Publication

Metal‐Mediated Synthesis of a Mixed Arduengo‐Fischer Carbodicarbene Ligand

Kay Severin, Farzaneh Fadaei Tirani, Bastiaan Kooij, Damien Wen Chen
2024
Journal Articles

Abstract

Carbodicarbenes are strong C‐donor ligands, which have found numerous applications in organometallic and main group element chemistry. Herein, we report a structurally distinct carbodicarbene ligand, which is formed by dinitrogenative coupling of a Fischer carbene complex with an N‐heterocyclic diazoolefin. The resulting carbonyl complex serves as a stable source for the mixed Arduengo‐Fischer carbodicarbene ligand. Facile ligand transfer reactions were demonstrated to occur with gold(I), copper(I), palladium(II), and rhodium(I) complexes.

Official source

https://infoscience.epfl.ch/entities/publication/f8b8bea9-bb2d-42d8-a68c-8af65ef76951

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