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Concept

Munition au phosphore blanc

Publications associées (20)

Global emergent responses of stream microbial metabolism to glacier shrinkage

Tom Ian Battin, Hannes Markus Peter, Tyler Joe Kohler, Massimo Bourquin, Michail Styllas, Nicola Deluigi

Most cryospheric ecosystems are energy limited. How their energetics will respond to climate change remains largely unknown. This is particularly true for glacier-fed streams, which interface with the cryosphere and initiate some of Earth's largest river s ...

Nature Portfolio2024

Electronic Structure of Few-Layer Black Phosphorus from & mu;-ARPES

Nicola Marzari, Marco Gibertini, Samuel Poncé, Christophe Berthod

Black phosphorus (BP) stands out among two-dimensional(2D) semiconductorsbecause of its high mobility and thickness dependent direct band gap.However, the quasiparticle band structure of ultrathin BP has remainedinaccessible to experiment thus far. Here we ...

AMER CHEMICAL SOC2023

Developing the Catalytic Applications of 1,3,2-Diazaphospholenes

John Henry Reed

The development of new catalytic methods for organic synthesis is a critical endeavour in order to obviate the economic and ecological drawbacks of stoichiometric organic synthesis. While catalysis can offer significant advantages in terms of atom-economy, ...

EPFL2021

Adapting the dynamic LakeMab model to simulate seasonal variations of phosphorus concentration in reservoirs: a case study of Lake Bultiere (France)

Camille Roland Marie Minaudo

Controlling phosphorus is fundamental to limit the risk of eutrophication of continental aquatic ecosystems. Integrated modelling of its concentration in the aquatic continuum requires specific tools for water bodies. However, although simple static empiri ...

2020

Recent progress in black phosphorus nanostructures as environmental photocatalysts

Sami Rtimi

Hazardous chemicals excruciatingly contaminated water, air, and soil for the past few decades. Eco-friendly techniques to clean and or destroy these harmful chemicals is an urgent requirement at this moment. In this direction, a large number of methodologi ...

ELSEVIER SCIENCE SA2020

Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays

Andrea Cannizzo, Giulia Fulvia Mancini, Camila Bacellar Cases Da Silveira, Victoria Kabanova

OLED technology beyond small or expensive devices requires light-emitters, luminophores, based on earth-abundant elements. Understanding and experimental verification of charge transfer in luminophores are needed for this development. An organometallic mul ...

Nature Publishing Group2020

Photocarrier-induced band-gap renormalization and ultrafast charge dynamics in black phosphorus

Majed Chergui, Marco Grioni, Alberto Crepaldi, Michele Puppin, Gianmarco Gatti, Steven Roth

With its tunable band-gap and its unique optical and electronic properties black phosphorus (BP) opens exciting opportunities for optoelectronic nanotechnology. The band-gap extends from the visible to the mid-infrared spectral range, as a function of samp ...

2019

Importance of mixotrophic flagellates during the ice-free season in lakes located along an elevational gradient

Hannes Markus Peter

Mixotrophy seems to be widespread among phytoplankton, but whether this strategy is more relevant in oligotrophic lakes remains unclear. Here, we tested the hypothesis that the relative abundance of mixotrophic flagellates in lakes increases along an eleva ...

Springer2019

Reduction of Fermi level pinning at Cu-BP interfaces by atomic passivation

Xiao Zhou

Black phosphorus (BP) is a semiconducting material with a direct finite band gap in its monolayer, attracting intense attention for its application in field-effect transistors. However, strong Fermi level pinning (FLP) has been observed for contacts betwee ...

2019

Characterization of phosphorus species distribution in waste activated sludge after anaerobic digestion and chemical precipitation with Fe3+ and Mg2+

Ho Ling Li, Jie Zhang

Given the great concern about phosphorus (P) resource depletion, it's promising to recover P from waste activated sludge (WAS) especially for agricultural application. To this end, it's necessary to understand the P speciation and fractionation within the ...

ELSEVIER SCIENCE SA2019

MOF-Derived Cobalt Phosphide/Carbon Nanocubes for Selective Hydrogenation of Nitroarenes to Anilines

Emad Oveisi, Wendy Lee Queen, Mehrdad Asgari, Shuliang Yang, Daniel Teav Sun, Li Peng, Olga Trukhina, Safak Bulut

Transition-metal phosphides have received tremendous attention during the past few years because they are earth-abundant, cost-effective, and show outstanding catalytic performance in several electrochemically driven conversions including hydrogen evolutio ...

2018

van der Waals Bonded Co/h-BN Contacts to Ultrathin Black Phosphorus Devices

Ahmet Avsar

Because of the chemical inertness of two dimensional (2D) hexagonal-boron nitride (h-BN), few atomic-layer hBN is often used to encapsulate air-sensitive 2D crystals such as black phosphorus (BP). However, the effects of h-BN on Schottky barrier height, do ...

Amer Chemical Soc2017

Land-use change affects phosphorus fractions in highly weathered tropical soils

Thomas Guillaume

Deforestation and land-use change in tropics have increased over the past decades, driven by the demand for agricultural products. Although phosphorus (P) is one of the main limiting nutrients for agricultural productivity in the tropics, the effect of lan ...

Elsevier Science Bv2017

Electronic transport properties of vertical and lateral graphene-based heterostructures

Roberto Urcuyo Solorzano

Graphene has some drawbacks, like the absence of an electronic band gap which leads to only small gate switching ratios, and its fast carrier recombination that limits its use in optoelectronics. In order to overcome these issues, the aim of this thesis wa ...

EPFL2016

Thin-layer black phosphorous/GaAs heterojunction p-n diodes

Klaus Kern, Marko Burghard, Pascal Gehring

Owing to its high carrier mobility and thickness-tunable direct band gap, black phosphorous emerges as a promising component of optoelectronic devices. Here, we evaluate the device characteristics of p-n heterojunction diodes wherein thin black phosphorous ...

Amer Inst Physics2015

Spatial variability of soil phosphorus in the Fribourg canton, Switzerland

Stéphane Joost

Phosphorus (P) is the second essential nutrient for plant growth but can become an ecological and economical concern in case of over-fertilization. Soil P dynamic is influenced by many parameters like soil physical-chemical properties and farming practices ...

Elsevier2014

Identification of trigger factors selecting for polyphosphate- and glycogen-accumulating organisms in aerobic granular sludge sequencing batch reactors

Christof Holliger, David Gregory Weissbrodt

Nutrient removal performances of sequencing batch reactors using granular sludge for intensified biological wastewater treatment rely on optimal underlying microbial selection. Trigger factors of bacterial selection and nutrient removal were investigated i ...

Elsevier2013

Optimized aeration strategies for nitrogen and phosphorus removal with aerobic granular sludge

Christof Holliger, Samuel Lochmatter, Graciela Gonzalez Gil

Biological wastewater treatment by aerobic granular sludge biofilms offers the possibility to combine carbon (COD), nitrogen (N) and phosphorus (P) removal in a single reactor. Since denitrification can be affected by suboptimal dissolved oxygen concentrat ...

Elsevier2013

Performance and microbial community composition dynamics of aerobic granular sludge from sequencing batch bubble column reactors operated at 20, 30, and 35°

Christof Holliger, Pierre Rossi, Julien Maillard, Emmanuelle Rohrbach, Sirous Ebrahimi

Two bubble column sequencing batch reactors fed with an artificial wastewater were operated at 20, 30 and 35°C. In a first stage, stable granules were obtained at 20°C whereas fluffy structures were observed at 30°C. Molecular analysis revealed high abunda ...

Springer-Verlag2010

Organized Mesoporous TiO2 Films Stabilized by Phosphorus: Application for Dye-Sensitized Solar Cells

Michael Graetzel, Jun Ho Yum, Ladislav Kavan

A synthetic protocol was developed for the preparation of thin mesoporous TiO2 films with enhanced thermal stability. This objective was achieved by a modification of the procedure of supramolecular templating by a Pluronic P-123 copolymer by an addition o ...

2010