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Concept

Enthalpie

Publications associées (25)

Pressure-freezing of dodecane: exploring the crystal structures, formation kinetics and phase diagrams for colossal barocaloric effects in n-alkanes

Tomasz Poreba

Barocaloric (BC) materials provide cheaper and more energy efficient alternatives to traditional refrigerants. Some liquid alkanes were recently shown to exhibit a colossal BC effect, matching the entropy changes in commercial vapour-liquid refrigerants. D ...

Royal Soc Chemistry2023

Twisting instabilities in elastic ribbons with inhomogeneous pre-stress: A macroscopic analog of thermodynamic phase transition

Pedro Miguel Nunes Pereira de Almeida Reis, Michael Christopher Gomez

We study elastic ribbons subject to large, tensile pre-stress confined to a central region within the cross-section. These ribbons can buckle spontaneously to form helical shapes, featuring regions of alternating chirality (phases) that are separated by so ...

PERGAMON-ELSEVIER SCIENCE LTD2023

Atmospheric biogenic volatile organic compounds in the Alaskan Arctic tundra: constraints from measurements at Toolik Field Station

Hélène Paule Angot

The Arctic is a climatically sensitive region that has experienced warming at almost 3 times the global average rate in recent decades, leading to an increase in Arctic greenness and a greater abundance of plants that emit biogenic volatile organic compoun ...

Copernicus GmbH2022

Adiabatic two-phase pressure drop of carbon dioxide in different channel orientations

Jürg Alexander Schiffmann, Rémi Revellin, David Schmid

Adiabatic pressure drop measurements of two-phase Carbon Dioxide (CO2) have been carried out in horizontal, vertical upward and downward direction with a dedicated test facility at the European Organization for Nuclear Research (CERN). A database of more t ...

2022

Probing unconventional performance of fiber resonators: light storage, generation and manipulation

Ivan Cardea

This thesis aims at investigating the performance of figure-9 (figure-of-nine) optical fiber resonators as a practical solution for light storage, light generation and manipulation. The first part of the thesis focuses on a theoretical and experimental stu ...

EPFL2021

Revisiting the concept of extents for chemical reaction systems using an enthalpy balance

Dominique Bonvin, Diogo Filipe Mateus Rodrigues

For the investigation of complex reaction systems, it has been proposed to decouple the various rate processes using a linear time-invariant transformation that is constructed from knowledge of stoichiometry, reaction enthalpies, inlet compositions and tem ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Dynamic wetting in pressure-infiltration of ceramic particle preforms by molten metal

Gionata Schneider

This thesis investigates the interaction between mechanically induced flow of a liquid metal into a porous solid, and kinetic effects at the triple line. The approach is experimental and focuses on metal-ceramic systems for which the literature gives value ...

EPFL2019

Improving Performance and Accuracy of Hybrid-Functional Based Molecular Dynamics in Plane Waves

Martin Peter Bircher

The simulation of condensed matter in first principles Molecular Dynamics (FPMD) heavily relies on Kohn-Sham Density Functional Theory (KS-DFT) calculations. The accuracy of such simulations is governed by the reliability of the underlying potential energy ...

EPFL2018

J1-J2 square lattice antiferromagnetism in the orbitally quenched insulator MoOPO4

László Forró, Henrik Moodysson Rønnow, Helmuth Berger, Arnaud Magrez, Oleg Yazyev, Bálint Náfrádi, Ivica Zivkovic, Peter Babkevich, Lin Yang, Noore Elahi Shaik

We report magnetic and thermodynamic properties of a 4d1 (Mo5+) magnetic insulator MoOPO4 single crystal, which realizes a J1−J2 Heisenberg spin-1/2 model on a stacked square lattice. The specific-heat measurements show a magnetic transition at 16 K which ...

Amer Physical Soc2017

Investigation of RF Nb-Ti PF 1&6 Coils Conductor Performances in the SULTAN Test Facility

Pierluigi Bruzzone, Boris Stepanov

This paper summarizes the work on the manufacturing and testing of conductor samples for ITER poloidal field 1&6 coils. The work was carried out by the IO and multiple institutions in the EU, Switzerland and Russia. Five samples were manufactured and teste ...

IEEE Institute of Electrical and Electronics Engineers2017

Crystal Structure of DMF-Intermediate Phases Uncovers the Link Between CH3NH3PbI3 Morphology and Precursor Stoichiometry

Michael Graetzel

We found for the first time a new origin of selection of perovskite crystallization pathways from DMF solutions containing MAI and PbI2 to present here a comprehensive study of a full set of essential intermediate phases determining the perovskite's morpho ...

American Chemical Society2017

Impact of water activity on the stability of ettringite

Karen Scrivener

The stability of ettringite as function of temperature and water vapour pressure was studied on synthetic samples using X-ray diffraction, thermogravimetric analysis, sorption balance measurements and different calorimetry techniques. Crystalline ettringit ...

Pergamon-Elsevier Science Ltd2016

Quantum chemical studies of reactive species in water

Daniela Trogolo

In this thesis, quantum chemical methods have been applied to elucidate the thermodynamics and the kinetics of reactions involving reactive species in water. Due to their high reactivity in water, many transient species are difficult to study by experiment ...

EPFL2016

Effects of Zeolite Structural Confinement on Adsorption Thermodynamics and Reaction Kinetics for Monomolecular Cracking and Dehydrogenation of n-Butane

Berend Smit

The effects of zeolite structure on the kinetics of n-butane monomolecular cracking and dehydrogenation are investigated for eight zeolites differing in the topology of channels and cages. Monte Carlo simulations are used to calculate enthalpy and entropy ...

American Chemical Society2016

Minimal entropy for uniform lattices in product of hyperbolic planes

Louis Georges Eric Merlin

Let M be a quotient of H-2 x ... x H-2 (product of hyperbolic planes) by a uniform lattice of. PSL2(R))(n). We prove that, among metrics of M of prescribed volume, the sum of hyperbolic metrics has minimal volume entropy. ...

European Mathematical Soc2016

Nanocalorimetric platform for accurate thermochemical studies in microliter volumes

Martinus Adela Maria Gijs, Thomas Lehnert, Raphaël Etienne Jean Trouillon, Rima Padovani

A straightforward and general way for monitoring chemical reactions is via their thermal signature. Such approach requires however an experimental setup with a high thermal stability that simultaneously allows time-resolved heat detection with high sensiti ...

Royal Soc Chemistry2015

Temperature Sensitivity of Nanochannel Electrical Conductance

Philippe Renaud, Arnaud Bertsch, Mojtaba Taghipoor

Electrical measurement is a widely used technique for the characterization of nanofluidic devices. The electrical conductivity of electrolytes is known to be dependent on temperature. However, the similarity of the temperature sensitivity of the electrical ...

Amer Chemical Soc2015

Results and analysis of the hot-spot temperature experiment for a cable-in-conduit conductor with thick conduit

Pierluigi Bruzzone, Kamil Sedlák

In the design of future DEMO fusion reactor a long time constant (similar to 23 s) is required for an emergency current dump in the toroidal field (TF) coils, e.g. in case of a quench detection. This requirement is driven mainly by imposing a limit on forc ...

Elsevier Sci Ltd2015

Hydrophobic hydration of poly-N-isopropyl acrylamide: a matter of the mean energetic state of water

Paolo De Los Rios

The enthalpically favoured hydration of hydrophobic entities, termed hydrophobic hydration, impacts the phase behaviour of numerous amphiphiles in water. Here, we show experimental evidence that hydrophobic hydration is strongly determined by the mean ener ...

Nature Publishing Group2014

Use of X-ray diffraction to quantify amorphous supplementary cementitious materials in anhydrous and hydrated blended cements

Karen Scrivener, Ruben Anton Snellings

The content of individual amorphous supplementary cementitious materials (SCMs) in anhydrous and hydrated blended cements was quantified by the PONKCS [1] X-ray diffraction (XRD) method. The analytical precision and accuracy of the method were assessed thr ...

Pergamon-Elsevier Science Ltd2014