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Concept

Usinage électrolytique

Publications associées (27)

Rate-Determining Step for Electrochemical Reduction of Carbon Dioxide into Carbon Monoxide at Silver Electrodes

Sophia Haussener, Etienne Boutin

Silver is one of the most studied electrode materials for the electrochemical reduction of carbon dioxide into carbon monoxide, a product with many industrial applications. There is a growing number of reports in which silver is implemented in gas diffusio ...

2024

High entropy molybdate-derived FeOOH catalyzes oxygen evolution reaction in alkaline media

Lichen Bai, Seunghwa Lee

High-entropy materials are a new class of materials that have lately been developed and applied to a variety of potential fields. Here we present that electrochemical activation facilitates the application of high-entropy molybdates (HEMo) as oxygen evolut ...

PERGAMON-ELSEVIER SCIENCE LTD2023

Review on Uric Acid Recognition by MOFs with a Future in Machine Learning

Shaswati Mandal

Uric acid (UA) is produced from purine metabolism and serves as a prevalent biomarker for multiple diseases including cancer. Hyperuricemia or hypouricemia can cause multiple dysfunctions throughout the biological processes. Consequently, there is a pressi ...

Amer Chemical Soc2023

The potentials of additive manufacturing for mass production of electrochemical energy systems

Demetri Psaltis, Seyyed Mohammad Hosseini Hashemi, Pooria Hadikhani, Ugljesa Babic

Additive manufacturing has established itself as a popular and powerful tool in electrochemistry research and development. In this short review, we focus on the latest results in both 3D printing and electrochemistry communities that could potentially bene ...

ELSEVIER2020

Integrated photo-electrochemical device for concentrated irradiation

Sophia Haussener, Meng Lin, Saurabh Yuvraj Tembhurne

The present invention relates to a photo-electrochemical device for production of a gas, liquid or solid using concentrated electromagnetic irradiation. The device comprises a photovoltaic component configured to generate charge carriers from the concentra ...

2019

Bacterial adhesion and inactivation on Ag decorated TiO2-nanotubes under visible light: Effect of the nanotubes geometry on the photocatalytic activity

Sami Rtimi

This study investigates the effect of the diameter of TiO2 nanotubes and silver decorated nanotubes on optical properties and photocatalytic inactivation of Escherichia coli under visible light. The TiO2 nanotubes (TiO2 -NTs) were prepared using the electr ...

2018

Potential-sensing electrochemical atomic force microscopy for in operando analysis of water-splitting catalysts and interfaces

Kevin Sivula

Heterogeneous electrochemical phenomena, such as (photo)electrochemical water splitting to generate hydrogen using semiconductors and/or electrocatalysts, are driven by the accumulated charge carriers and thus the interfacial electrochemical potential grad ...

2018

PowerCool: Simulation of Cooling and Powering of 3D MPSoCs with Integrated Flow Cell Arrays

David Atienza Alonso, Marina Zapater Sancho, Arvind Raj Mahankali Sridhar, Mohamed Mostafa Sabry Aly, Artem Andreev

Integrated Flow-Cell Arrays (FCAs) represent a combination of integrated liquid cooling and on-chip power generation, converting chemical energy of the flowing electrolyte solutions to electrical energy. The FCA technology provides a promising way to addre ...

Institute of Electrical and Electronics Engineers2017

Soft-Sphere Continuum Solvation in Electronic-Structure Calculations

Nicola Marzari, Oliviero Andreussi

We present an implicit solvation approach where the interface-between the quantum-mechanical solute and the surrounding environment is, described by a fully continuous permittivity built up with atomic-centered "soft" spheres. This approach combines many o ...

Amer Chemical Soc2017

Role of microstructure on electrode operating mechanisms for mixed ionic electronic conductors: From synchrotron-based 3D reconstruction to electrochemical modeling

Arata Nakajo

A typical La0.6Sr0.4Co0.2Fe0.8O3-delta (LSCF) electrode was reconstructed by X-ray nanotomography. The new Nano Imaging beamline ID16A-NI of the European Synchrotron Radiation Facility (ESRF) was used to conduct the investigation. Particular attention was ...

Elsevier Science Bv2016

Electrochemical Model of a Triode Solid Oxide Fuel Cell

Jan Van Herle, Stefan Diethelm, Arata Nakajo, Priscilla Caliandro

A Triode Solid Oxide Fuel Cell is a novel cell architecture that consists of two circuits: an auxiliary circuit, operated in electrolysis mode, and a conventional main fuel cell circuit. During triode operation, performance enhancement can be expected espe ...

2015

Interplay between the potential waveform and diffusion layer dynamics determines the time-response of voltammetric detection in microchannels

Martinus Adela Maria Gijs, Raphaël Etienne Jean Trouillon

The diffusion layer is a critical factor affecting the temporal response of electrochemical devices. In this article, we have investigated the effect of the relaxation of the diffusion layer during the potentiodynamic sensing of ferrocenemethanol (FcMeOH) ...

Elsevier2015

Robust production of purified H-2 in a stable, self-regulating, and continuously operating solar fuel generator

Sophia Haussener, Miguel Antonio Modestino

The development of practical solar-driven electrochemical fuel generators requires the integration of light absorbing and electrochemical components into an architecture that must also provide easy separation of the product fuels. Unfortunately, many of th ...

Royal Society of Chemistry2014

Photo-Ionic Cells: Two Solutions to Store Solar Energy and Generate Electricity on Demand

Hubert Girault, Pekka Eero Peljo, Heron Vrubel, Manuel Alejandro Méndez Agudelo, Micheal Diarmaid Scanlon

A solar energy conversion concept based on the photo-induced separation of a pair of redox species in a biphasic liquid cell is presented. The redox pair is subsequently discharged in an electrochemical flow cell to generate electricity. To illustrate this ...

Amer Chemical Soc2014

Local Activation and Degradation of Electrochemical Processes in a SOFC

Jan Van Herle, Zacharie Wuillemin, Hossein Madi

The local electrochemistry is studied in a SOFC repeat-element using a test setup that allows a local control of the polarization. During long-term tests, the local current densities evolve, following activation and degradation periods. Electrochemical imp ...

2013

The Transient Photocurrent and Photovoltage Behavior of a Hematite Photoanode under Working Conditions and the Influence of Surface Treatments

Michael Graetzel, Kevin Sivula, Florian Le Formal

Hematite (alpha-Fe2O3) is widely recognized as a promising candidate for the production of solar fuels via water splitting, but its intrinsic optoelectronic properties have limited its performance to date. In particular, the large electrochemical overpoten ...

American Chemical Society2012

Electrochemical Model of Solid Oxide Fuel Cell for Simulation at the Stack Scale I. Calibration Procedure on Experimental Data

Jan Van Herle, Daniel Favrat, Stefan Diethelm, Zacharie Wuillemin, Arata Nakajo

Lifetime prediction and improvement of solid oxide fuel cell (SOFC) devices require a reliable electrochemical model that supports the implementation of degradation phenomena. This study comprises two parts. This Part I describes the calibration of an elec ...

2011

Electrochemical model of solid oxide fuel cell for simulation at the stack scale. Part II: Implementation of degradation processes

Jan Van Herle, Daniel Favrat, Arata Nakajo, Stefan Diethelm, Pietro Tanasini

The degradation of the electrochemical performance of solid oxide fuel cell (SOFC) devices is a major hurdle to overcome before commercialisation. The interplay between the phenomena and the long testing times complicate the research, which highlights the ...

2011

Electrochemically controlled wear transitions in the tribocorrosion of ruthenium

Michel Declercq, Didier Bouvet, Stefano Mischler

This work presents an investigation of the tribocorrosion of ruthenium in sulphuric acid solutions. The study was focused on the effect of the electrode potential on wear of ruthenium during sliding against an inert alumina ball in a reciprocating sliding ...

2009

Self and induced stabilized nanoparticles for electrocatalysis

Since few decades the search of new catalysts formulations for fuel cell applications has motivated numerous projects especially due to the future lack of fossil fuel, environmental and economical reasons. Consequently, Direct Alcohol Fuel Cell (DAFC) or D ...

EPFL2009