Publication

Nonplanar structures of allyl- and pentadienylmetal compounds: folding for better charge distribution?

Manfred Schlosser
1982
Journal Articles

Abstract

The 2J (13C, H), a measure of bond angle in CH2:CHCH2R (R = MgBr, Li, Na, K), (Z)- and (E)-MeCH:CHCH2K, CH2:CHCH:CHCH2R (R = Li, K), or (E)-hexadienyllithium, is used to assign the % s character in the C-H bonds. This and the 13C NMR chem. shifts indicate conformations in which the cations are outside of the hydrocarbon planes and in which they participate in nonbonding interactions with every other (odd numbered) C atoms. The electrostatics, based on the electron d. in chains, are discussed. [on SciFinder (R)]

Official source

https://infoscience.epfl.ch/entities/publication/ff47b3d7-6ee6-4bbd-bd4e-a592ba9257bc

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Manfred Schlosser
1982
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/ff47b3d7-6ee6-4bbd-bd4e-a592ba9257bc

About this result

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Related publications (1)

Nonplanar structures of allyl- and pentadienylmetal compounds: folding for better charge distribution?

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