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Concept

Salaison

Publications associées (21)

Universal Casimir attraction between filaments at the cell scale

Anne-Florence Raphaëlle Bitbol

The electromagnetic Casimir interaction between dielectric objects immersed in salted water includes a universal contribution that is not screened by the solvent and therefore long-ranged. Here, we study the geometry of two parallel dielectric cylinders. W ...

Iop Publishing Ltd2024

Second harmonic scattering of nanoparticles: A journey into the electrical double layer

Bingxin Chu

In aqueous solutions, a charged surface causes the redistribution of nearby ions. The ion layers formed are known as the electrical double layer (EDL), and are widespread in many systems involving electrochemistry, colloidal science, biomedicine, and energ ...

EPFL2024

The influence of the gas on the dynamics of cavitation bubbles

Davide Bernardo Preso

Cavitation bubbles, extensively investigated in fluid mechanics, present enduring challenges in hydraulic machinery, while holding considerable potential for practical applications in biomedicine and sonochemistry. Despite more than a century of research, ...

EPFL2023

Modeling Snow Saltation: The Effect of Grain Size and Interparticle Cohesion

Varun Sharma, Michael Lehning, Francesco Comola, Daniela Brito Melo, Armin Sigmund

The surface of the Earth is snow-covered at least seasonally over large areas. This snow surface is highly dynamic, particularly under the influence of strong winds. The motion of snow particles driven by the wind not only changes the snow cover but has im ...

2022

Quantitative electronic structure and work-function changes of liquid water induced by solute

Bruno Credidio

Recent advancement in quantitative liquid-jet photoelectron spectroscopy enables the accurate determination of the absolute-scale electronic energetics of liquids and species in solution. The major objective of the present work is the determination of the ...

ROYAL SOC CHEMISTRY2022

High Sensitivity Detection of a Solubility Limiting Surface Transformation of Drug Particles by DNP SENS

David Lyndon Emsley, Arthur César Pinon, Jasmine Viger-Gravel

We investigate the presence of a surface species for the active pharmaceutical ingredient (API) AZD9496 with dynamic nuclear polarization surface enhanced nuclear spectroscopy (DNP SENS). We show that using DNP we can elucidate the presence of an amorphous ...

2021

Catechol Containing Polyelectrolyte Complex Nanoparticles as Local Drug Delivery System for Bortezomib at Bone Substitute Materials

Martin Guillermo Mueller, Jeremy Pak Hei Wong

The proteasome inhibitor bortezomib (BZM) is one of the most potent anti-cancer drugs in the therapy of multiple myeloma. In this study, an adhesive drug delivery system (DDS) for BZM was developed. Therefore, we extended the present DDS concept of polyele ...

2020

Aqueous electrolytes for high-voltage batteries and supercapacitors

David Reber

Lithium-ion batteries are widely implemented as energy storage devices due to their high energy density and low cost. They enabled modern portable electronics and electric ve-hicles, and are key to manage the integration of intermittent renewable electrici ...

EPFL2020

Stability of aqueous electrolytes based on LiFSI and NaFSI

Corsin Battaglia, David Reber

Through a combination of bulk, interface, and interphase effects, water-in-salt electrolytes, employing a high salt concentration, offer a wider electrochemical stability window than traditional dilute aqueous electrolytes. Here we explore chemical stabili ...

2019

Suppressing Crystallization of Water-in-Salt Electrolytes by Asymmetric Anions Enables Low-Temperature Operation of High-Voltage Aqueous Batteries

Corsin Battaglia, David Reber

The discovery of enhanced electrochemical stability for aqueous electrolytes with very high salt concentration has stimulated the development of high-voltage aqueous batteries. We show that a key factor limiting the applicability of these batteries is the ...

AMER CHEMICAL SOC2019

Polycation Interactions with Zwitterionic Phospholipid Monolayers on Oil Nanodroplets Suspensions in Water (D2O) Probed by Sum Frequency Scattering

Sylvie Roke, Nikolay Smolentsev

By combining dynamic light scattering (DLS) measurements and infrared (IR) spectroscopy with the interface- and bond-specificity of vibrational sum frequency generation scattering (SFS) spectroscopy, we probe several structural aspects of how zwitterionic ...

2018

Wind tunnel observations of weak and strong snow saltation dynamics

Michael Lehning, Philip Crivelli, Enrico Paterna

Theoretical considerations suggest that saltation dynamics is dominated by either aerodynamic entrainment or by a combination of ejection and rebound at a given time and location. Calling these two regimes weak and strong saltation, respectively, we have i ...

Amer Geophysical Union2017

Guanidinium can both Cause and Prevent the Hydrophobic Collapse of Biomacromolecules

Halil Ibrahim Okur

A combination of Fourier transform infrared and phase transition measurements as well as molecular computer simulations, and thermodynamic modeling were performed to probe the mechanisms by which guanidinium (Gnd(+)) salts influence the stability of the co ...

2017

Wind tunnel experiments: saltation is necessary for wind-packing

Michael Lehning, Charles Fierz, Christian Gabriel Sommer

Wind-packed snow in the form of slabs or crusts is an important part of alpine and polar snow covers. Yet, the formation process of such layers is poorly understood. For example, it remains unclear whether drifting snow is necessary for wind-packing or not ...

International Glaciological Society2017

Quantum versus classical protons in pure and salty ice under pressure

Richard Gaal, Livia Eleonora Bove Kado

It is generally accepted that nuclear quantum effects (NQEs) trigger the transition to the nonmolecular form of ice under increasing pressure. This picture is challenged in salty ice, where Raman scattering measurements up to 130 GPa of molecular ice VII c ...

Amer Physical Soc2016

Influence of Fluorinated Surfactant Composition on the Stability of Emulsion Drops

Esther Amstad, Gianluca Nicolas Etienne, Michael David Kessler

Aqueous drops of a well-defined size are often used as small containers for conducting chemical and biochemical reactions, cell assays and as templates to produce microparticles. To prevent their coalescence, they must be stabilized, for example, using sur ...

Wiley-Blackwell2016

Prolonged river water pollution due to variable-density flow and solute transport in the riverbed

David Andrew Barry

A laboratory experiment and numerical modeling were used to examine effects of density gradients on hyporheic flow and solute transport under the condition of a solute pulse input to a river with regular bed forms. Relatively low-density gradients due to a ...

American Geophysical Union2015

Thermodynamics of Writhe in DNA Minicircles from Molecular Dynamics Simulations

Jonathan Mitchell

DNA supercoiling plays a role in genetic control by imposing torsional stress. This can induce writhe, which changes the global shape of the DNA. We have used atomistic molecular dynamics simulations to partition the free energy changes driving the writhin ...

Amer Physical Soc2013

Force spectroscopy of barnase-barstar single molecule interaction

Giovanni Dietler, Serguei Sekatski, Mélanie Favre, Dmitry Klinov, Andrey Mikhaylov

Results of the single molecule force spectroscopy study of specific interactions between ribonuclease barnase and its inhibitor barstar are presented. Experimental data obtained for the force loading rate ranging 2-70 nN/s are well approximated by a single ...

Wiley-Blackwell2010

Characterization of PEI-coated superparamagnetic iron oxide nanoparticles for transfection: Size distribution, colloidal properties and DNA interaction

Heinrich Hofmann, Alke Fink, Benedikt Steitz

Superparamagnetic iron oxide nanoparticles (SPIONs) were coated with polyethylenimine. Here, we briefly describe the synthesis as well as DNA:PEI:SPION complexes and the characterization of the compounds according to their particle size, zeta-potential, mo ...

2007