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Concept

Hydrodynamic voltammetry

Publications associées (31)

Probing charge transfer processes at p-GaAs electrodes under weak optical excitation

Jean-Philippe Ansermet, Christophe Roussel, Mika Antero Tamski, Felix Blumenschein

The p-GaAs photocathode/acetonitrile interface was characterised in the dark and with tens of mu W/cm(2) laser powers at 830 nm wavelength, using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Two redox mediators were used that p ...

2019

Double bridged mu(2)-Halide Cu (II) complexes for the electrocatalytic reduction of CO2

Kurt Schenk, Farzaneh Fadaei Tirani, Jun Gu

Two dicopper (II) complexes of general formula CuLX2 {L = 2, 5-diphenyl-3, 4(2-pyridyl) cyclopenta-2, 4-dien-1-one, X = Cl (1) or Br (2)} have been synthesized and characterized by elemental analysis, IR, UV-Vis spectroscopic methods. The crystal stru ...

2019

Perovskite Solar Cells Based on Oligotriarylamine Hexaarylbenzene as Hole-Transporting Materials

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt

A cobalt-catalyzed cyclotrimerization of bis(aryl)alkyne is used as an innovative tool to obtain hole-transport materials (HTMs). The novel HTM containing six units of oligotriarylamine (HAB1), characterized by UV-vis, cyclic voltammetry, DFT, and thermogr ...

AMER CHEMICAL SOC2019

Fast Procedures for the Electrodeposition of Platinum Nanostructures on Miniaturized Electrodes for Improved Ion Sensing

Giovanni De Micheli, Sandro Carrara, Irene Taurino, Francesca Criscuolo

Nanostructured materials have attracted considerable interest over the last few decades to enhance sensing capabilities thanks to their unique properties and large surface area. In particular, noble metal nanostructures offer several advantages including h ...

2019

3D-Integration Of Printed Electrochemical Sensors In Pet Microfluidics For Biochemical Sensing

Danick Briand, Peter Van der Wal, Silvia Demuru

This paper presents a novel process for screen printed electrode fabrication, functionalization and integration in a polyethylene terephthalate (PET) fluidics system for electrochemical analysis. The innovative components utilized are: 1. 3D Through-Foil V ...

IEEE2019

Standard ion transfer potential at the water|butyronitrile interface

Hubert Girault, Astrid Johana Olaya Avendano, Victor Costa Bassetto, Julieta Soledad Riva

Butyronitrile is an organic solvent stable enough to be used in photochemical reactions at liquid/liquid interfaces. However, it provides a rather short polarisation window making the analysis of ion transfer across the water|butyronitrile interface challe ...

2019

Spin-Dependent Processes at Electrodes Detected by Simultaneously Performed EPR, Electrochemistry and EDMR

Felix Blumenschein

The electrically detected magnetic resonance (EDMR) results presented in this thesis demonstrate a spin dependence of the charge transfer between an electrode and an electrolyte. These results were found using simultaneous detection of continuous wave elec ...

EPFL2019

Triarylamine-based hydrido-carboxylate rhenium(i) complexes as photosensitizers for dye-sensitized solar cells

Ulf Anders Hagfeldt, Thomas Moehl, Kazuteru Nonomura

Two new dyes based on a dinuclear rhenium complex and (E)-3-(5-(4-(bis(2,4-dibutoxy-[1,1-biphenyl]-4-yl)amino)phenyl)thiophen-2-yl)-2-cyanoacrylic acid (namely D35) have been investigated as sensitizers for dye sensitized solar cells (DSSCs). Two different ...

ROYAL SOC CHEMISTRY2019

Mixed gold and platinum nanostructured layers for all-solid-state ion sensors

Giovanni De Micheli, Sandro Carrara, Danilo Demarchi, Irene Taurino, Francesca Criscuolo

The great interest in portable and wearable monitoring systems has promoted in recent years a major expansion of all-solid-state Ion-Selective Electrodes (ISEs). Nanostructured Solid-Contacts (SCs) have shown a promising potential in order to eliminate the ...

IEEE2018

Pyridination of hole transporting material in perovskite solar cells questions the long-term stability

Mohammad Khaja Nazeeruddin, Sanghyun Paek, Natalia Gasilova, Kasparas Rakstys

In this work, for the first time, reactive radical-cation species present in hole-transporting materials were shown to react with tert-butylpyridine additive, routinely used in hole transporting layer composition. As a result, new pyridinated products were ...

Royal Society of Chemistry2018

Synthesis and Characterization of High-Photoactivity Electrodeposited Cu2O solar absorber by photoelectrochemistry and ultrafast spectroscopy

Michael Graetzel, Jacques-Edouard Moser, Jan Cornelius Brauer, Adriana Paracchino

We present a systematic study on the effects of electrodeposition parameters on the photoelectrochemical properties of Cu2O. The influence of deposition variables (temperature, pH, and deposition current density) on conductivity has been widely explored in ...

2012