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Concept

Union internationale de chimie pure et appliquée

Publications associées (14)

Understanding and mitigating resistive losses in fired passivating contacts: role of the interfaces and optimization of the thermal budget

Christophe Ballif, Franz-Josef Haug, Aïcha Hessler-Wyser, Luca Massimiliano Antognini, Sofia Libraro, Audrey Marie Isabelle Morisset, Julien Hurni, Ezgi Genç

This work presents a study of p-type passivating contacts based on SiCx formed via a rapid thermal processing (RTP) step, using conditions compatible with the firing used to sinter screen-printed metallization pastes in industry. The contributions of the t ...

Elsevier2023

Modelling the coupled mercury-halogen-ozone cycle in the central Arctic during spring

Julia Schmale, Ivo Fabio Beck, Hélène Paule Angot

Near-surface mercury and ozone depletion events occur in the lowest part of the atmosphere during Arctic spring. Mercury depletion is the first step in a process that transforms long-lived elemental mercury to more reactive forms within the Arctic that are ...

2023

Constraining the response factors of an extractive electrospray ionization mass spectrometer for near-molecular aerosol speciation

Julia Schmale

Online characterization of aerosol composition at the near-molecular level is key to understanding chemical reaction mechanisms, kinetics, and sources under various atmospheric conditions. The recently developed extractive electrospray ionization time-of-f ...

2021

Detection of Pressure or Flow Rate Variations in MR Valves through Magnetic Flux Analysis

Yves Perriard, Yoan René Cyrille Civet, Daniel Grivon

Magneto-Rheological (MR) fluids consist in a suspension of ferromagnetic particles dispersed in a fluid carrier. If excited by a magnetic source, the nearby magnetic field induces the particles magnetization with the formation of chainlike structures align ...

2016

Development of Accurate and Efficient Electronic Structure Approaches for the Description of Organic Systems

Riccardo Petraglia

The overarching objective of this thesis is extending and adapting the set of computational tools available for describing molecular precursors of organic semiconductors. The research presented within develops adhering to three principle goals: (1) provide ...

EPFL2016

Fibroblast adhesion on ECM-derived peptide modified poly(2-hydroxyethyl methacrylate) brushes: Ligand co-presentation and 3D-localization

Harm-Anton Klok, Solenne Desseaux

Polymer brushes prepared via surface-initiated polymerization of 2-hydroxyethyl methacrylate are powerful platforms for the fabrication of model biointerfaces to study cell-substrate interactions. In this manuscript, the versatility of surface-initiated po ...

Elsevier2015

Electrochemical behaviour of ferrocenes in tributylmethylphosphonium methyl sulfate mixtures with water and 1,2-dichloroethane

Thomas James Stockmann, Zhifeng Ding

Electron transfer (ET) reactions in ionic liquid (IL)vertical bar organic solvent (1,2-dichloroethane, DCE) and IL vertical bar water mixtures were investigated using a Pt disk ultramicroelectrode (UME) along with ferrocene (Fc) and ferrocenemethanol (FcCH ...

Canadian Science Publishing, Nrc Research Press2015

How Accurately Can We Predict the Melting Points of Drug-like Compounds?

Luc Patiny

This article contributes a highly accurate model for predicting the melting points (MPs) of medicinal chemistry compounds. The model was developed using the largest published data set, comprising more than 47k compounds. The distributions of MPs in drug-li ...

American Chemical Society2014

Europium Complexes of Tris(dipicolinato) Derivatives Coupled to Methylumbelliferone: A Double Sensitization

Anne-Sophie Chauvin, Julien Alexandre Andres

A para-poly(oxyethylene) dipicolinic acid derivative coupled to methylumbelliferone was synthesized and used as a ligand for coordination with europium ions. Characterization of the complex by mass spectrometry and spectrophotometry was performed in aqueou ...

Wiley-Blackwell2010

Fabrication of nanopore arrays and ultrathin silicon nitride membranes by block-copolymer-assisted lithography

Jeffrey Alan Hubbell

Here we show a method for patterning a thin metal film using self-assembled block-copolymer micelles monolayers as a template. The obtained metallic mask is transferred by reactive ion etching in silicon oxide, silicon and silicon nitride substrates, thus ...

2009

Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV - gas phase reactions of organic halogen species

Michel Rossi

This article, the fourth in the series, presents kinetic and photochemical data sheets evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the gas phase and photochemical reactions of organic halogen spec ...

Copernicus Publications2008

Position-flexible elaboration of halogenated heterocycles: Metalated species as key intermediates for synthesis

Halogens, in particular fluorine atoms, are favorite tools to fine-tune the chemical and biological properties of pharmaceutical or agricultural development products. At the same time, such an electronegative substituent can effectively assist the site-sel ...

2007

Salts of electrophilic cations and Lewis acid-base adducts with weakly coordinating anions : synthesis, characterization and quantum chemical calculations

Ines Raabe

During the last decades, weakly coordinating anions (WCAs) have become a field of great interest both in basic and applied chemistry, as – if compared to "normal" classical anions like Cl- or SO42- – they have a lot of unique and unusual properties, such a ...

EPFL2007

Metalation/functionalization sequences applied to 2-bromo-3-fluoroquinolines

Levente Ondi

Mono- and disubstituted 2-bromo-3-fluoroquinolines are readily accessible. They can be converted into the 3-fluoroquinoline-2-carboxylic acids by consecutive halogen/metal permutation and into the 2-bromo-3-fluoroquinoline-4-carboxylic acids by consecutive ...

2005