Publications associées à Chirality (mathematics)

Publications associées (17)

Complexation Strategies towards Challenging Group 9 Metal Cyclopentadienyl Scaffolds

Cyclopentadienyl (Cp) metal complexes and their chiral counterparts (CpX) have enabled the development of challenging C-H activation transformations. While major progresses were made in developing new chiral CpX complexes and exploring their reactivity, th ...

EPFL2023

Hard X-ray helical dichroism of disordered molecular media

Majed Chergui, Giulia Fulvia Mancini, Malte Oppermann, Oliviero Cannelli, Dominik Kinschel, Camila Bacellar Cases Da Silveira

Chirality is a structural property of molecules lacking mirror symmetry that has strong implications in diverse fields, ranging from life sciences to materials science. Chirality-sensitive spectroscopic methods, such as circular dichroism, exhibit weak sig ...

Nature Publishing Group2022

Observation of a singular Weyl point surrounded by charged nodal walls in PtGa

Oleg Yazyev, Jan Hugo Dil, Quansheng Wu, Shengnan Zhang

Constrained by the Nielsen-Ninomiya no-go theorem, in all so-far experimentally determined Weyl semimetals (WSMs) the Weyl points (WPs) always appear in pairs in the momentum space with no exception. As a consequence, Fermi arcs occur on surfaces which con ...

Nature Research2021

Discrete metal nanoparticles with plasmonic chirality

Jijun He

From a geometrical perspective, a chiral object does not have mirror planes or inversion symmetry. It exhibits the same physical properties as its mirror image (enantiomer), except for the chiroptical activity, which is often the opposite. Recent advanceme ...

Royal Society of Chemistry2021

Control of a polar order via magnetic field in a vector-chiral magnet

Helmuth Berger

Vector-chiral (VC) antiferromagnetism is a spiral-like ordering of spins which may allow ferroelectricity to occur due to loss of space inversion symmetry. In this Letter we report direct experimental observation of ferroelectricity in the VC phase of beta ...

AMER PHYSICAL SOC2021

Chirok: a post-refinement tool to analyse absolute structure

Philip Pattison

Chirok is software for a post-refinement test of the absolute structure. The software allows a user to calculate a distribution of the measure of chirality based on intensity quotients and linked to the Flack parameter. The distribution is fitted by a set ...

2020

Correlation between Optical Activity and the Helical Molecular Orbitals of Allene and Cumulenes

Anne-Clémence Corminboeuf, Marc Hamilton Folkmann Garner

Helical frontier molecular orbitals (MOs) appear in disubstituted allenes and even-n cumulenes. Chiral molecules are optically active, but while these molecules are single-handed chiral, p-orbitals of both helicities are present. Here we computationally ex ...

AMER CHEMICAL SOC2020

A Subwavelength Microwave Bandpass Filter Based on a Chiral Waveguide

Romain Christophe Rémy Fleury, Maliheh Khatibi Moghaddam

Wave manipulation at a subwavelength scale has recently attracted significant interest, especially for low-frequency wave propagation, from acoustic to microwave devices. Recently, a few methods achieving subwavelength routing using locally resonant metama ...

IEEE Xplore2020

Helical structures with switchable and hierarchical chirality

Huijuan Feng

Chirality is present as a trend of research in biological and chemical communities for it has a significant effect on physiological properties and pharmacological effects. Further, manipulating specific morphological chirality recently has emerged as a pro ...

AMER INST PHYSICS2020

Subwavelength robust waveguiding with chiral metamaterial waveguides

Romain Christophe Rémy Fleury, Bakhtiyar Orazbayev, Nadège Sihame Kaïna

In this work, we design and experimentally demonstrate in the microwave range a robust metamaterial waveguide, which is formed at the boundary between two locally resonant chiral metamaterials with opposite chirality. We show that the interface states at s ...

IEEE2019

Chiral Waveguides for Robust Waveguiding at the Deep Subwavelength Scale

Romain Christophe Rémy Fleury, Bakhtiyar Orazbayev, Nadège Sihame Kaïna

Routing electromagnetic energy at a scale smaller than the wavelength is a highly sought functionality in a variety of applications, including compact lightweight satellite communications, slow-waves sensors, all-optical information processing, and energy ...

American Physical Society (APS)2018

Exchange anisotropy as mechanism for spin-stripe formation in frustrated spin chains

Helmuth Berger

We investigate the spin-stripe mechanism responsible for the peculiar nanometer modulation of the incommensurate magnetic order that emerges between the vector-chiral and the spin-density-wave phase in the frustrated zigzag spin-1/2 chain compound beta-TeV ...

Amer Physical Soc2016

Giant spin splitting of the two-dimensional electron gas at the surface of SrTiO3

Jan Hugo Dil

Two-dimensional electron gases (2DEGs) forming at the interfaces of transition metal oxides(1-3) exhibit a range of properties, including tunable insulator-superconductor-metal transitions(4-6), large magnetoresistance(7), coexisting ferromagnetism and sup ...

Nature Publishing Group2014

Scalar masses in general N=2 gauged supergravity theories

Claudio Scrucca, Paul Smyth

We readdress the question of whether any universal upper bound exists on the square mass m(2) of the lightest scalar around a supersymmetry breaking vacuum in generic N=2 gauged supergravity theories for a given gravitino mass m(3/2) and cosmological const ...

Springer Nature2014

Zero-temperature Monte Carlo study of the noncoplanar phase of the classical bilinear-biquadratic Heisenberg model on the triangular lattice

Frédéric Mila, Sandro Wenzel

We investigate the ground-state properties of the highly degenerate noncoplanar phase of the classical bilinear-biquadratic Heisenberg model on the triangular lattice with Monte Carlo simulations. For that purpose, we introduce an Ising pseudospin represen ...

2013

Impact of Strain Effects on the Stability of Ising Walls in Ferroelectrics

Nava Setter, Alexander Tagantsev, Petr Yudin

The stability of Ising 180-degree domain walls with respect to appearance of chirality is analytically studied in tetragonal perovskite-type ferroelectrics taking into account electro-mechanical coupling. It is shown that the widely used approximation negl ...

2012

Bulk homochirality of a 3-D inorganic framework: ligand control of inorganic network chirality

Philip Pattison

Enantioselective synthesis of a 3-D inorganic net has been achieved leading to metal–organic frameworks built from cobalt-oxide helices in which handedness is controlled by the chirality of the linked ligand. ...

Royal Society of Chemistry2009