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Concept

Homo erectus

Publications associées (12)

Benzothiadiazole Aryl-amine Based Materials as Efficient Hole Carriers in Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Manuel Alejandro Méndez Agudelo, Cristina Roldán Carmona

Four hole transport materials (HTMs) based on a benzothiadiazole (BT) central core have been synthesized and successfully employed in triple-cation mixed-halide perovskite solar cells (PSCs), reaching 18.05% solar to energy conversion efficiency. The synth ...

AMER CHEMICAL SOC2020

Hole transporting materials for perovskite solar cells and a simple approach for determining the performance limiting factors

Mohammad Khaja Nazeeruddin, Tom Theodorus Antonius Lummen, Iwan Zimmermann

The synthesis and characterization of three novel HTMs with different highest occupied molecular orbital (HOMO) energy levels and their performances in MAPbI(3)-based devices in comparison with Spiro-OMeTAD is reported. Without systematic optimization, the ...

Royal Society of Chemistry2020

Heterobimetallic Ru(mu-dppm)Fe and homobimetallic Ru(mu-dppm)Ru complexes as potential anti-cancer agents

Paul Joseph Dyson, Lucinda Kate Batchelor

Two heterobimetallic mu-dppm bridged Fe,Ru complexes, [(eta(6)-Arene)RuCl2(mu-dppm)Fe(CO)I(eta(5)-C5H5)] (Ar - C6H6 (1) and p-cymene (2), dppm-1,1-bis(diphenylphosphino)methane) were obtained in a facile reaction between [Fe(eta(5)-C5H5)I(CO)(kappa(1)-dppm ...

2019

Electrochemical potential window of battery electrolytes: the HOMO-LUMO misconception

Hubert Girault, Pekka Eero Peljo

A widespread misconception in the lithium ion battery literature is the equality of the energy difference of HOMO and LUMO of the solvent with the electrochemical stability window. HOMO and LUMO are concepts derived from approximated electronic structure t ...

2018

2-homopiperazine-1-yl-4h-1,3-benzothiazine-4-one derivatives and process for the preparation of 2- (homo)piperazine 1,3-benzothiazine-4-one hydrochlorides

2-homopiperazine-1-yl-4H-l, 3 -bensothiazine-4-one derivatives of formula (I) are provided. They are useful in the treatment of bacterial infections, in particular tuberculosis, buruli ulcer and leprosy. A process for the preparation of 2- (homo)piperazine ...

2016

Strategy to Boost the Efficiency of Mixed-Ion Perovskite Solar Cells: Changing Geometry of the Hole Transporting Material

Ulf Anders Hagfeldt, Nikolaos Vlachopoulos

The hole transporting material (HTM) is an essential component in perovskite solar cells (PSCs) for efficient extraction and collection of the photoinduced charges. Triphenylamine- and carbazole-based derivatives have extensively been explored as alternati ...

Amer Chemical Soc2016

Structured light enables biomimetic swimming and versatile locomotion of photoresponsive soft microrobots

Tian Qiu

Microorganisms move in challenging environments by periodic changes in body shape. In contrast, current artificial microrobots cannot actively deform, exhibiting at best passive bending under external fields. Here, by taking advantage of the wireless, scal ...

Nature Publishing Group2016

New pyrido[3,4-b]pyrazine-based sensitizers for efficient and stable dye-sensitized solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Jacques-Edouard Moser, Pascal Comte, Thomas Moehl, Mateusz Barnaba Wielopolski

A series of new pyrido[3,4-b]pyrazine-based organic sensitizers (PP-I and APP-I–IV) containing different donors and p-spacers have been synthesized and employed in dye-sensitized solar cells (DSSCs). The absorption spectra properties of dyes are analysed b ...

Royal Soc Chemistry2014

Near-infrared absorbing unsymmetrical Zn(II) phthalocyanine for dye-sensitized solar cells

Mohammad Khaja Nazeeruddin

Unsymmetrical Zn phthalocyanine consisting of six S-aryl groups at alpha-positions and a carboxy anchoring group at beta-position has been designed and synthesized for dye-sensitized solar cells (DSCs) applications. The unsymmetrical phthalocyanine has bee ...

Elsevier2013

Physico-chemical properties and photo-reactivity relationship for para-substituted phenols in photo-assisted Fenton system

César Pulgarin, Félicien Mazille

The reactivity of phenolic compounds can be drastically affected by the electronic nature of the substituting groups. In this work, the effect of physico-chemical properties on the reactivity via photo-assisted Fenton catalysis is reported for several para ...

2010

RAFT homo- and copolymerization of N-acryloyl-morpholine, piperidine, and azocane and their self-assembled structures

Jeffrey Alan Hubbell, Davide Demurtas, Yun Suk Jo

We present new polymeric amphiphiles derived from N-acryloyl derivatives of the cyclic secondary amines: morpholine, piperidine, and azocane polymerized by reversible addition -fragmentation transfer (RAFT) polymerization. Both homopolymerization and block ...

American Chemical Society2008

Cationic P-S-X cages (X=Br, I)

The first condensed-phase preparation of ternary P-Ch-X cations (Ch=O-Te, X=F-I) is reported: [P5S3X2]+, [P5S2X2]+, and [P4S4X]+ (X=Br, I). [P5S3X2]+ is formed from the reaction of the Ag+/PX3 reagent with P4S3. The [P5S3X2]+ ions have a structure that is ...

2006