalcante, Brice Emile Maurin, Niko Neufeld, Vincenzo Battista, Matthew Needham, Marc-Olivier Bettler, Greig Alan Cowan, Maurizio Martinelli, Vladislav Balagura, Donal Patrick Hill, Liang Sun, Mirco Dorigo, Xiaoxue Han, Liupan An, Thibaud Humair, Hang Yin, Maria Vieites Diaz, Tommaso Colombo, Albert Puig Navarro, Evgenii Shmanin, Sebastian Schulte, Dipanwita Dutta, Zheng Wang, Yi Wang, Hans Dijkstra, Gerhard Raven, Peter Clarke, Frédéric Teubert, Giovanni Carboni, Victor Coco, Adam Davis, Paolo Durante, Yu Zheng, Anton Petrov, Maxim Borisyak, Feng Jiang, Zhipeng Tang, Luis Alberto Granado Cardoso, Xuan Li

The fi rst untagged decay-time-integrated amplitude analysis of B 0 s ! K 0 S K decays is performed using a sample corresponding to 3: 0 fb of pp collision data recorded with the LHCb detector during 2011 and 2012. The data are described with an amplitude ...

Springer Nature2019

Saddle-like, π-conjugated, cyclooctatetrathiophene-based, hole-transporting material for perovskite solar cells

Mohammad Khaja Nazeeruddin, Iwan Zimmermann, Giulia Grancini, Inés Garcia Benito, Javier Urieta Mora

A flexible, saddle-like, π-conjugated skeleton composed of four fused thiophene rings forming a cyclooctatetrathiophene (CoTh) with four triphenylamines (CoTh-TTPA) is presented as a hole-transporting material (HTM) for perovskite solar cells. The new HTM ...

Royal Society of Chemistry2019

Shaping light to influence occupants’ experience of space: a kinetic shading system with composite materials

Marilyne Andersen, Anastasios Vassilopoulos, Jan Wienold, Kynthia Chamilothori, Joëlle Baehr-Bruyère

Adaptive kinetic façades are systems capable of modifying their shape to optimize their behavior regarding real time outdoor and indoor conditions. They are typically evaluated based on quantifiable physical parameters such as illuminance levels, with litt ...

IOP Publishing2019

Controlling Ferromagnetic Ground States and Solitons in Thin Films and Nanowires Built from Iron Phthalocyanine Chains

Gabriel Aeppli

Iron phthalocyanine (FePc) is a molecular semiconductor whose building blocks are 1D ferromagnetic chains. It is shown that its optical and magnetic properties are controlled by the growth strategy, obtaining extremely high coercivities of over 1 T and mod ...

WILEY-V C H VERLAG GMBH2019

Cellular Uptake and Intracellular Trafficking of Poly(N-(2-Hydroxypropyl) Methacrylamide)

Anders Meibom, Harm-Anton Klok, Graham Knott, Stéphane Laurent Escrig, Olivier Burri, Arne Seitz, Claudia Battistella, Romain Guiet

Cellular uptake and intracellular trafficking of polymer conjugates or polymer nanoparticles is typically monitored using fluorescence-based techniques such as confocal microscopy. While these methods have provided a wealth of insight into the internalizat ...

American Chemical Society2019

Long-lived Photo-Charges in 1D Helical Organic Semiconductor Nanostructures

Regina Judith Hafner

The formation of photoexcited states in organic semiconductors, their separation into long-lived or stable charge carriers, as well as the charge transport are critical processes relevant to several important research fields and emerging technologies. Whil ...

EPFL2018

Lattice Energy as Emerging General Parameter Describing Ionic Organic Semiconducting Materials Properties

Donatas Gesevicius

Cyanine dyes represent a class of ionic functional materials used by a broad heterogeneous science community contain-ing biologists, chemists, physicists and materials scientists. Their diverse application opportunities are ranging from fluorescence marker ...

EPFL2018

Lateral Intermolecular Electronic Interactions of Diketopyrrolopyrrole D−π–A Solar Dye Sensitizers Adsorbed on Mesoporous Alumina

Jacques-Edouard Moser, Ulf Anders Hagfeldt, Heewon Bahng

The development of push−pull organic dyes utilizing the donor−(π-conjugated bridge)−acceptor (D−π−A) motif has induced a paradigm shift in the design of efficient nanocrystalline dye-sensitized solar cells (DSSCs), offering control over the aesthetic prope ...

2018

Molecular Engineering Strategies for Morphology Control in Organic Semiconductors for Optoelectronics

Muhammad Aiman Bin Rahmanudin Hamdan

It is understood that the optoelectronic performance of organic electronic devices is determinant on the macroscopic solid state self-assembly of organic semiconductors (OSC), which is driven by the supramolecular Ï -Ï stacking interactions between the co ...

EPFL2018