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Accessible triple-phase boundary length: A performance metric to account for transport pathways in heterogeneous electrochemical materials

Related publications (30)

Insights into Electrocatalyst Transformations Studied in Real Time with Electrochemical Liquid-Phase Transmission Electron Microscopy

Vasiliki Tileli, Tzu-Hsien Shen, Robin Pierre Alain Girod

The value of operando and in situ characterization methodologies for understanding electrochemical systems under operation can be inferred from the upsurge of studies that have reported mechanistic insights into electrocatalytic processes based on such mea ...

Amer Chemical Soc2023

Electron imaging of gas diffusion electrodes for proton exchange membrane fuel cells

Michele Bozzetti

The current energy crisis demands the development of new sustainable energy sources and devices with low environmental impact, including in the field of electrochemical cells. Mass transport limitations can reduce the overall performance of the device by l ...

EPFL2023

2023 Roadmap on molecular modelling of electrochemical energy materials

Alfredo Pasquarello, Chunmin Zhang, Assil Bouzid

New materials for electrochemical energy storage and conversion are the key to the electrification and sustainable development of our modern societies. Molecular modelling based on the principles of quantum mechanics and statistical mechanics as well as em ...

Iop Publishing Ltd2023

Pathways to enhance electrochemical CO2 reduction identified through direct pore-level modeling

Sophia Haussener, Shuo Liu, Etienne Boutin, Evan Fair Johnson

Electrochemical conversion of CO2 to fuels and valuable products is one pathway to reduce CO2 emissions. Electrolyzers using gas diffusion electrodes (GDEs) show much higher current densities than aqueous phase electrolyzers, yet models for multi-physical ...

2023

Catalyst Aggregate Size Effect on the Mass Transport Properties of Non-Noble Metal Catalyst Layers for PEMFC Cathodes

Yen-Chun Chen, Vasiliki Tileli, Robin Pierre Alain Girod, Michele Bozzetti, Secil Unsal

Non-noble metal catalysts (NNMCs) are regarded as a promising alternative to the costly Pt-based materials required to catalyze the oxygen reduction reaction (ORR) in proton exchange membrane fuel cell (PEMFC) cathodes. However, the large diversity of NNMC ...

ELECTROCHEMICAL SOC INC2023

Expansion Work Recovery of Hydrogen for a FC-Truck-Tentative Design of an Expansion Machine

Alfred Rufer

Hydrogen powered vehicles use high-pressure reservoirs from which the gas is transferred to the low-pressure fuel-cell via a classical pressure reduction valve. In these systems no expansion work is recovered and the question is addressed of the potential ...

MDPI2023

Using Complex Hydrides for Hydrogen Storage and Direct Borohydride Fuel Cells for Electricity Production

Youngdon Ko

Hydrogen storage and utilization are the technologies to achieve carbon-neutral energy systems with renewable energy sources. Among the various materials that have been investigated, complex hydrides are a material exhibiting high gravimetric hydrogen dens ...

EPFL2023

The design and development of anion exchange membranes for hydrogen fuel cells

Xingyu Wu

Hydrogen fuel cells are an essential component of hydrogen economy, which have been advocated as a major path towards the decarbonization of the energy sector. Within the two main types of low-temperature hydrogen fuel cells, anion-exchange membrane fuel c ...

EPFL2023

An Advanced Alkaline Al-Air Fuel Cell Using L-Ascorbic Acid Interface Layer upon Al Anode via Gradient Anti-corrosion

Pengfei Zhang, Manhui Wei

Al metal is considered as an excellent anode material for metal-air fuel cells thanks to the advantages in terms of capacity and energy density. However, the anodic parasitic corrosion has brought great obstacles to the performance breakthrough of Al-air f ...

AMER CHEMICAL SOC2023

Three-dimensional nanoimaging of fuel cell catalyst layers

Vasiliki Tileli, Robin Pierre Alain Girod, Timon Lazaridis

Catalyst layers in proton exchange membrane fuel cells consist of platinum-group-metal nanocatalysts supported on carbon aggregates, forming a porous structure through which an ionomer network percolates. The local structural character of these heterogeneo ...

NATURE PORTFOLIO2023