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Concept

Théorie SIT

Publications associées (10)

Effect of a temperature gradient on the screening properties of ionic fluids

Andrea Grisafi, Federico Grasselli

The electrostatic screening properties of ionic fluids are of paramount importance in countless physical processes. Yet the screening behavior of ionic conductors out of thermal equilibrium has to date mainly been studied in the context of thermoelectric p ...

AMER PHYSICAL SOC2023

Detailed Analysis of Estimated pH, Activity Coefficients, and Ion Concentrations between the Three Aerosol Thermodynamic Models

Athanasios Nenes

In this work, we utilize a rich set of simulated and ground-based observational data in Tianjin, China to examine and compare the differences in aerosol acidity and composition predicted by three popular thermodynamic equilibrium models: ISORROPIA II, the ...

AMER CHEMICAL SOC2019

Effects of water-soluble organic carbon on aerosol pH

Athanasios Nenes

Water-soluble organic carbon (WSOC) is a ubiquitous and significant fraction of fine particulate matter. Despite advances in aerosol thermodynamic equilibrium models, there is limited understanding on the comprehensive impacts of WSOC on aerosol acidity (p ...

Copernicus GmbH2019

The Jones-Ray Effect Reinterpreted: Surface Tension Minima of Low Ionic Strength Electrolyte Solutions are caused by Electric Field Induced Water-Water Correlations

Sylvie Roke, Yixing Chen, Halil Ibrahim Okur

The surface tension of electrolyte solutions exhibits a minimum at millimolar electrolyte concentrations and then rises with increasing concentration. This minimum, known as the Jones-Ray effect, has been hotly debated over the past 80 years. If not consid ...

Elsevier2017

Characterization of Solid-Liquid Interfaces with High-Resolution Atomic Force Microscopy

Maria Ricci

Solid-liquid interfaces are ubiquitous. Despite the unquestioned relevance, many scientific research fields rely on simplified or macroscopic descriptions, discarding the molecular nature of the constituents. However, it is the specific molecular interacti ...

EPFL2015

Temperature Sensitivity of Nanochannel Electrical Conductance

Philippe Renaud, Arnaud Bertsch, Mojtaba Taghipoor

Electrical measurement is a widely used technique for the characterization of nanofluidic devices. The electrical conductivity of electrolytes is known to be dependent on temperature. However, the similarity of the temperature sensitivity of the electrical ...

Amer Chemical Soc2015

Modelling early age hydration kinetics of alite

Karen Scrivener, Aditya Kumar

The modelling platform mu ic [1] has been used to investigate the mechanisms occurring during the hydration of alite. It is shown that it is possible to obtain a good simulation of the hydration kinetics through the implementation of two mechanisms: a diss ...

Pergamon-Elsevier Science Ltd2012

Simulation tool for variably saturated flow with comprehensive geochemical reactions in two and three-dimensional domains

David Andrew Barry, Laurin Wissmeier

We present a software tool for simulations of flow and multi-species solute transport in two and three-dimensional domains in combination with comprehensive intra-phase and inter-phase geochemistry. The software uses IPhreeqc, the coupling version of the g ...

2011

pH prediction and control in bioprocesses using mid-infrared spectroscopy

Ian William Marison, Jonas Schenk

An on-line pH monitoring method based on mid-infrared spectroscopy relevant to bioprocesses is presented. This approach is non-invasive and does not require the addition of indicators or dyes, since it relies on the analysis of species of common buffers us ...

2008

Interfacial interactions and colloid retention under steady flows in a capillary channel

Dani Or

Colloidal interfacial interactions in a capillary channel under different chemical and flow conditions were studied using confocal microscopy. Fluorescent latex microspheres (1.1 mu m) were employed as model colloids and the effects of ionic strength and f ...

Elsevier2006