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Concept

Hexacarbonyle de molybdène

Publications associées (4)

Mechanistic Studies on the Formation of eta(2)-Diphosphine (eta(6)-p-cymene)ruthenium(II) Compounds

Paul Joseph Dyson, Gabor Laurenczy, Céline Fellay

A new range of pendent diphosphine (η6-p-cymene)ruthenium(II) complexes, [RuCl(PPh3)(η1-(P-P))(η6-p-cymene)]PF6 (P-P = dppm, cis-PPh2CHCHPPh2

2007

Biomimetic catalysis with immobilized transition metal complexes

Alexander Schiller

The tetradentate chelate ligand tris[(1-vinylimidazol-2-yl)methyl]amine (10) was synthesized in five steps from commercially available starting materials. Upon reaction with MCl2 (M = Zn, Cu, Ni, Co) in the presence of NH4PF6, the complexes [M(10)Cl]PF6 (M ...

EPFL2006

Highly cross-linked polymers containing N,N ',N ''-chelate ligands for the Cu(II)-mediated hydrolysis of phosphoesters

Rosario Scopelliti, Kay Severin, Alexander Schiller

Three immobilized Cu(II) complexes were generated by the following: (a) homopolymerization of the N,N',N '' chelate ligand tris[2-(1-vinylimidazolyl)]phosphine (1) and subsequent metalation with CuCl2; (b) copolymerization of 1 with ethyleneglycol dimethac ...

2005

Synthesis and characterization of organometallic ionic liquids and a heterometallic carbene complex containing the chromium tricarbonyl fragment

Paul Joseph Dyson, Rosario Scopelliti

Direct reaction between [Cr(CO)6] and arenes with ionic substituents affords the corresponding arene-chromium tricarbonyl complexes, [Cr(CO)3(arene)], in only modest yield. In contrast, these complexes can be prepared in pure form in ...

2005