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Concept

Spectrométrie de masse à résonance cyclonique ionique

Publications associées (26)

Alignment of ND3 molecules in dc-electric fields

Andreas Osterwalder, Junwen Zou, Viet Le Duc

The control of movement and orientation of gas-phase molecules has become the focus of many research areas in molecular physics. Here, ND3 molecules are polarized in a segmented, curved electrostatic guide and adiabatically aligned inside a rotatable mass ...

Aip Publishing2024

Adding Color to Mass Spectra of Biopolymers: Charge Determination Analysis (CHARDA) Assigns Charge State to Every Ion Peak

Yury Tsybin, Natalia Gasilova, Laure Menin, Anton Kozhinov, Konstantin Nagornov

Traditionally, mass spectrometry (MS) output is the ion abundance plotted versus the ionic mass-to-charge ratio m/z. While employing only commercially available equipment, Charge Determination Analysis (CHARDA) adds a third dimension to MS, estimating for ...

Amer Chemical Soc2024

Using Hadamard Transform Multiplexed IR Spectroscopy Together with a Segmented Ion Trap for the Identification of Mobility-Selected Isomers

Thomas Rizzo, Ahmed Ben Faleh, Stephan Warnke, Vasyl Yatsyna, Ali H Abikhodr

The high isomeric complexity of glycans makes them particularly difficult to analyze. While ultra-high-resolution ion mobility spectrometry(IMS) can offer rapid baseline separation of many glycan isomers,their unambiguous identification remains a challengi ...

2023

Investigating the bioaccumulation potential of anionic organic compounds using a permanent rainbow trout liver cell line

Kristin Schirmer, Fabian Gerhard Peter Balk

Permanent rainbow trout (Oncorhynchus mykiss) cell lines represent potential in vitro alternatives to experiments with fish. We here developed a method to assess the bioaccumulation potential of anionic organic compounds in fish, using the rainbow trout li ...

PERGAMON-ELSEVIER SCIENCE LTD2023

Identification of human milk oligosaccharide positional isomers by combining IMS-CID-IMS and cryogenic IR spectroscopy

Thomas Rizzo, Ahmed Ben Faleh, Stephan Warnke, Vasyl Yatsyna, Ali H Abikhodr

High-resolution ion mobility spectrometry (IMS) coupled with cryogenic infrared spectroscopy has proven to be a powerful technique for the identification of oligosaccharides. However, the need for an extensive database, combined with the scarcity of pure s ...

2023

The competing effects of wave amplitude and collisions on multi-ion species suppression of stimulated Brillouin scattering in inertial confinement fusion Hohlraums

Stephan Brunner

Reduction in stimulated Brillouin scattering (SBS) from National Ignition Facility Hohlraums has been predicted through the use of multi-ion species materials on Hohlraum walls. This approach to controlling SBS is based upon introducing a lighter ion speci ...

2023

High-useful yield and new autoionizing state of resonantly ionized tungsten

Reto Georg Trappitsch

In order to measure tungsten isotopic composition in presolar stardust grains that contain a limited number of atoms, we developed a new three-photon three-color resonance ionization scheme using titanium:sapphire lasers and the Laser Ionization of Neutral ...

ROYAL SOC CHEMISTRY2022

Sheath collapse at critical shallow angle due to kinetic effects

Alessandro Geraldini

The Debye sheath is known to vanish completely in magnetised plasmas for a sufficiently small electron gyroradius and small angle between the magnetic field and the wall. This angle depends on the current onto the wall. When the Debye sheath vanishes, ther ...

IOP Publishing Ltd2022

Low and high frequency electromagnetic forces: numerical modelling and practical applications

Marco Riccardi

The understanding and manipulation of nanoscale analytes is a central theme in nanotechnology and has been one of the main driving forces behind the development of this field as we know it today. Furthermore, such a technology has the potential to also rev ...

EPFL2022

Helicon wave plasma generated by a resonant birdcage antenna: magnetic field measurements and analysis in the RAID linear device

Ivo Furno, Alan Howling, Philippe Frédérique Bruno Guittienne, Rémy Jacquier, Riccardo Agnello

This paper describes a helicon-wave-sustained plasma generated by a novel birdcage antenna with cosine azimuthal current distribution. The resonant birdcage source maintains a stable intense plasma column from low (300 W) to high (10 kW) steady-state RF po ...

2021

Nonlinear kinetic simulation study of the ion-ion streaming instability in single- and multi-ion species plasmas

Stephan Brunner

The nonlinear evolution of the ion-ion streaming instability (IISI) is studied using numerical techniques novel to this problem that afford direct insight into the evolution of the particle distributions of each species. During the linear phase of the inst ...

2021

Numerics and computation in gyrokinetic simulations of electromagnetic turbulence with global particle-in-cell codes

Laurent Villard, Alberto Bottino, Emmanuel Lanti

Electromagnetic turbulence is addressed in tokamak and stellarator plasmas with the global gyrokinetic particle-in-cell codes ORB5 (E Lanti et al, Comp. Phys. Comm., 251, 107072 (2020)) and EUTERPE (V Kornilov et al, Phys. Plasmas, 11, 3196 (2004)). The la ...

2021

Analyzing glycans cleaved from a biotherapeutic protein using a combination of ion mobility spectrometry and cryogenic ion spectroscopy

Natalia Yalovenko

The characterization of biomolecules plays a central role in biomedical research. The development of state-of-the-art technologies is needed to make such analyses faster, more sensitive, and more accurate. While mass spectrometry continues to play a centra ...

EPFL2021

Wall conditioning in fusion devices with superconducting coils

Stefano Coda

Wall conditioning is essential in tokamak and stellarator research to achieve plasma performance and reproducibility. This paper presents an overview of recent conditioning results, both from experiments in present devices and modelling, in view of devices ...

IOP PUBLISHING LTD2020

Using SLIM-Based IMS-IMS Together with Cryogenic Infrared Spectroscopy for Glycan Analysis

Thomas Rizzo, Ahmed Ben Faleh, Stephan Warnke, Priyanka Bansal, Ali H Abikhodr, Vasyl Yatsyna, Natalia Yalovenko

The isomeric heterogeneity of glycans poses a great challenge for their analysis. While combining ion mobility spectrometry (IMS) with tandem mass spectrometry is a powerful means for identifying and characterizing glycans, it has difficulty distinguishing ...

2020

Efficacy of pulsed electromagnetic fields and electromagnetic fields tuned to the ion cyclotron resonance frequency of Ca2+ on chondrogenic differentiation

Philippe Renaud, Harald Van Lintel

Previous studies provide strong evidence for the therapeutic effect of electromagnetic fields (EMFs) on different tissues including cartilage. Diverse exposure parameters applied in scientific reports and the unknown interacting mechanism of EMF with biolo ...

WILEY2019

Nonlinear Gyrokinetic Coulomb Collision Operator

Paolo Ricci, Rogério Manuel Cabete De Jesus Jorge, Baptiste Jimmy Frei

A gyrokinetic Coulomb collision operator is derived, which is particularly useful to describe the plasma dynamics at the periphery region of magnetic confinement fusion devices. The derived operator is able to describe collisions occurring in distribution ...

Cambridge University Press2019

Ultraslow radiative cooling of Cn- (n=3-5)

Eduardo Carrascosa Casado

Ultraslow radiative cooling lifetimes and adiabatic detachment energies for three astrochemically relevant anions, Cn- (n = 3-5), are measured using the Double ElectroStatic Ion Ring ExpEriment (DESIREE) infrastructure at Stockholm University. DESIREE main ...

AMER INST PHYSICS2019

Analysis of functional groups in atmospheric aerosols by infrared spectroscopy: systematic intercomparison of calibration methods for US measurement network samples

Satoshi Takahama, Matteo Reggente

Peak fitting (PF) and partial least squares (PLS) regression have been independently developed for estimation of functional groups (FGs) from Fourier transform infrared (FTIR) spectra of ambient aerosol collected on Teflon filters. PF is a model that quant ...

Copernicus GmbH2019

Combining ultra-high resolution ion-mobility spectrometry with cryogenic IR spectroscopy for the study of biomolecular ions

Thomas Rizzo, Ahmed Ben Faleh, Stephan Warnke, Robert Paul Pellegrinelli, Natalia Yalovenko

Double-resonance spectroscopic schemes in combination with cryogenic ion traps are the go-to techniques when isomer-specific high-resolution spectra are required for analysis of molecular ions. Their limitation lies in the requirement for well-resolved, is ...

2019