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Publications associées (22)

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The capture technology matters: Composition of municipal wastewater solids drives complexity of microbial community structure and volatile fatty acid profile during anaerobic fermentation

Pierre Rossi, Arnaud Michel Gelb

The production of volatile fatty acids (VFAs) represents a relevant option to valorize municipal wastewater (MWW). In this context, different capture technologies can be used to recover organic carbon from wastewater in form of solids, while pre-treatment ...

2022

Cellulose phosphorylation comparison and analysis of phosphorate position on cellulose fibers

David Lyndon Emsley, Jayasubba Reddy Yarava

Chemical modifications of cellulose fibers as pretreatment for cellulose nanofibrils (CNF) production have been investigated to improve the production process and the quality of obtained cellulosic nanomaterial. In this study, phosphorylation of cellulose ...

ELSEVIER SCI LTD2020

Adsorption of HPDX and CaHPOx (x=1, ...,4) molecules on anatase TiO2 (001) surfaces

Alfonso Baldereschi

perform DFT calculations within the COSMO framework to study the adsorption properties of the CaHPOx (x = 1,...,4) phosphate family, and of the related HPOx acids, on a paradigmatic anatase (001) surface. Of particular interest is CaHPO4, a precursor of hy ...

ELSEVIER SCIENCE BV2019

Hydrogen storage in the carbon dioxide/formic acid system, using homogeneous iron(II)-phosphine catalysts in aqueous solution

Mickael Montandon-Clerc

The valorization of carbon dioxide and its transformation into useful chemicals is essential as mankind consumes more and more fossil fuels, thus producing equivalent wastes. The storage of hydrogen, a promising energy carrier, is also of great interest in ...

EPFL2018

The spatial impact of socio-technical transitions – The case of phosphorus recycling as a pilot of the circular economy

Claudia Rebeca Binder Signer

Socio-technical innovations for the recovery of phosphorus (P) from sewage sludge (ashes) and the recycling of the secondary material in the agri-food system have been gaining prominent roles in current debates on circular economy. While research has been ...

2018

Selective Catalytic Reduction of NOx

Oliver Kröcher

The deactivation pathways of sulfonated carbon catalysts prepared from different carbons were studied during the aqueous‐phase hydrolysis of cellobiose under continuous‐flow conditions. The sulfonation of carbon materials with a low degree of graphitizatio ...

2018

Influence of TiO2 phase composition on the photocatalytic activity of TiO2/MWCNT composites prepared by combined sol-gel/hydrothermal method

László Forró, Arnaud Magrez, Endre Horvath

Titanium dioxide/multiwall carbon nanotube (TiO2/MWCNT) composites were prepared by sol-gel method with hydrolysis of titanium alkoxide precursor followed by crystallization via hydrothermal treatment at different acid concentrations. Transmission electron ...

Elsevier Science Bv2016

Influence of calcium to silica ratio on aluminium uptake in calcium silicate hydrate

Karen Scrivener, Émilie Michèle L'Hôpital

Aluminium uptake in calcium silicate hydrate (C-S-H) was studied at different Ca/Si ratios from 0.6 to 1.6 at 20 degrees C. Aluminium incorporation in C-S-H depends on the total amount of aluminium present in the sample. At low Al/Si ratio (

Pergamon-Elsevier Science Ltd2016

Quantitative aqueous phase formic acid dehydrogenation using iron(II) based catalysts

Gabor Laurenczy, Andrew Francis Dalebrook, Mickael Montandon-Clerc

We present here the results of our investigation on aqueous phase formic acid (FA) dehydrogenation using non-noble metal based pre-catalysts. This required the synthesis of m-trisulfonated-tris[2-(diphe nylphosphino)ethyl]phosphine sodium salt (PP3TS) as a ...

Elsevier2016

Clumped isotope fractionation during phosphoric acid digestion of carbonates at 70°C

Marie Estelle Solange Violay

The application of clumped isotopes (Delta(47)) in carbonate minerals as a sensitive temperature proxy in paleo-environments depends on a well-constrained clumped isotope fractionation for the necessary step of phosphoric acid digestion of the carbonate mi ...

Elsevier2016

Mycobacterium tuberculosis Phosphate Uptake System Component PstA2 Is Not Required for Gene Regulation or Virulence

John McKinney, Anna De Graff Tischler

The Mycobacterium tuberculosis genome encodes two complete high-affinity Pst phosphate-specific transporters. We previously demonstrated that a membrane-spanning component of one Pst system, PstA1, was essential both for M. tuberculosis virulence and for r ...

Public Library of Science2016

Calorimetric and Spectroscopic Studies on the Solvation Energetics for H2 Storage in the CO2/HCOOH System

Gabor Laurenczy, Cornel Fink

Solvents play a crucial role in many chemical reactions and additives can be used to shift the reaction equilibrium. Herein we study the enthalpy of mixing for selected solvents (aqueous, organic) and basic additives (amines, aqueous KOH) when mixed with f ...

Royal Society of Chemistry2016

Incorporation of aluminium in calcium-silicate-hydrates

Karen Scrivener, Émilie Michèle L'Hôpital

Calcium silicate hydrate (C-S-H) was synthetized at 20 degrees C to investigate the effect of aluminium uptake (Al/Si = 0-0.33) in the presence and absence of alkalis on the composition and the solubility of a C-S-H with a Ca/Si equal to 1.0. C-S-H incorpo ...

Pergamon-Elsevier Science Ltd2015

Intramolecular symmetry-adapted perturbation theory with a single-determinant wavefunction

Anne-Clémence Corminboeuf, Antonio Prlj, Jérôme Florian Gonthier, Ewa Maria Pastorczak

We introduce an intramolecular energy decomposition scheme for analyzing non-covalent interactions within molecules in the spirit of symmetry-adapted perturbation theory (SAPT). The proposed intra-SAPT approach is based upon the Chemical Hamiltonian of May ...

American Institute of Physics2015

Decamethylruthenocene Hydride and Hydrogen Formation at Liquid|Liquid Interfaces

Hubert Girault, Pekka Eero Peljo, Manuel Alejandro Méndez Agudelo, Micheal Diarmaid Scanlon, Thomas James Stockmann, Lucie Josette Renée Rivier

The formation and the dissociation of metal hydrides are key steps within the hydrogen evolution reaction (HER) pathway for photochemical water splitting, but also impacts a wide range of other catalytic, industrial, and biochemical reactions. Herein, we d ...

American Chemical Society2015

Aluminium and alkali uptake in calcium silicate hydrates (C-S-H)

Émilie Michèle L'Hôpital

Calcium silicate hydrate (C-S-H) is the main hydrate phase in Portland cements. Its composition varies depending on the Ca/Si ratio and on the presence of other ions such as aluminium (called CA- S-H) or alkalis. This thesis aimed to study the compositi ...

EPFL2014

Ethanol and lignin production from Brazilian empty fruit bunch biomass

Edgard Gnansounou, Jegannathan Kenthorai Raman

Brazil Government is promoting palm plantations to use degraded land for biofuels. Palm production is expected to increase 35 per cent in future and there would be profuse biomass available that needs to be handled efficiently. Therefore, in this study the ...

Elsevier2014

A microfluidic approach to synthesizing high-performance microfibers with tunable anhydrous proton conductivity

Philippe Renaud, Arnaud Bertsch, Mohammad Mahdi Hasani-Sadrabadi, Jules John Vandersarl

Here, we demonstrate a new approach for the synthesis of ion exchange microfibers with finely tuned anhydrous conductivity. This work presents microfluidics as a system to control the size and phosphoric acid (PA) doping level of the polybenzimidazole (PBI ...

Royal Society of Chemistry2013

High aspect ratio etching of nanopores in PECVD SiC through AAO mask

Jürgen Brugger, Songmei Wu, Vaida Auzelyte, Wei Tang

We present in this work the fabrication of high aspect ratio nanopores in 500 nm PECVD SiC films through AAO (anodic aluminum oxide) mask. The initial AAO thin film is 180 nm thick and the diameter of nanopores is 33 ± 7 nm. We have used three plasma chemi ...

IEEE2013

Biphasic Model Describing Soybean Oil Epoxidation with H2O2 in Continuous Reactors

Albert Renken

Epoxidized soybean oil (ESBO) is produced in industry by reacting soybean oil, at 60-70 degrees C, with hydrogen peroxide in the presence of formic or acetic acid. A small amount of sulphuric or phosphoric acid is necessary to catalyze the oxidation of the ...

2012