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Concept

Gadolinium

Publications associées (27)

Dynamic nuclear polarisation of 1H in Gd-doped In(OH)3

David Lyndon Emsley, Michael Allan Hope, Amrit Venkatesh, Yuxuan Zhang

Dynamic nuclear polarisation (DNP) of solids doped with high-spin metal ions, such as Gd3+, is a useful strategy to enhance the nuclear magnetic resonance (NMR) sensitivity for these samples. Spin diffusion can relay polarisation throughout a sample, which ...

Academic Press Inc - Elsevier Science2023

Endogenous O-17 Dynamic Nuclear Polarization of Gd-Doped CeO2 from 100 to 370 K

David Lyndon Emsley, Michael Allan Hope, Snaedis Björgvinsdóttir

O-17 NMR is an invaluable tool to study the structure and dynamics of oxide materials but remains challenging to apply in many systems. Even with isotopic enrichment, studies of samples with low masses and/or concentrations of the active species, such as t ...

2021

Design of Ductile Rare-Earth-Free Magnesium Alloys

William Curtin, Binglun Yin, Rasool Ahmad

Pure Mg has low ductility due to a transition of < c+a > pyramidal dislocations to a sessile basal-oriented structure. Dilute alloying generally improves ductility. Enhancement of pyramidal cross-slip from the lower-energy pyramidal II plane to the higher- ...

SPRINGER INTERNATIONAL PUBLISHING AG2020

Accessing the plus IV Oxidation State in Molecular Complexes of Praseodymium

Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Aurélien René Willauer, Chad Thomas Palumbo

Out of the 14 lanthanide (Ln) ions, molecular complexes of Ln(IV) were known only for cerium and more recently terbium. Here we demonstrate that the +IV oxidation state is also accessible for the large praseodymium (Pr) cation. The oxidation of the tetraki ...

2020

Unconventional Spin Relaxation Involving Localized Vibrational Modes in Ho Single-Atom Magnets

Harald Brune, Stefano Rusponi, Marina Pivetta, Jan Gui-Hyon Dreiser, Pietro Gambardella, Fabio Donati, Christian Wäckerlin, Aparajita Singha, Romana Baltic, Katharina Johanna Diller

We investigate the spin relaxation of Ho single atom magnets on MgO/Ag(100) as a function of temperature and magnetic field. We find that the spin relaxation is thermally activated at low field, while it remains larger than 1000 s up to 30 K and 8 T. This ...

AMER PHYSICAL SOC2020

Colorimetry of Luminescent Lanthanide Complexes

Anne-Sophie Chauvin, Julien Alexandre Andres

Europium, terbium, dysprosium, and samarium are the main trivalent lanthanide ions emitting in the visible spectrum. In this work, the potential of these ions for colorimetric applications and colour reproduction was studied. The conversion of spectral dat ...

2020

Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties

Paul Muralt, Robin Nigon

Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently shown exceptional electrostrictive properties that are even superior to the best performing lead-based electrostrictors, e.g. lead-magnesium-niobates (PMN). Compared to pi ...

PERGAMON-ELSEVIER SCIENCE LTD2019

Doping and phase segregation in Mn2+- and Co2+-doped lead halide perovskites from Cs-133 and H-1 NMR relaxation enhancement

Michael Graetzel, Shaik Mohammed Zakeeruddin, David Lyndon Emsley, Dominik Józef Kubicki, Gabriele Stevanato, Albert Hofstetter, Daniel Prochowicz, Arthur César Pinon

Lead halide perovskites belong to a broad class of compounds with appealing optoelectronic and photovoltaic properties. Doping with transition metal ions such as Mn2+ and Co2+ has recently been reported to substantially enhance luminescence and stability o ...

Royal Society of Chemistry2019

Fast and Sensitive Detection of Paramagnetic Species Using Coupled Charge and Spin Dynamics in Strongly Fluorescent Nanodiamonds

Claudia Esther Avalos

Sensing of a few unpaired electron spins, such as in metal ions and radicals, is a useful but difficult task in nanoscale physics, biology, and chemistry. Single negatively charged nitrogen-vacancy (NV-) centers in diamond offer high sensitivity and spatia ...

2019

Effects of co-doped barium cerate additive on morphology, conductivity and electrochemical properties of samarium doped ceria electrolyte for intermediate temperature solid oxide fuel cells

Yongpeng Liu, Xinchao Wang, Chiara Bonati, Meng Xia

The composite of samarium doped ceria (Sm0.2Ce0.8O2-delta, SDC) and co-doped barium cerate (BaZr0.1Ce0.7Y0.1Yb0.1O3-delta, BZCYYb) is prepared by mechanical mixing and investigated as electrolyte for intermediate temperature solid oxide fuel cells (IT-SOFC ...

PERGAMON-ELSEVIER SCIENCE LTD2018

Self-Assembled Nanomicelles as MRI Blood-Pool Contrast Agent

Lothar Helm, Anne-Sophie Chauvin

Gadolinium‐loaded nanomicelles show promise as future magnetic resonance imaging (MRI) contrast agents (CAs). Their increased size and high gadolinium (Gd) loading gives them an edge in proton relaxivity over smaller molecular Gd‐complexes. Their size and ...

2017

Nanoionics Phenomena and Devices with Oxide Thin Films

Mahmoud Hadad

The number of studies on solid state ionic thin films (Nanoionics) has increased dramatically over last decades due to their high potential in micro and nanoscale technologies. Micro solid oxide fuel cells (micro-SOFC), and resistive switching memories (Re ...

EPFL2017

Magnetic properties of surface-adsorbed single rare earth atoms, molecules, and atomic scale clusters

Aparajita Singha

This thesis presents combined experimental and theoretical investigations of nanoscale, surface-supported magnets based on rare earths (RE) to understand and control the magnetic properties down to the scale of single atoms. We present the effects of adato ...

EPFL2017

J1−J2 square-lattice Heisenberg antiferromagnets with 4d1 spins: AMoOPO4Cl (A=K,Rb)

Henrik Moodysson Rønnow, Peter Babkevich

Magnetic properties of AMoOPO4Cl (A=K,Rb) with Mo5+ ions in the 4d1 electronic configuration are investigated by magnetization, heat capacity, and nuclear magnetic resonance (NMR) measurements on single crystals, combined with powder neutron diffraction ex ...

2017

Key-features in processing and microstructure for achieving giant electrostriction in gadolinium doped ceria thin films

Paul Muralt, Silviu Cosmin Sandu, Mahmoud Hadad

Gadolinium doped ceria is a well-known oxygen ion conduction material for solid fuel cell electrolytes. With its centrosymmetric average lattice and relatively low bulk dielectric constant it does not look interesting for electromechanical applications. Ho ...

Elsevier2016

Dinuclear DOTA-Based Gd-III Chelates - Revisiting a Straightforward Strategy for Relaxivity Improvement

Lothar Helm, Shima Karimi

The need for magnetic resonance imaging (MRI) contrast agents with improved relaxivity maintains the development of new Gd-III chelates as an intensive and demanding field of research. In this work, we introduce the new dimeric chelators bis{1,4,7,10-tetra ...

Wiley-Blackwell2015

PEGylated DOTA-AHA-Based Gd-III Chelates: A Relaxometric Study

Lothar Helm, Shima Karimi

Three PEGylated derivatives of 6-amino-2-[4,7,10-tris(carboxymethyl)-1,4,7,10-tetrazacyclododec-1-yl]hexanoic acid (DOTA-AHA) with different molecular weights were prepared and characterized. Their Gd-III chelates were studied in aqueous solution through v ...

Wiley-Blackwell2015

Strong antiferromagnetic exchange between manganese phthalocyanine and ferromagnetic europium oxide

Stefano Rusponi, Jan Gui-Hyon Dreiser, Fabio Donati, Christian Wäckerlin, Aparajita Singha, Romana Baltic

We report on the antiferromagnetic exchange coupling between a submonolayer of Mn(II)-phthalocyanine molecules and a ferromagnetic Eu(II)-oxide thin film. The exchange energy is larger by nearly two orders of magnitude compared to previous studies involvin ...

Royal Society of Chemistry2015

Optical properties of V2O3 in its whole phase diagram

Vanadium sesquioxide V2O3 is considered a textbook example of Mott-Hubbard physics. In this paper, we present an extended optical study of its whole temperature/doping phase diagram as obtained by doping the pure material with M = Cr or Ti atoms (V1-x M-x) ...

Amer Physical Soc2015

Luttinger liquid behavior in the alternating spin-chain system copper nitrate

Felix Groitl

We determine the phase diagram of copper nitrate Cu(NO3)(2)center dot 2.5D(2)O in the context of quantum phase transitions and novel states of matter. We establish this compound as an ideal candidate to study quasi-1D Luttinger liquids, 3D Bose-Einstein-Co ...

American Physical Society2015